Research Progress Catalysts for the Copolymerization of 4-Methyl-1-pentene and Olefins

Jun WANG; Lian-peng LIU; Cui-qin LI; Wei-guang SHI

doi:10.14028/j.cnki.1003-3726.2016.03.005

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Research Progress Catalysts for the Copolymerization of 4-Methyl-1-pentene and Olefins

更新时间：2022-09-12

- Research Progress Catalysts for the Copolymerization of 4-Methyl-1-pentene and Olefins
- Polymer Bulletin Vol. 29, Issue 3, Pages: 29-35(2016)
- 作者机构：
  
  东北石油大学石油与天然气化工省重点实验室，大庆 163318
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2016.03.005
  CLC：
- Published：20 March 2016，
  
  Received：05 August 2015，
  
  Revised：14 October 2015，
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Jun WANG, Lian-peng LIU, Cui-qin LI, Wei-guang SHI. Research Progress Catalysts for the Copolymerization of 4-Methyl-1-pentene and Olefins. [J]. Polymer Bulletin 29(3):29-35(2016)
DOI：

Jun WANG, Lian-peng LIU, Cui-qin LI, Wei-guang SHI. Research Progress Catalysts for the Copolymerization of 4-Methyl-1-pentene and Olefins. [J]. Polymer Bulletin 29(3):29-35(2016) DOI： 10.14028/j.cnki.1003-3726.2016.03.005.

摘要

4-甲基-1-戊烯(4M1P)是烯烃工业中一种重要的支链α-烯烃

它的主要用途是用于制备均聚物和共聚物。虽然绝大部分4M1P共聚物尚未进入工业化生产阶段

但由于共聚物作为一类新型的合成树脂具有突出的力学性能和光学性能

已成为国外聚烯烃领域的一个研究热点。本文阐述了4M1P与烯烃共聚反应催化剂包括Ziegler-Natta催化剂、茂金属催化剂及后过渡金属催化剂的开发研究现状;重点阐述了催化剂的结构对共聚物分子结构的影响;同时也简要介绍了二亚胺镍催化剂催化4M1P共聚反应作用机理

展望了这一领域的发展趋势。为开发高端聚烯烃新材料提供参考。

Abstract

4-Methyl-1-pentene(4M1P)

which main purpose is to prepare homopolymers and copolymers

is an important branched chain α-olefin. Although majority 4M1P copolymers have not to be industrialized

the copolymers with excellent mechanical and optical properties have became a hot research topic on the field of foreign polyolefins as a new type synthetic resin. In this paper

the research and development status of copolymerization catalysts including Ziegler-Natta catalysts

metallocene catalysts and transition metal catalyst for copolymerization of 4M1P and olefin has been reviewed. The influence of catalyst structure on the molecular structure of the copolymers was summarized emphatically. And the α-Diimine Nickel Catalyst catalytic mechanism of typical 4M1P copolymerization was also briefly introduced

as well as prospects for further work in this field. This paper provided theoretical support for developing of high-end polyolefin new material.

关键词

4-甲基-1-戊烯烯烃共聚功能聚烯烃催化剂

Keywords

4-Methyl-1-penteneOlefin copolymerizationFunctional polyolefinCatalyst

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Research and Development Center of Carbon Based Synthetic Materials of Huayang Group

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