Progress in Living/Controlled Radical Polymerization of Fluoroalkenes

Jing-wen DAI; Ru-ke BAI

doi:10.14028/j.cnki.1003-3726.2014.12.005

您当前的位置：

首页 >

文章列表页 >

Progress in Living/Controlled Radical Polymerization of Fluoroalkenes

更新时间：2022-09-18

- Progress in Living/Controlled Radical Polymerization of Fluoroalkenes
- Polymer Bulletin Vol. 27, Issue 12, Pages: 47-59(2014)
- 作者机构：
  
  中国科学院软物质化学重点实验室　中国科学技术大学高分子科学与工程系，合肥　230026
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2014.12.005
  CLC：
- Published：2014-12，
  
  Received：13 October 2014，
  
  Revised：29 October 2014，
扫描看全文
Jing-wen DAI, Ru-ke BAI. Progress in Living/Controlled Radical Polymerization of Fluoroalkenes. [J]. Polymer Bulletin 27(12):47-59(2014)
DOI：

Jing-wen DAI, Ru-ke BAI. Progress in Living/Controlled Radical Polymerization of Fluoroalkenes. [J]. Polymer Bulletin 27(12):47-59(2014) DOI： 10.14028/j.cnki.1003-3726.2014.12.005.

摘要

含氟聚合物具有优异而独特的性能，主要是通过氟烯烃的聚合反应合成的。自从上世纪90年代以来，活性/可控自由基聚合反应获得极大的进展，发展了多种活性自由基聚合的方法，为聚合物的精确设计、合成提供了强有力的手段。氟烯烃的活性/可控自由基聚合反应研究始于上世纪70年代，碘转移聚合已经成功地应用于含氟热塑性弹性体的商业化生产。文献已经报道的氟烯烃活性/可控自由基聚合反应包括碘转移聚合(ITP)、烷基硼自由基聚合、原子转移自由基聚合(ATRP)和可逆加成断裂链转移聚合(RAFT)或黄原酸酯交换法（MADIX）等。通过这些方法可以制备出分子量确定、结构多样化的含氟聚合物，如嵌段、接枝和遥爪聚合物等，使含氟聚合物的应用范围得到进一步拓展。本文结合本课题组的研究工作，对氟烯烃活性/可控自由基聚合反应的研究进展进行了简要综述。

Abstract

Fluorinated polymers exhibit excellent and unique properties and are mostly synthesized via radical polymerization of fluoroalkenes. Significant progresses have been achieved in living/controlled radical polymerization since 1990s. Several strategies for living/controlled radical polymerization have been developed and become powerful tools for precise design and synthesis of well-defined polymers. The living/controlled radical polymerization of fluoroalkenes was pioneered in the late 1970s

and the iodine transfer polymerization of fluoroalkenes was successfully used for commercial preparation of thermoplastic elastomers. The living/controlled radical polymerizations of fluoroalkenes reported in literatures include iodine transfer polymerization (ITP)

atom radical transfer polymerization (ATRP)

organic borinates and reversible addition-fragmentation chain transfer polymerization (RAFT)/interchange of xanthates (MADIX). Based on these polymerizations

the well-defined fluorinated polymers have been prepared with controlled molecular weight and various architectures

such as telechelic

block and graft copolymers. This paper summarized recent progresses in living/ controlled radical polymerization of fluoroalkenes

including our lab's achievements.

关键词

氟烯烃含氟聚合物活性聚合可控聚合

Keywords

FluoroalkenesFluoropolymerLiving polymerizationControlled polymerization

references

更多指标>

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Construction and Application of "Comb-shaped" Fluorine-containing Functional Polymers

Bulky Backbone Strategy in α-Diimine Nickel and Palladium Catalyzed-Olefin Polymerization

Research Development of Fluoropolymer Fibers

Progress on the Metal-Free Anionic Polymerization

Recent Progress in Controlled Ring-Opening Polymerization of Aliphatic Polyesters

Related Author

No data

Related Institution

Sichuan Key Laboratory of Asymmetric Synthesis and Chiral Technology

School of Science, Xihua University

University of Chinese Academy of Sciences

Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences

School of Materials Science and Engineering, Sun Yat-sen University

⁰