Progress in Synthesis of Fluorinated Polymers

Hai-rong WANG; Ming-zu ZHANG; Pei-hong NI

doi:10.14028/j.cnki.1003-3726.2011.11.003

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Progress in Synthesis of Fluorinated Polymers

更新时间：2022-09-18

- Progress in Synthesis of Fluorinated Polymers
- Polymer Bulletin Vol. 24, Issue 11, Pages: 41-52(2011)
- 作者机构：
  
  苏州大学材料与化学化工学部，江苏省先进功能高分子材料设计及应用重点实验室，苏州　215123
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2011.11.003
  CLC：
- Published：2011-11，
  
  Received：08 March 2011，
  
  Revised：20 April 2011，
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Hai-rong WANG, Ming-zu ZHANG, Pei-hong NI. Progress in Synthesis of Fluorinated Polymers. [J]. Polymer Bulletin 24(11):41-52(2011)
DOI：

Hai-rong WANG, Ming-zu ZHANG, Pei-hong NI. Progress in Synthesis of Fluorinated Polymers. [J]. Polymer Bulletin 24(11):41-52(2011) DOI： 10.14028/j.cnki.1003-3726.2011.11.003.

摘要

含氟聚合物由于其优异的化学和物理性能以及广泛的应用前景而受到关注。根据聚合反应单体结构不同

可以通过不同方法合成各种结构的含氟聚合物。这些聚合方法主要是可控/“活性” 聚合

例如:原子转移自由基聚合(ATRP)、原子转移自由基-乙烯基自缩合聚合(ATR-SCVP)、可逆加成-断裂链转移聚合 (RAFT)、氮氧稳定自由基聚合(NMP)、活性阳离子聚合、活性阴离子聚合、氧阴离子聚合。此外

常规自由基聚合及乳液聚合方法也受到青睐。本文对近年来文献报道的不同含氟聚合物结构及其相关合成方法的研究进展进行了综述。

Abstract

Fluorinated polymers have received much attention recently because of their excellent physical and chemical properties. According to different monomers

fluorinated polymers with different structures can be synthesized by different method such as controlled/’living' polymerization: atom transfer radical polymerization (ATRP )

atom transfer radical-self-condensing vinyl polymerization (ATR-SCVP)

reversible addition-frag mentation transfer (RAFT)

nitroxide-mediated polymerization (NMP)

living cationic polymerization

living anionic polymerization

oxyanion-initiated polymerization; conventional free radical polymerization

emulsion polymerization and so forth. Living polymerization can provide the narrow molecular weight distribution and high conversion to polymers and polymerization. Polymers with different structures like linear

star-shape even branching can be synthesized through these methods. The recent progress of polymerization have been reviewed in this paper.

关键词

含氟聚合物可控/“活性”聚合常规自由基聚合乳液聚合

Keywords

Fluorinated polymersCont rolled/living polymerizationConventional free radical polyme rizationEmulsion polymerization

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