Recent Advances in Lipase Catalyzed Ring-opening Polymerization

Dong WANG; Yan XIAO; Heng XU; Mei-dong LANG

doi:10.14028/j.cnki.1003-3726.2016.08.001

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Recent Advances in Lipase Catalyzed Ring-opening Polymerization

更新时间：2022-09-12

- Recent Advances in Lipase Catalyzed Ring-opening Polymerization
- Polymer Bulletin Vol. 29, Issue 8, Pages: 1-11(2016)
- 作者机构：
  
  1.华东理工大学材料科学与工程学院，超细材料制备与应用教育部重点实验室，上海 200237
  2.石油化工新材料协同创新中心，安庆 246011
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2016.08.001
  CLC：
- Published：20 August 2016，
  
  Received：18 November 2015，
  
  Revised：26 January 2016，
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Dong WANG, Yan XIAO, Heng XU, Mei-dong LANG. Recent Advances in Lipase Catalyzed Ring-opening Polymerization. [J]. Polymer Bulletin 29(8):1-11(2016)
DOI：

Dong WANG, Yan XIAO, Heng XU, Mei-dong LANG. Recent Advances in Lipase Catalyzed Ring-opening Polymerization. [J]. Polymer Bulletin 29(8):1-11(2016) DOI： 10.14028/j.cnki.1003-3726.2016.08.001.

摘要

酶是一种绿色、安全、高效、专一的生物催化剂，在反应中具有能耗小、可循环利用和选择性高等优点，更重要的是酶催化聚合能够制备传统的化学催化无法（或难以）实现的聚合物，具有一定的工业化前景。本文简述了酶催化的发展历程、机理以及其制备特殊结构和功能聚合物材料的特点，特别是脂肪酶催化下的开环聚合相对于缩聚反应来说，具有反应条件温和、分子量和结构可控性好等优势，因此重点描述脂肪酶催化开环聚合在合成不同拓扑结构（线型、支化、交联）聚合物中的研究进展。

Abstract

Enzyme is a green

safe

efficient and specific biocatalyst with advantages of low energy consumption

recyclability and high selectivity. It is more important that enzyme-catalyzed polymerization may lead to polymers which cannot be (easily) prepared by conventional chemical catalysis. Therefore

enzymatic polymerization possesses definite potential for industrialization. This review describes the development of enzyme catalyst

its catalytic mechanism as well as its character of preparation for polymeric materials with special structure and functionality. The lipase-catalyzed ring-opening polymerization is especially advantageous to condensation polymerization with the aspects of mid reaction condition and good control over molecular weight and structure. Therefore

lipase-catalyzed ring-opening polymerization to synthesize polymers of different topologies (linear

branched

crosslinked) is emphasized.

关键词

酶脂肪酶催化开环聚合拓扑结构

Keywords

EnzymeLipase-catalyzedRing-opening polymerizationTopologies

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