Solubil ity of Polymers in Imidazolium Ionic Liquids

Fu-yong LIU; Jin-ming ZHANG; Jun ZHANG; Bao-qing ZHANG; Chen-yang LIU

doi:10.14028/j.cnki.1003-3726.2011.10.004

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Solubil ity of Polymers in Imidazolium Ionic Liquids

更新时间：2022-09-18

- Solubil ity of Polymers in Imidazolium Ionic Liquids
- Polymer Bulletin Vol. 24, Issue 10, Pages: 99-110(2011)
- 作者机构：
  
  中国科学院化学研究所，工程塑料重点实验室，北京　100190
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2011.10.004
  CLC：
- Published：2011-10，
  
  Received：15 August 2011，
  
  Revised：22 August 2011，
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Fu-yong LIU, Jin-ming ZHANG, Jun ZHANG, Bao-qing ZHANG, Chen-yang LIU. Solubil ity of Polymers in Imidazolium Ionic Liquids. [J]. Polymer Bulletin 24(10):99-110(2011)
DOI：

Fu-yong LIU, Jin-ming ZHANG, Jun ZHANG, Bao-qing ZHANG, Chen-yang LIU. Solubil ity of Polymers in Imidazolium Ionic Liquids. [J]. Polymer Bulletin 24(10):99-110(2011) DOI： 10.14028/j.cnki.1003-3726.2011.10.004.

摘要

离子液体(ILs)具有难挥发、热稳定、宽液程和高电导率等独特优点

在聚合物领域中的应用受到越来越多的关注。由于ILs 内部的复杂相互作用力

ILs 的溶剂化能力还不能像分子溶剂那样有定量的方法来表征

特别是ILs 与聚合物的相容性没有一个统一的判据。本文从咪唑基ILs 内部的四个主要相互作用力出发

简述了ILs 内部的相互作用对不同类型聚合物在咪唑基ILs 中溶解情况的影响

给读者一个初步的规律性认识。

Abstract

Ionic liquids (ILs) have attracted considerable attention and are widely used in the field of polymer science because of their negligible volatility

thermal stability

non-flammability

and high ionic conductivity. There is no a common theory or method defining the solvation of ILs like that of molecular solvents because of the complexity of the interactions between anion and cation of ILs. The compatibility of polymer and ILs can not be easily characterized using commonly accepted parameters. In order to address some primary rules behind the solubility phenomenon of polymers in ILs

the effects of different interactions between anion and cation on the solubility of different kinds of polymers in imidazolium ILs were discussed based on four interactions.

关键词

离子液体聚合物相互作用溶剂性质相容性

Keywords

Ionic liquidsPolymersInteractionsSolvation propertiesCompatibility

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