Advance in Research of ROMP of DCPD and the Structures and Applications of PDCPD

Fang-yuan HU; Yu-bin ZHENG

doi:10.14028/j.cnki.1003-3726.2011.09.009

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Advance in Research of ROMP of DCPD and the Structures and Applications of PDCPD

更新时间：2022-09-18

- Advance in Research of ROMP of DCPD and the Structures and Applications of PDCPD
- Polymer Bulletin Vol. 24, Issue 9, Pages: 139-150(2011)
- 作者机构：
  
  大连理工大学化工学院高分子材料系辽宁省高分子科学与工程重点实验室，大连　116024
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2011.09.009
  CLC：
- Published：2011-09，
  
  Received：08 July 2011，
  
  Revised：22 July 2011，
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Fang-yuan HU, Yu-bin ZHENG. Advance in Research of ROMP of DCPD and the Structures and Applications of PDCPD. [J]. Polymer Bulletin 24(9):139-150(2011)
DOI：

Fang-yuan HU, Yu-bin ZHENG. Advance in Research of ROMP of DCPD and the Structures and Applications of PDCPD. [J]. Polymer Bulletin 24(9):139-150(2011) DOI： 10.14028/j.cnki.1003-3726.2011.09.009.

摘要

开环易位聚合环烯烃已成为高分子工程领域的一个研究热点。其中，由于双环戊二烯(DCPD) 价格低廉、来源充分、聚合后形成的聚双环戊二烯(PDCPD) 具有优异的力学性能等优点，使得DCPD 的开环易位聚合得到广泛关注。本文综述了DCPD 开环易位聚合反应机理、催化体系、PDCPD 的结构、PDCPD 的表面改性、纳米共聚物以及PDCPD 自修复材料的研究进展。最后，对PDCPD 材料的未来发展趋势及应用前景进行了展望。

Abstract

Ring-opening metathesis polymerization(ROMP) of cycloolefins has become a research hotspot

among which the ROMP of dicyclopentadiene (DCPD) gains widespread interest recently due to the low cost

sufficient source and the excellent mechanical properties of polydicy clopentadiene (PDCPD). The mechanism of ROMP

the catalysts used in the ROMP of DCPD and the chemical structures of PDCPD were introduced

advances in PDCPD materials

the surface modification of PDCPD

PDCPD nanocopolymers and PDCPD self-healing (assembling ) materials were reviewed. Finally

future trends in PDCPD materials were forecasted.

关键词

双环戊二烯开环易位聚合聚合机理催化体系聚双环戊二烯

Keywords

DCPDROMPPolymerization mechanismCatalyst systemPDCPD

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