Research Progress of Polyolefin Alloys (I)——Progress on Polymerization Catalysts and Processes

Bai-yu JIANG; Ai-hua HE; Zhen-xue LIU

doi:10.14028/j.cnki.1003-3726.2015.11.002

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Research Progress of Polyolefin Alloys (I)——Progress on Polymerization Catalysts and Processes

更新时间：2022-09-18

- Research Progress of Polyolefin Alloys (I)——Progress on Polymerization Catalysts and Processes
- Polymer Bulletin Vol. 28, Issue 11, Pages: 13-19(2015)
- 作者机构：
  
  1.青岛科技大学　高分子科学与工程学院　橡塑材料与工程教育部重点实验室/山东省橡塑材料与　工程重点实验室，青岛　266042
  2.黄河三角洲京博化工研究院有限公司，滨州　256500
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2015.11.002
  CLC：
- Published：2015-11，
  
  Received：14 April 2015，
  
  Revised：12 May 2015，
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Bai-yu JIANG, Ai-hua HE, Zhen-xue LIU. Research Progress of Polyolefin Alloys (I)——Progress on Polymerization Catalysts and Processes. [J]. Polymer Bulletin 28(11):13-19(2015)
DOI：

Bai-yu JIANG, Ai-hua HE, Zhen-xue LIU. Research Progress of Polyolefin Alloys (I)——Progress on Polymerization Catalysts and Processes. [J]. Polymer Bulletin 28(11):13-19(2015) DOI： 10.14028/j.cnki.1003-3726.2015.11.002.

摘要

聚烯烃合金以其优异的综合性能

得到了日益广泛的关注和研究.本文从聚合催化剂体系和聚合工艺技术角度出发

系统地综述了聚烯烃催化剂体系的发展历程及聚烯烃合金的制备工艺技术.特别介绍了基于反应器颗粒技术的聚合工艺特点

重点关注了Spheripol工艺、Catalloy工艺、Spherizone工艺等工艺技术.以第四代Ziegler-Natta催化剂为基础的反应器颗粒技术和以复合催化剂为基础的多催化剂反应器颗粒技术是聚烯烃新材料未来的发展方向。

Abstract

Polyolefin alloys have attracted lots of attentions due to its excellent comprehensive properties. In this paper

polymerization progresses of polyolefin alloys were reviewed systematically from the aspects of catalyst systems and polymerization processes. The features of polymerization processes of polyolefin alloys were illustrated briefly. Typical polymerization processes based on the reactor granule technology

such as Spheripol process

Catalloy process and Spherizone process

were discussed in detail. It was noted that development of novel polyolefin materials based on the reactor granule technology from the 4th generation catalyst and the multicatalyst reactor granule technology from the two-component catalyst technology will be the researching direction in the future.

关键词

聚烯烃合金工艺反应器颗粒技术

Keywords

Polyolefin alloysProcessReactor granule technology

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Related Institution

Shandong Provincial Key Laboratory of Olefin Catalysis and Polymerization, Key Laboratory of Rubber-Plastics(Ministry of Education)/Shandong Provincial Key Laboratory of Rubber-Plastics, School of Polymer Science and Engineering, Qingdao University of Science and Technology

Institute of Material Science and Engineering, South China University of Technology

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