Due to the mild condition and high selectivity

polymerization catalyzed by enzyme has attracted many scholars’ attentions. In this paper

enzymatic synthesis of polysaccharide

polyester

polycarbonate

polyaniline

polyolefin and phenolic polymer were summarized. Polymers with special structure

such as functional polyester and phenolic polymer

can be prepared owing to high selectivity of enzymatic reaction. Though enzymatic polymerizations have good application prospects

there are still some problems to be solved in the field and they were discussed at the end of the paper.