The Research of ATRP Macromolecular Initiator and Application Process in the Molecular Structure Design

Si-yang MU; Jing GUO; Shan-wei QI; Li-jun YANG; Yu-mei GONG; Sen ZHANG

doi:10.14028/j.cnki.1003-3726.2015.11.004

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The Research of ATRP Macromolecular Initiator and Application Process in the Molecular Structure Design

更新时间：2022-09-18

- The Research of ATRP Macromolecular Initiator and Application Process in the Molecular Structure Design
- Polymer Bulletin Vol. 28, Issue 11, Pages: 28-34(2015)
- 作者机构：
  
  大连工业大学　纺织与材料工程学院，大连　116034
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2015.11.004
  CLC：
- Published：2015-11，
  
  Received：27 January 2015，
  
  Revised：26 April 2015，
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Si-yang MU, Jing GUO, Shan-wei QI, Li-jun YANG, Yu-mei GONG, Sen ZHANG. The Research of ATRP Macromolecular Initiator and Application Process in the Molecular Structure Design. [J]. Polymer Bulletin 28(11):28-34(2015)
DOI：

Si-yang MU, Jing GUO, Shan-wei QI, Li-jun YANG, Yu-mei GONG, Sen ZHANG. The Research of ATRP Macromolecular Initiator and Application Process in the Molecular Structure Design. [J]. Polymer Bulletin 28(11):28-34(2015) DOI： 10.14028/j.cnki.1003-3726.2015.11.004.

摘要

原子转移自由基聚合(ATRP)是一种新型"活性"/可控聚合技术

可有效地实现对聚合物分子结构的设计

精准地控制聚合物分子结构.本文在介绍了官能团反应法、偶联反应法以及自由基聚合法制备ATRP大分子引发剂的基础上

进一步介绍了通过控制大分子引发剂"活性"点位置进行聚合物结构设计.同时还着重综述了大分子引发剂在嵌段聚合物、梳状聚合物、分子刷聚合物、树状及超支化聚合物和星形聚合物分子设计中的应用。

Abstract

The Atom Transfer Radical Polymerization(ATRP) is a new type of controllable/active polymerization technology

which can effectively realize the structure design of the polymer molecular and precise control the polymer molecular structure. In this paper

we firstly introduce latest advances about the preparation methods of the ATRP macromolecular initiator in recent years

such as functional group reaction

coupling reaction and free radical polymerization. Then

we emphatically summarize the structure design of the the polymer through controlling the active position of macromolecules initiators briefly. Moreover

we focus on introducing the latest application of the macromolecular initiator through ATRP reaction in the structure design of the polymer

such as block polymers

comblike polymer

molecular brush polymer

dendritic polymers

branched polymer

star polymer.

关键词

ATRP大分子引发剂分子设计进展

Keywords

ATRPMacromolecular initatorMolrcular designResearch progress

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