Characterization and Copolymerization of Hemin and N-vinylpyrrolidone

Yao-bing YIN; Hui-dong GAO; Yu SU

doi:10.14028/j.cnki.1003-3726.2011.11.013

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Characterization and Copolymerization of Hemin and N-vinylpyrrolidone

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- Characterization and Copolymerization of Hemin and N-vinylpyrrolidone
- Polymer Bulletin Vol. 24, Issue 11, Pages: 80-83(2011)
- 作者机构：
  
  河北工程大学，邯郸　056038
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2011.11.013
  CLC：
- Published：2011-11，
  
  Received：07 November 2010，
  
  Revised：23 February 2011，
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Yao-bing YIN, Hui-dong GAO, Yu SU. Characterization and Copolymerization of Hemin and N-vinylpyrrolidone. [J]. Polymer Bulletin 24(11):80-83(2011)
DOI：

Yao-bing YIN, Hui-dong GAO, Yu SU. Characterization and Copolymerization of Hemin and N-vinylpyrrolidone. [J]. Polymer Bulletin 24(11):80-83(2011) DOI： 10.14028/j.cnki.1003-3726.2011.11.013.

摘要

利用血红素卟啉环上的乙烯基与N-乙烯吡咯烷酮进行共聚反应，制备得到了血红素-聚乙烯吡咯烷酮水溶性卟啉高分子。采用核磁、红外光谱、GPC 色谱表征了聚合物结构，同时，探讨了引发剂用量和投料比对聚合反应的影响。结果表明，血红素与乙烯基吡咯烷酮能够发生共聚反应，且生成交联结构。

Abstract

Copolymerization of vinyl group of hemin and

-vinylpyrrolidone was performed

and the water-soluble porphyrin polymer of hemin-poly (

-vinylpyrrolidone) was obtained. The structure of the polymer was characterized using

H NMR

IR spectra and GPC chromatography. Meanwhile

the effect of dosage of initiator and ratio of the two monomers on the polymerization reaction was studied. The results showed that the copolymerization between vinyl group of hemin and N-vinylpyrrolidone occurred and a cross-linking copolymer was obtained.

关键词

血红素聚乙烯吡咯烷酮共聚

Keywords

HeminPoly(N-vinylpyrrolidone)Copolymerization

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