Progress in the Research of Poly(trimethylene carbonate)

Li-qun YANG; Qun-hua ZHOU; Wei ZHANG; Miao LI; Jian-xin LI

doi:10.14028/j.cnki.1003-3726.2016.08.004

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Progress in the Research of Poly(trimethylene carbonate)

更新时间：2022-09-12

- Progress in the Research of Poly(trimethylene carbonate)
- Polymer Bulletin Vol. 29, Issue 8, Pages: 29-43(2016)
- 作者机构：
  
  1.辽宁省计划生育科学研究院，国家卫生和计划生育委员会生殖健康与遗传医学重点实验室，沈阳 110031
  2.郑州澍青医学高等专科学校，郑州 450064
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2016.08.004
  CLC：
- Published：20 August 2016，
  
  Received：05 January 2016，
  
  Revised：17 March 2016，
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Li-qun YANG, Qun-hua ZHOU, Wei ZHANG, Miao LI, Jian-xin LI. Progress in the Research of Poly(trimethylene carbonate). [J]. Polymer Bulletin 29(8):29-43(2016)
DOI：

Li-qun YANG, Qun-hua ZHOU, Wei ZHANG, Miao LI, Jian-xin LI. Progress in the Research of Poly(trimethylene carbonate). [J]. Polymer Bulletin 29(8):29-43(2016) DOI： 10.14028/j.cnki.1003-3726.2016.08.004.

摘要

聚三亚甲基碳酸酯具有良好的生物降解性能及生物相容性，是一种重要的生物降解医用高分子材料，在生物医用领域具有较大的应用前景。本文结合近年来的研究进展，综述了阳离子开环聚合、阴离子开环聚合、配位聚合、酶促开环聚合以及微波开环聚合等方法在聚三亚甲基碳酸酯制备过程中的应用，总结了聚三亚甲基碳酸酯的分子量与物理性能的关系，并重点讨论了聚三亚甲基碳酸酯的体内外降解性能，详细描述了分子量及脂肪酶对聚三亚甲基碳酸酯降解行为的影响，最后总结了聚三亚甲基碳酸酯在生物医用领域的应用。

Abstract

As one of the most important aliphatic polycarbonates

poly (trimethylene carbonate) (PTMC) has been widely studied because of its well-documented biocompatibility

biodegradability and rubber-like properties. This paper summarized the synthesis methods of PTMC

such as cationic

anionic

enzymatic ring-opening polymerization

microwave radiation polymerization and coordination polymerization

and discussed the effect of molecular weight on the physical properties of PTMC. Furthermore

the degradation behavior of PTMC in vitro and in vivo was especially discussed with the description of the role of molecular weight as well as enzymes on the degradation behavior of PTMC. At last

this paper summarized the potential applications of PTMC in biomedical fields.

关键词

聚三亚甲基碳酸酯开环聚合物理性能降解性能医用材料

Keywords

Poly (trimethylene carbonate)Ring-opening polymerizationPhysical propertiesDegradation behaviorBiomedical materials

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