The Progress of the Hydrosilylation Polymerization

Xiu-fang HUA; Chuan-yang LI; Dong-mei GUI

doi:10.14028/j.cnki.1003-3726.2016.09.020

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The Progress of the Hydrosilylation Polymerization

Special Issue for Celebrating 60th Anniversary of ICCAS | 更新时间：2022-09-12

- The Progress of the Hydrosilylation Polymerization
- Polymer Bulletin Vol. 29, Issue 9, Pages: 203-226(2016)
- 作者机构：
  
  1.中国科学院长春应用化学研究所高分子物理与化学重点实验室，长春 130022
  2.中国科学院大学长春分院，长春 130022
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2016.09.020
  CLC：
- Published：20 September 2016，
  
  Received：19 May 2016，
  
  Revised：24 June 2016，
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Xiu-fang HUA, Chuan-yang LI, Dong-mei GUI. The Progress of the Hydrosilylation Polymerization. [J]. Polymer Bulletin 29(9):203-226(2016)
DOI：

Xiu-fang HUA, Chuan-yang LI, Dong-mei GUI. The Progress of the Hydrosilylation Polymerization. [J]. Polymer Bulletin 29(9):203-226(2016) DOI： 10.14028/j.cnki.1003-3726.2016.09.020.

摘要

硅氢化反应可以构建Si-C、Si-O、Si-N键，是有机硅化学中的重要反应，通过研究筛选合适的催化体系设计适当的单体进行硅氢化聚合来构建新型的大分子进而制备新的高分子材料是现在高分子化学发展的重要方向之一。本文综述了近几十年硅氢化聚合的研究进展，根据硅氢化聚合单体官能团的种类与数目，分为烯烃的硅氢化聚合、炔烃的硅氢化聚合、醛酮的硅氢化聚合以及非线性硅氢化聚合四个部分进行叙述，重点介绍不同结构的单体所得聚合物的分子量和性质的差异，通过对这方面的总结与分析，希望能够给予从事相关工作的科研工作者一定的思路和启发。

Abstract

Hydrosilylation is one of the most important reactions in organosilicon chemistry

by which Si-X bond can be constructed. Using favorable monomers and catalysts

polymers with different structures and unique functions can be prepared through hydrosiltlation polymerization

which is a frontier in polymer chemistry. In this paper

hydrosilylation polymerization of olefins

alkynes

aldehydes and ketones

as well as nonlinear hydrosilylation polymerization are mainly introduced. We focus on the molecular weight and properties of polymers obtained from diverse systems. By summarizing the previous works of hydrosilylation polymerization

it is hoped to give some ideas and inspirations for related researchers.

关键词

硅氢化聚合聚碳硅烷聚碳硅氧烷聚硅醚超支化含硅聚合物

Keywords

Hydrosilylation polymerizationPolycarbosilanePolycarbosiloxanePoly ( silyl ether)Hyperbranched silicon-containing polymer

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Key Laboratory of Green Preparation and Application for Functional Materials,Ministry of Education; School of Materials Science and Engineering, Hubei University

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