Controlled ATRP of <italic style="font-style: italic">N</italic>-Hydroxysuccinimide Methacrylate and its Block Copolymer Synthesis

Bao-wei MAO; Ming JIA; Li ZHANG; Shao-kui CAO

doi:10.14028/j.cnki.1003-3726.2014.12.018

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Controlled ATRP of N-Hydroxysuccinimide Methacrylate and its Block Copolymer Synthesis

更新时间：2022-09-18

- Controlled ATRP of N-Hydroxysuccinimide Methacrylate and its Block Copolymer Synthesis
- Polymer Bulletin Vol. 27, Issue 12, Pages: 157-162(2014)
- 作者机构：
  
  郑州大学材料科学与工程学院，郑州　450001
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2014.12.018
  CLC：
- Published：2014-12，
  
  Received：09 November 2014，
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Bao-wei MAO, Ming JIA, Li ZHANG, Shao-kui CAO. Controlled ATRP of N-Hydroxysuccinimide Methacrylate and its Block Copolymer Synthesis. [J]. Polymer Bulletin 27(12):157-162(2014)
DOI：

Bao-wei MAO, Ming JIA, Li ZHANG, Shao-kui CAO. Controlled ATRP of N-Hydroxysuccinimide Methacrylate and its Block Copolymer Synthesis. [J]. Polymer Bulletin 27(12):157-162(2014) DOI： 10.14028/j.cnki.1003-3726.2014.12.018.

摘要

以CuCl/

-苄基-2-吡啶基甲亚胺(NBPM)/2-溴异丁酸乙酯(EBrIB)作为引发催化体系，使甲基丙烯酸（

-羟基琥珀酰亚胺）酯(MASI)进行ATRP聚合，得到的聚甲基丙烯酸（

-羟基琥珀酰亚胺）酯(PMASI)具有较高的单体转化率(90%)、较窄PDI(~1. 10)和较高的分子量。在整个聚合过程中，较强的C-Cl键仍使聚合物的端基保持活性，有利于与第二单体甲基丙烯酸（

-二甲氨基）乙酯（DMAEMA）嵌段共聚形成结构明确的嵌段共聚物P（MASI-

-DMAEMA）。当MASI的链长较短时，P（DMAEMA

-MASI

，）具有水溶性并可自组装成直径均匀的核-壳型微胶束，间接证明了聚合过程的可控特征。

Abstract

The present paper reports the controlled polyemrization of MASI using CuCl/N-benzyl-2-pyridylmethanimine (NBPM)/ethyl 2-bromoisobutyrate (EBrIB) as initiator. Poly(MASI) of narrow PDI (~1. 10) and high molecular weight with monomer conversion up to 90% were obtained. The end groups of the polymer remained active throughout the polymerization due to stronger carbon-chlorine bond. Thus

well-defined P(MASI

-DMAEMA

) and P(DMAEMA

- MASI

) block copolymers were obtained. P (DMAEMA

-MASI

) with shorter MASI segments showed water solubility

which self-assembled into uniform micelles with core-shell structure.

关键词

甲基丙烯酸（N-羟基琥珀酰亚胺）酯N-苄基-2-吡啶基甲亚胺ATRP甲基丙烯酸(NN-二甲氨基）乙酯

Keywords

Poly (N-hydroxysuccinimide methacrylate)N-benzyl-2-pyridylmethanimineATRP2-(Dimethylamino) ethyl methacrylate

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School of Materials Science and Engineering, Shanghai Jiao Tong University

College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning Shihua University

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State Key Laboratory of Chemical Resource Engineering, College of Materials Science and Engineering, Beijing University of Chemical Technology

⁰

Controlled ATRP of N-Hydroxysuccinimide Methacrylate and its Block Copolymer Synthesis

DOI：10.14028/j.cnki.1003-3726.2014.12.018

摘要

Abstract

关键词

Keywords

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