Research Progress on Spiro Orthoester Expansion Compound

Jing LIU; Gang LI; Yang LIU

doi:10.14028/j.cnki.1003-3726.2017.06.004

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Research Progress on Spiro Orthoester Expansion Compound

更新时间：2022-09-06

- Research Progress on Spiro Orthoester Expansion Compound
- Polymer Bulletin Vol. 30, Issue 6, Pages: 27-31(2017)
- 作者机构：
  
  辽宁工程技术大学材料科学与工程学院，阜新 123000
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2017.06.004
  CLC：
- Published：01 June 2017，
  
  Received：02 December 2015，
  
  Revised：10 March 2017，
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Jing LIU, Gang LI, Yang LIU. Research Progress on Spiro Orthoester Expansion Compound. [J]. Polymer Bulletin 30(6):27-31(2017)
DOI：

Jing LIU, Gang LI, Yang LIU. Research Progress on Spiro Orthoester Expansion Compound. [J]. Polymer Bulletin 30(6):27-31(2017) DOI： 10.14028/j.cnki.1003-3726.2017.06.004.

摘要

膨胀单体的特点是在聚合过程中没有体积收缩，甚至会产生体积膨胀，这种特殊的性能使其具有广阔的应用前景。目前可用作膨胀单体的螺环化合物主要有螺环原碳酸酯（SOC)、螺环原酸酯(SOE)和双环原酸酯(BOE)。螺环原酸酯（SOE)是最早发现能进行膨胀聚合反应的一类化合物。本文介绍了螺环原酸酯类化合物的发现、合成方法、聚合反应及应用的研究进展，并提出未来的发展前景。

Abstract

The characteristic of expansion monomer is no volume shrinkage during the polymerization process

even to produce volume expansion. This special performance has broad application prospects. Currently spiro compounds that can be used as expansion monomer mainly include spiro orthocarbonate (SOC)

spiro orthoester (SOE) and bicyclic orthoester (BOE). Spiro orthoester (SOE) is discovered the first class of compounds capable of swelling polymerization. This article demonstrated the discovery

synthetic methods and polymerization reaction of spiro orthoesters

and reviewed their applications

then proposed their future developments.

关键词

螺环原酸酯膨胀化合物聚合反应应用

Keywords

Spiro orthoesterExpansion compoundPolymerizationApplication

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