The Development of Bridged Polysilsesquioxanes

Shi-you GUAN; Xin-zhu YAN; Yin-feng LIU

doi:10.14028/j.cnki.1003-3726.2014.12.006

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The Development of Bridged Polysilsesquioxanes

更新时间：2022-09-18

- The Development of Bridged Polysilsesquioxanes
- Polymer Bulletin Vol. 27, Issue 12, Pages: 60-67(2014)
- 作者机构：
  
  1.华东理工大学材料科学与工程学院，上海　200237
  2.上海大学材料学院，上海　200444
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2014.12.006
  CLC：
- Published：2014-12，
  
  Received：14 October 2014，
  
  Revised：04 November 2014，
扫描看全文
Shi-you GUAN, Xin-zhu YAN, Yin-feng LIU. The Development of Bridged Polysilsesquioxanes. [J]. Polymer Bulletin 27(12):60-67(2014)
DOI：

Shi-you GUAN, Xin-zhu YAN, Yin-feng LIU. The Development of Bridged Polysilsesquioxanes. [J]. Polymer Bulletin 27(12):60-67(2014) DOI： 10.14028/j.cnki.1003-3726.2014.12.006.

摘要

桥联聚倍半硅氧烷是一类被广泛应用的有机-无机杂化材料，这种材料具有三维网状结构，该结构使其实现了有机和无机组分在分子水平上的混合，从而让它兼具有机和无机组分的双重性质，同时通过改变有机组分的类型，可以得到具有特殊性能的桥联聚倍半硅氧烷。本文从分子结构、合成方法、典型物质及典型应用方面简要介绍了桥联聚倍半硅氧烷干凝胶与气凝胶。此外，对一种具有特殊结构——有序介孔结构的桥联聚倍半硅氧烷材料从其发展历史、单体结构以及应用几个角度做了简单综述。

Abstract

Bridged polysilsesquioxanes is a widely used organic-inorganic hybrid material. This material has a three- dimensional net-like structure

which makes the material achieve the mixture of the inorganic phase and the organic phase in the molecular level. Its properties are the combination of the two-phase nature. We can gain varieties of bridged polysilsesquioxanes with different properties by changing the type of organic phase. In this paper

we introduce the bridged polysilsesquioxanes xerogel and aerogel from the view of molecular structure

synthetic methods

representative materials and typical applications. In addition

we also introduce the history

the monomer structure and the application of a special bridged polysilsesquioxane material with periodic mesoporous structure.

关键词

桥联聚倍半硅氧烷凝胶结构合成应用介孔

Keywords

Bridged polysilsesquioxanesGelStructureSynthesisApplicationMesoporous

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