Research Progress of Synthesis,Properties and Applications of FDCA Based Polyesters

Shu-gang MA; Hua CAI; Shi-xuan XIN

doi:10.14028/j.cnki.1003-3726.2017.09.001

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Research Progress of Synthesis,Properties and Applications of FDCA Based Polyesters

更新时间：2022-09-06

- Research Progress of Synthesis,Properties and Applications of FDCA Based Polyesters
- Polymer Bulletin Vol. 30, Issue 9, Pages: 1-9(2017)
- 作者机构：
  
  1.中国石油天然气股份有限公司石油化工研究院，北京 102206
  2.中国石油天然气股份有限公司华北化工销售分公司，北京 100009
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2017.09.001
  CLC：
- Published：01 September 2017，
  
  Received：10 June 2017，
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Shu-gang MA, Hua CAI, Shi-xuan XIN. Research Progress of Synthesis,Properties and Applications of FDCA Based Polyesters. [J]. Polymer Bulletin 30(9):1-9(2017)
DOI：

Shu-gang MA, Hua CAI, Shi-xuan XIN. Research Progress of Synthesis,Properties and Applications of FDCA Based Polyesters. [J]. Polymer Bulletin 30(9):1-9(2017) DOI： 10.14028/j.cnki.1003-3726.2017.09.001.

摘要

生物质资源是一种储量丰富的可再生资源。生物质资源的高效利用不仅具有非常巨大的经济和生态价值，而且对新能源与生物基合成材料的可持续发展战略具有重大意义。由植物纤维素等生物质材料经生物或者简单化学过程处理，可获得丰富的生物基单体2，5-呋喃二甲酸（FDCA）。FDCA可用于生物基聚酯材料的合成。FDCA系列聚酯材料性能优异，可作为由石油基单体对苯二甲酸（PTA）而合成的芳香族聚酯材料（例如PET）的一种潜在的高性能生物可降解替代材料。本文简要说明了生物基单体FDCA的物性及制备方法，并重点阐述了包括聚呋喃二甲酸乙二酯（PEF）与聚呋喃二甲酸丁二酯（PBF）等一系列FDCA基聚酯材料的合成及性质，同时对FDCA基聚酯材料的应用进展进行了简要介绍，最后对FDCA基聚酯生物基合成材料的发展前景作了初步展望。

Abstract

Biomass is a class of abundant renewable resource.The high efficiency use of biomass not only has a great economic and ecological value

but also of great significance for the implementation of sustainable development strategies for new energy and new bio-based synthetic materials.2

5-furandicarboxylic acid (FDCA) as a bio-based monomer

can be obtained now in mass amount from plant cellulose via simple bio-or chemical processes.FDCA can be used for the syntheses of the FDCA based polyesters.These polyesters have excellent properties and are regarded as bio-degradable potentially substitution materials for aromatic polyesters (such as PET)

which are synthesized from oil-based purified terephthalic acid (PTA).The properties and preparation methods of bio-based monomer FDCA are briefly summarized.The synthesis and properties of FDCA based polyesters

including poly(ethylene 2

5-furandicarboxylate) (PEF) and poly(1

4-butylene 2

5-furandicarboxylate) (PBF) are discussed.The progress of FDCA based polyesters application is introduced

and the expectations for the development and prospect of FDCA based polyesters are proposed.

关键词

生物质资源2，5-呋喃二甲酸聚酯合成材料应用

Keywords

Biomass2 5-Furandicarboxylic acidPolyesterSynthetic materialsApplication

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