Progress in Synthesis and Applications of Liquid-like Nanoparticles Ionic Materials

Yi-han ZHANG; Shu-ying GU; Wei-zhong YUAN

doi:10.14028/j.cnki.1003-3726.2011.08.016

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Progress in Synthesis and Applications of Liquid-like Nanoparticles Ionic Materials

更新时间：2022-09-18

- Progress in Synthesis and Applications of Liquid-like Nanoparticles Ionic Materials
- Polymer Bulletin Vol. 24, Issue 8, Pages: 8-15(2011)
- 作者机构：
  
  同济大学材料科学与工程学院，上海　201804；同济大学材料科学与工程学院先进土木工程材料教育部重点实验室，上海　201804
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2011.08.016
  CLC：
- Published：2011-08，
  
  Received：12 October 2010，
  
  Revised：30 November 2010，
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Yi-han ZHANG, Shu-ying GU, Wei-zhong YUAN. Progress in Synthesis and Applications of Liquid-like Nanoparticles Ionic Materials. [J]. Polymer Bulletin 24(8):8-15(2011)
DOI：

Yi-han ZHANG, Shu-ying GU, Wei-zhong YUAN. Progress in Synthesis and Applications of Liquid-like Nanoparticles Ionic Materials. [J]. Polymer Bulletin 24(8):8-15(2011) DOI： 10.14028/j.cnki.1003-3726.2011.08.016.

摘要

有机-无机纳米颗粒离子化材料（NIMs）是由无机纳米颗粒核和与其以共价键相连的离子化有机齐聚物或低聚物的冠状层组成的有机-无机杂化材料。根据核和冠状层的几何和化学性质，如纳米核的尺寸、形状及含量，有机层的分子量及接枝度的不同，NIMs 可以是从玻璃态固体到自由流动的流体，即纳米颗粒离子化流体（NILs）。液态有机-无机纳米颗粒离子化材料折射指数高，零蒸汽压，高的热导性，此外，液态有机-无机纳米颗粒离子化材料具有较高的化学和热稳定性，并具有离子导电性，因此在导电润滑剂、高效致冷剂、浸润蚀刻技术、能量供给、储存和生产及电解质等领域有潜在的应用。本文综述了液态有机-无机纳米颗粒离子化材料的合成方法、应用前景及结构性能研究进展，并总结了存在的问题，展望了未来研究和发展趋势。

Abstract

Organic-inorganic nanoparticle ionic materials (NIMs) are hybrid materials comprising a nanoparticle core functionized with a covalently tethered ionic corona.NIMs can be tailored over a broad range from glass solids to free flowing liquids by varying geometric and chemical characteristics of the core and corona such as content

size and shape of nanoparticles

molecular weight and grafting density. Liquid-like nanoparticle ionic materials have high-refractive-index

zero-vapor pressure

high heat conductivity.Besides

NIMs are chemically and thermally stable and ionically conductive.They are therefore excellent candidate in immersion photolithography

high-conductivity lubricants

high efficiency coolants

engergy supply

storage

production and so on.Progress in synthesis and applications of liquid-like nanoparticle ionic materials is reviewed in this review.And the problems and promising future are prospected.

关键词

纳米颗粒离子化材料导电润滑剂浸润蚀刻流变特性动力学

Keywords

Nanoparticle ionic materials (NIMs)Conductive lubricantsImmersion lithographyRheologyDynamics

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