The polymeric porphyrin and Co (Ⅱ) 、Mn (Ⅱ) and Zn (Ⅱ) complexes have prepared with meso-5

10

15

20-tetra (hydroxyphenyl ) porphyrin and terephthaloyl chloride by interfacical polycondensation. Their structures were charactered with infrared spectra (IR)

scanning electron microscope (SEM) and X-ray photoelectron spectroscopic (XPS) analysis. It showed that the film of the polymeric porphyrin was synthesis by two-dimensional polymeric method

compared with the typical crystal structure of porphyrin unit. When the metalloporphyrins were synthesis

a pair of proton in which N-H bond is replaced by metal coordination

there N

1

s

orbital electron binding energy changes less than0.2eV. The other two N atom of the porphyrin ring are coordinated to the metal coordination formation σcoordination bond

effect of the M

2

p

3/2

of metal coordination electron binding energy changes more than 0.5eV. The porphyrin ring inner electron density was changed when metal ion coordination to ligand L.