Recent Progress on Poly (butylene succinate) : Synthesis, Copolymerization and Functionalization

Liu-chun ZHENG; Chun-cheng LI; Shao-hua WU; Dong ZHANG; Yao-nan XIAO; Bo ZHANG; Wen-xiang ZHU

doi:10.14028/j.cnki.1003-3726.2016.09.010

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Recent Progress on Poly (butylene succinate) : Synthesis, Copolymerization and Functionalization

Special Issue for Celebrating 60th Anniversary of ICCAS | 更新时间：2022-09-12

- Recent Progress on Poly (butylene succinate) : Synthesis, Copolymerization and Functionalization
- Polymer Bulletin Vol. 29, Issue 9, Pages: 115-125(2016)
- 作者机构：
  
  1.中国科学院化学研究所工程塑料院重点实验室，北京 100190
  2.中国科学院大学，北京 100049
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2016.09.010
  CLC：
- Published：20 September 2016，
  
  Received：07 June 2016，
  
  Revised：04 July 2016，
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Liu-chun ZHENG, Chun-cheng LI, Shao-hua WU, Dong ZHANG, Yao-nan XIAO, Bo ZHANG, Wen-xiang ZHU. Recent Progress on Poly (butylene succinate) : Synthesis, Copolymerization and Functionalization. [J]. Polymer Bulletin 29(9):115-125(2016)
DOI：

Liu-chun ZHENG, Chun-cheng LI, Shao-hua WU, Dong ZHANG, Yao-nan XIAO, Bo ZHANG, Wen-xiang ZHU. Recent Progress on Poly (butylene succinate) : Synthesis, Copolymerization and Functionalization. [J]. Polymer Bulletin 29(9):115-125(2016) DOI： 10.14028/j.cnki.1003-3726.2016.09.010.

摘要

聚丁二酸丁二酯（PBS)因具备良好的物理性能和加工性能而备受关注，是最具有前途的生物降解材料之一。本文总结了 PBS材料合成、共聚改性及其功能化方面的研究进展。无规共聚、嵌段共聚等方法可以调节材料的力学性能、生物降解性能、热性能和结晶行为。通过与聚富马酸丁二酯无规共聚或者嵌段共聚，可以利用分子链上的双键高效引入磺酸根、羧酸、氨基等基团，提高材料的亲水性和生物相容性能，并制备PH响应性的电荷翻转胶束，拓展PBS在生物医药领域的应用。

Abstract

Poly(butylene succinate) (PBS) is one of the most promising members of biodegradable materials because of its good physical property and processability. In this review

progress on synthesis

copolymerization and functionalization of PBS has been summarized. The material's mechanical properties

biodegrability

thermal properties and crystallization behavior can be tuned by random copolymerization and block copolymerization. Sulfonate

carboxylate

amino have been introduced to improve the hydrophilicity and biocompatibility via the high-efficient reaction of the double bonds on poly (butylene fumarate) based random or block polymers. Micelles with pH-triggered reversible surface charges has been prepared. It has great potential to be used as intelligent drug delivery system for cancer therapy.

关键词

聚丁二酸丁二酯共聚力学性能降解功能化

Keywords

Poly(butylene succinate)CopolymerizationMechanical propertiesBiodegradationFunctionalization

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