Progress on Molecular Design and Synthesis of High-Performance Cycloal iphatic Epoxy Resins

Zhong-gang WANG; Wan-shuang LIU; Lin-ni ZHAO; Zhuo CHEN

doi:10.14028/j.cnki.1003-3726.2011.09.013

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Progress on Molecular Design and Synthesis of High-Performance Cycloal iphatic Epoxy Resins

更新时间：2022-09-18

- Progress on Molecular Design and Synthesis of High-Performance Cycloal iphatic Epoxy Resins
- Polymer Bulletin Vol. 24, Issue 9, Pages: 13-21(2011)
- 作者机构：
  
  大连理工大学化工学院高分子材料系，大连　116024
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2011.09.013
  CLC：
- Published：2011-09，
  
  Received：29 June 2011，
  
  Revised：07 July 2011，
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Zhong-gang WANG, Wan-shuang LIU, Lin-ni ZHAO, Zhuo CHEN. Progress on Molecular Design and Synthesis of High-Performance Cycloal iphatic Epoxy Resins. [J]. Polymer Bulletin 24(9):13-21(2011)
DOI：

Zhong-gang WANG, Wan-shuang LIU, Lin-ni ZHAO, Zhuo CHEN. Progress on Molecular Design and Synthesis of High-Performance Cycloal iphatic Epoxy Resins. [J]. Polymer Bulletin 24(9):13-21(2011) DOI： 10.14028/j.cnki.1003-3726.2011.09.013.

摘要

脂环族环氧树脂具有优异的加工性、热稳定性、电绝缘性和耐紫外辐射等综合性能，已经广泛应用于航空航天、微电子封装和电机绝缘等重要工业领域。针对现代工业对高分子材料日益提高的性能和功能化要求，近年来脂环族环氧树脂的合成与性能研究非常活跃。本文综述了新型脂环族环氧树脂的分子设计与合成进展，包括环氧官能度、交联密度和玻璃化温度可调的脂环族环氧树脂的合成，脂环族环氧树脂的化学结构对热固化反应速率和固化产物性能的影响，引入硅氧烷和烷基醚链段对脂环族环氧树脂的增韧改性，热可修复性脂环族环氧树脂的合成以及结构性能关系等，对脂环族环氧树脂今后的发展趋势也做了简要介绍和展望。

Abstract

Cycloaliphatic epoxy resins (CEPs) have been used in a variety of important industrial fields such as microelectronic and LED packagings

insulation of electric generators

and fabrication of high-performance polymeric composites for aeronautics and astronautics due to their excellent processability

thermal stability

electric insulativity and UV radiation-resistance. In recent years

wide studies on the synthesis of cycloaliphatic epoxy resins have been undertaken to fulfill the increasing demands for physical properties. This paper describes the recent progress on molecular design and synthesis of novel cycloaliphatic epoxy resins with tunable functionality

crosslinking density and glass transition temperature

studies of influences of chemical structures of CEPs on thermal curing behaviors and physical properties of cured products

the toughening modifications of CEPs by incorporation of silane and alkoxyl groups as well as the thermally reworkable CEPs and their structure-property relationships. The trends for developing new CEPs are also int roduced.

关键词

脂环族环氧树脂合成结构性能关系进展

Keywords

Cycloaliphatic epoxy resinsSynthesisStructure-property relationshipProgress

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