The Progress of Iron Compounds for Degradable Polyesters

Jin-xi DOU; Rui WANG; Wen-juan ZHANG; Dong-zhi ZHU; Wen-hua SUN

doi:10.14028/j.cnki.1003-3726.2018.01.002

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The Progress of Iron Compounds for Degradable Polyesters

更新时间：2022-09-05

- The Progress of Iron Compounds for Degradable Polyesters
- Polymer Bulletin Vol. 31, Issue 1, Pages: 13-22(2018)
- 作者机构：
  
  1.北京服装学院材料学院，北京市服装材料研究开发与评价重点实验室，北京市纺织纳米纤维工程技术研究中心，北京　100029
  2.中国科学院化学研究所　工程塑料重点实验室，北京　100190
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2018.01.002
  CLC：
- Published：20 January 2018，
  
  Received：02 November 2017，
  
  Revised：25 November 2017，
扫描看全文
Jin-xi DOU, Rui WANG, Wen-juan ZHANG, Dong-zhi ZHU, Wen-hua SUN. The Progress of Iron Compounds for Degradable Polyesters. [J]. Polymer Bulletin 31(1):13-22(2018)
DOI：

Jin-xi DOU, Rui WANG, Wen-juan ZHANG, Dong-zhi ZHU, Wen-hua SUN. The Progress of Iron Compounds for Degradable Polyesters. [J]. Polymer Bulletin 31(1):13-22(2018) DOI： 10.14028/j.cnki.1003-3726.2018.01.002.

摘要

牛物可降解材料由于其绿色环保性，越来越引起人们的关注，催化剂在其制备中具有非常重要的作用。目前工业中常采用锡类催化剂催化环酯单体的开环聚合得到，成本较高，同时锡在聚合物中的残留限制了它们的应用。铁是地球上丰度较高的金属元素，对人体无害以及具有独特的牛物活性等特点，现有报道表明铁化合物能在温和条件下高效催化内酯聚合，是未来绿色催化制备聚酯的重要发展方向。本文主要介绍铁化合物催化制备牛物可降解聚酯的进展。

Abstract

Biodegradable polyesters have attracted much attention because of their environmentally friendlily. The metal catalyst plays a very important role in their preparation. Up to now

tin-based catalysts are often used to catalyze ring- opening polymerization of cyclic ester monomers in the industry

in which the cost is high and the residues of tin in the polymer also limit their applications. Iron is the abundant metal elements on the earth

and it also has a friendly and unique biological activity for human being. Iron compounds can catalyze cyclic ester polymerization under mild conditions

which is a potentially important green catalyst for biodegradable polyesters in the future. In this paper

the progress of iron catalyst for preparation of biodegradable polyesters was reviewed from several aspects.

关键词

催化剂开环聚合铁化合物生物可降解聚酯

Keywords

CatalystRing-opening polymerizationIron compoundsBiodegradable polyesters

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