离子液体1-乙基-3-甲基咪唑醋酸盐([ EMIM] Ac)可以溶解天然高分子等许多聚合物,尤其对于纤维素具有较强的溶解能力,且溶解过程基本不造成纤维素降解,故可以作为纤维素的有效溶剂,用于纤维素的溶解加工。与其它溶剂相比,[ EMIM] Ac 具有使用安全、不污染环境、易回收循环利用等优势,故在纤维素溶解、纺丝方面具有广阔的应用前景。本文主要介绍了[ EMIM] Ac 的多种制备方法及其优缺点,这对其它醋酸盐类离子液体的制备也具有指导意义;并概述了[ EMIM] Ac 在纤维素溶解、纺丝等方面的应用研究。
which has stronger ability to dissolve cellulose especially
can be used to dissolve natural polymer and many other polymers. As the dissolving process of cellulose causes no degradation
[ EMIM] Ac can be used as an effective solution in dissolving and processing of cellulose. Compared with other solutions
[ EMIM] Ac has many advantages of use safety
no pollution to environment and easy recovery recycling
and has wide application prospect in the dissolving and spinning of cellulose. Various preparation methods of [ EMIM] Ac and their advantages or disadvantages are introduced in this paper
which have a guiding significance to the preparations of other acetic acid salts ionic liquid. And the application research of [ EMIM] Ac in cellulose dissolving and spinning is summarized.
Dissolution and Spinning Research Progress of Cellulose in Alkali/Urea Compound Solvents at Low Temperature
Quality Analysis of Dissolving Pulp Cellulose Fibers in NaOH/Additives Aqueous Solution
Cellulose-based Aerogels Prepared with Ionic Liquids
Application Research Progress of Ionic Liquids in Cellulose Chemistry
Preparation and Application of Graphene/Cellulose Hybrid Materials
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Related Institution
State Key Laboratory of Biobased Fiber Manufacturing Technology, China Textile Academy Co., Ltd.
Department of Packaging Engineering, Tianjin University of Commerce
Beijing National Laboratory for Molecular Science (BNLMS),CAS Key Laboratory of Engineering Plastics, Institute of Chemistry, Chinese Academy of Sciences
College of Chemistry and Chemical Engineering,University of Chinese Academy of Sciences (UCAS )
Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Engineering Plastics (KLEP), Institute of Chemistry, Chinese Academy of Sciences (CAS)