Progress in Studies on the Methodologies of Living Anionic Polymerization Using High Vacuum Technique

Hong-wei MA; Yang LI; Chun-qing ZHANG; Yu-rong WANG

doi:10.14028/j.cnki.1003-3726.2011.09.004

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Progress in Studies on the Methodologies of Living Anionic Polymerization Using High Vacuum Technique

更新时间：2022-09-18

- Progress in Studies on the Methodologies of Living Anionic Polymerization Using High Vacuum Technique
- Polymer Bulletin Vol. 24, Issue 9, Pages: 35-51(2011)
- 作者机构：
  
  精细化工国家重点实验室，辽宁省高分子科学与工程重点实验室，大连理工大学化工与环境生命学部高分子材料系，大连　116024
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2011.09.004
  CLC：
- Published：2011-09，
  
  Received：17 July 2011，
  
  Revised：21 July 2011，
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Hong-wei MA, Yang LI, Chun-qing ZHANG, Yu-rong WANG. Progress in Studies on the Methodologies of Living Anionic Polymerization Using High Vacuum Technique. [J]. Polymer Bulletin 24(9):35-51(2011)
DOI：

Hong-wei MA, Yang LI, Chun-qing ZHANG, Yu-rong WANG. Progress in Studies on the Methodologies of Living Anionic Polymerization Using High Vacuum Technique. [J]. Polymer Bulletin 24(9):35-51(2011) DOI： 10.14028/j.cnki.1003-3726.2011.09.004.

摘要

活性阴离子聚合能够得到分子量及分布可控的模板聚合物，是环状、树枝状以及多臂星形等复杂拓扑结构聚合物的重要合成方法。高真空实验技术能够使反应环境彻底封闭、杜绝杂质影响从而得到更加精确的实验数据，因此成为活性阴离子聚合理论研究的重要手段。本文对基于高真空实验技术的活性阴离子聚合方法学研究进行了总结，通过多官能引发剂、“大单体”方法、定量化偶联方法、环状聚合物以及新型功能化聚合物合成以及活性阴离子至点击化学的转化等方面的简要介绍，基本阐述了近期国内外在高真空条件下的活性阴离子聚合研究方面的进展情况。

Abstract

Living anionic polymerization is the primary method to synthesize the polymers with complicated topological structure

such as cyclic

dendritic and miktoarm star polymers.High vacuum technique is a powerful tool for the theoretical researches because excellent experimental environment free from impurities can be obtained.The studies on methodologies of living anionic polymerization using high vacuum technique were summarized.Some aspects

such as multi-functional initiators

macro-monomer

iterative titration coupling method

synthesis of cyclic polymers and new type functionalized polymers and combination of anionic polymerization and click chemistry

were introduced.

关键词

活性阴离子聚合高真空实验技术方法学研究

Keywords

Living anionic polymerizationHigh vacuum techniqueStudies on methodologies

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Related Institution

Shenyang Research Institute of Chemical Industry Co. ,Ltd

Technical Center of Dongfeng Motor Corporation

Department of Polymer Science and Engineering, School of Chemical Engineering, Dalian University of Technology

State Key Laboratory of Fine Chemicals,Key Laboratory of Polymer Science and Engineering of Liaoning Province, Department of Polymer Science and Engineering,Faculty of Chemical,Environmental and Biological Science and Technology, Dalian University of Technology

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