Progress on Synthesis of Heterocyclic Polymers Containing Phthalazinone Moiety and the Relationship of Their Structure and Properties

Jin-yan WANG; Xi-gao JIAN

doi:10.14028/j.cnki.1003-3726.2011.09.003

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Progress on Synthesis of Heterocyclic Polymers Containing Phthalazinone Moiety and the Relationship of Their Structure and Properties

更新时间：2022-09-18

- Progress on Synthesis of Heterocyclic Polymers Containing Phthalazinone Moiety and the Relationship of Their Structure and Properties
- Polymer Bulletin Vol. 24, Issue 9, Pages: 22-34(2011)
- 作者机构：
  
  大连理工大学化工学院高分子材料系，大连　116024；辽宁省高性能树脂工程技术研究中心，大连　116012
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2011.09.003
  CLC：
- Published：2011-09，
  
  Received：04 July 2011，
  
  Revised：13 July 2011，
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Jin-yan WANG, Xi-gao JIAN. Progress on Synthesis of Heterocyclic Polymers Containing Phthalazinone Moiety and the Relationship of Their Structure and Properties. [J]. Polymer Bulletin 24(9):22-34(2011)
DOI：

Jin-yan WANG, Xi-gao JIAN. Progress on Synthesis of Heterocyclic Polymers Containing Phthalazinone Moiety and the Relationship of Their Structure and Properties. [J]. Polymer Bulletin 24(9):22-34(2011) DOI： 10.14028/j.cnki.1003-3726.2011.09.003.

摘要

高性能高分子材料在高温下仍保持优异的综合性能，是航空航天、电子电气、高速轨道交通等重要高技术领域不可或缺的材料。在不牺牲耐热性能的前提下改善高性能聚合物的加工性能一直是国内外研究的热点。含二氮杂萘酮结构高性能聚合物是高性能高分子材料的新成员。本文主要综述了含二氮杂萘酮结构的聚芳醚（包括聚芳醚砜酮系列、聚芳醚腈砜酮系列、聚芳醚砜酮酮系列和聚三芳基三嗪环系列）、聚芳酰胺、聚芳酯的合成与性能的研究进展。因二氮杂萘酮联苯结构具有扭曲、非平面和稠环结构特点，使上述聚合物既耐高温又可溶解，加工方式多样，即可热成型加工（模压、挤出、注射等），又可溶液方式加工，应用领域广泛。

Abstract

High-performance polymers with excellent comprehensive properties have been becoming crucial materials for their applications in aerospace

automobile

electronics

and other high technology fields.Modifying their processibility without sacrifice of their outstanding thermal stability is receiving considerable attention. Polymers containing phthalazinone moieties are a series of novel high performance thermoplastics.In this paper

the synthesis of poly(phthalazinone ether)s

involving poly (phthalazinone ether sulfone ketone) s

poly (phthalazinone ether nitrile sulfone ketone) s

poly (phthalazinone ether sulfone ketone ketone)s and poly(phthalazinone ether triphenyl1

5-triazine)s

and their structure-property were elaborately reviewed.They have outstanding thermal stability and good solubility in some aprotic polar organic solvents because of introducing twist and non-coplanar phthalazinone moiety into polymer main chain.Thus they can be processed by melting

such as injection

extrusion and molding

and in solution in the result of expanding their application

such as in coating and membrane.

关键词

聚芳醚聚芳酰胺聚芳酯聚酰亚胺二氮杂萘酮高性能聚合物

Keywords

Poly (arylene ether) sPolyamidePolyarylatePolyimidePhthalazinoneHigh performance Polymer

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