Research Progress of Silicon Containing Polymers by Thiol-ene Chemistry

Di HU; Cai-hong XU

doi:10.14028/j.cnki.1003-3726.2011.10.005

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Research Progress of Silicon Containing Polymers by Thiol-ene Chemistry

更新时间：2022-09-18

- Research Progress of Silicon Containing Polymers by Thiol-ene Chemistry
- Polymer Bulletin Vol. 24, Issue 10, Pages: 111-119(2011)
- 作者机构：
  
  中国科学院化学研究所，北京　100190
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2011.10.005
  CLC：
- Published：2011-10，
  
  Received：31 July 2011，
  
  Revised：25 August 2011，
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Di HU, Cai-hong XU. Research Progress of Silicon Containing Polymers by Thiol-ene Chemistry. [J]. Polymer Bulletin 24(10):111-119(2011)
DOI：

Di HU, Cai-hong XU. Research Progress of Silicon Containing Polymers by Thiol-ene Chemistry. [J]. Polymer Bulletin 24(10):111-119(2011) DOI： 10.14028/j.cnki.1003-3726.2011.10.005.

摘要

巯基-乙烯基加成反应具有清洁、高效、条件温和的特点

广泛应用于有机合成、聚合物科学和材料化学等诸多领域。国内外关于这一反应的研究已有大量文献报道

但该反应在含硅聚合物的合成与应用研究中还少有触及。本文综述了巯基-乙烯基加成反应在聚硅氮烷、聚硅碳烷、聚硅氧烷三种含硅聚合物合成中的应用

介绍了国内外的研究现状及发展趋势

并对硅基聚合物中的巯基-乙烯基加成反应的反应机理、动力学特征及其潜在应用领域进行了概述。

Abstract

The thiol-ene addition reaction is a clean

efficient

robust and mild method with wide applications in organic synthesis

polymer and materials chemistry. Till now

there are a lot of references about this reaction

but which has been used rarely in organosilicon and this micro-review summarizes the reports that describe the thiol-ene reactions of vinylsilanes prepared in polycarbosilane

polysiloxane and polysilazane. The mechanism

kinetics and its potential applications of thiol-ene addition reaction were overviewed as well.

关键词

巯基-乙烯基加成含硅聚合物合成应用

Keywords

Thiol-ene additionSilicon containing polymersSynthesisApplication.

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