Progress on the Research of Silicone Modified Epoxy Resin

Xin-xiu SHI; Chong-kai YUAN; Chuan-ping WANG; Meng-zhong CUI

doi:10.14028/j.cnki.1003-3726.2015.04.003

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Progress on the Research of Silicone Modified Epoxy Resin

更新时间：2022-09-18

- Progress on the Research of Silicone Modified Epoxy Resin
- Polymer Bulletin Vol. 28, Issue 4, Pages: 18-37(2015)
- 作者机构：
  
  烟台大学化学化工学院，烟台　264005
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2015.04.003
  CLC：
- Published：2015-04，
  
  Received：21 August 2014，
  
  Revised：23 October 2014，
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Xin-xiu SHI, Chong-kai YUAN, Chuan-ping WANG, Meng-zhong CUI. Progress on the Research of Silicone Modified Epoxy Resin. [J]. Polymer Bulletin 28(4):18-37(2015)
DOI：

Xin-xiu SHI, Chong-kai YUAN, Chuan-ping WANG, Meng-zhong CUI. Progress on the Research of Silicone Modified Epoxy Resin. [J]. Polymer Bulletin 28(4):18-37(2015) DOI： 10.14028/j.cnki.1003-3726.2015.04.003.

摘要

热固性环氧树脂材料具有良好的物理、化学等诸多优异性能

对于金属和非金属材料的表面都具有优异的粘接强度

可用于浇注、浸渍、层压、粘接剂、涂料等

用途十分广泛。由于环氧树脂材料存在脆性大

抗冲击性差、耐热性差等缺点

科研工作者对环氧树脂进行了大量的改性研究并取得了丰硕的成果。有机硅化合物改性环氧树脂在提高其热氧稳定性、韧性以及耐烧蚀性能等方面具有独特的优势

近年来

研究人员利用功能性有机硅化合物或聚合物在环氧树脂进行改性方面

开展了反应共聚改性、作为交联剂固化改性、与环氧树脂共混/交联改性、增容改性、互穿聚合物网络(IPN)、引入阻燃剂结构改性以及微纳米复合改性等方面的研究

取得了很多新的成果。本文旨在总结上述各种有机硅改性环氧树脂研究的新进展

并预测了有机硅改性环氧树脂材料的潜在应用和发展方向。

Abstract

The thermosetting epoxy resins have excellent physical and chemical properties

and they have outstanding adhesive strength to the surface of both metallic and non-metallic materials. They are widely applied in casting

impregnation

lamination

adhesive and coating production

and other uses. However

epoxy resins have certain disadvantages

including brittleness

low resistance to impact and poor heat resistance

which limit their application. Many researchers have made fruitful studies on modification of epoxy resin. For example

organosilicon compound modified epoxy resin has unique advantages in improving its thermal oxidative stability

toughness and ablation resistance. In recent years

new results have been achieved in modifying epoxy resins using functional organic silicone compounds and polymers as modifiers. These researches include copolymerization modification

curing agent crosslinking modification

blending/cocrosslinking with resin epoxy modification

compatibilization modification

interpenetrating polymer network (IPN) modification

flame retardants introduced modification and nano/micron composite modification. This paper is aimed to draw a conclusion of the investigative progress of the research in organosilicon modified epoxy resins listed above. In addition

we predict the potential application and possible future development directions of silicone modified epoxy materials.

关键词

有机硅环氧树脂化学改性增韧热氧稳定性

Keywords

OrganosiliconEpoxy resinChemical modificationToughnessThermo-oxidative stability

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