Applications of Organic Reactions in the Synthesis of POPs from the View of Reaction Conditions

Ji-tao HUANG; Liang-ji CHEN; Zi-yin LI; Quan-jie LIN; Yi-si YANG; Fa-hui XIANG; Zhang-jing ZHANG; Sheng-chang XIANG

doi:10.14028/j.cnki.1003-3726.2018.06.011

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Applications of Organic Reactions in the Synthesis of POPs from the View of Reaction Conditions

更新时间：2022-09-05

- Applications of Organic Reactions in the Synthesis of POPs from the View of Reaction Conditions
- Polymer Bulletin Vol. 31, Issue 6, Pages: 114-128(2018)
- 作者机构：
  
  1.福建师范大学化学与材料学院, 福州 350007
  2.宁德师范学院化学与材料学院, 宁德 352100
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2018.06.011
  CLC：
- Published：20 June 2018，
  
  Received：31 January 2018，
  
  Revised：04 April 2018，
扫描看全文
Ji-tao HUANG, Liang-ji CHEN, Zi-yin LI, Quan-jie LIN, Yi-si YANG, Fa-hui XIANG, Zhang-jing ZHANG, Sheng-chang XIANG. Applications of Organic Reactions in the Synthesis of POPs from the View of Reaction Conditions. [J]. Polymer Bulletin 31(6):114-128(2018)
DOI：

Ji-tao HUANG, Liang-ji CHEN, Zi-yin LI, Quan-jie LIN, Yi-si YANG, Fa-hui XIANG, Zhang-jing ZHANG, Sheng-chang XIANG. Applications of Organic Reactions in the Synthesis of POPs from the View of Reaction Conditions. [J]. Polymer Bulletin 31(6):114-128(2018) DOI： 10.14028/j.cnki.1003-3726.2018.06.011.

摘要

多孔有机聚合物（POPs）是一种完全通过有机共价连接的具有良好的热、化学稳定性以及高的比表面积和永久空隙率的化合物，在气体储存、吸附分离、均相催化、光电材料等领域潜具有潜在的应用前景。将基础有机反应拓展到POPs的合成，不仅可以通过多样的、可调节的合成方法赋予POPs优异的性能，而且极大地促进了POPs的发展，使之成为继沸石、MOFs等之后研究的一大热点。由于POPs具有高的分子量和交联度，合成单体具有大的立体空间结构产生的空间位阻等特点，要求合成条件更为苛刻。Suzuki及Friedel-Crafts烷基化反应作为合成POPs重要的合成方法，本文系统地介绍了这两种方法的历史、反应体系以及近几年在POPs合成中的最新研究进展，希望从合成体系的角度为POPs的设计、合成提供一定的借鉴。

Abstract

Porous organic polymers (POPs) are compounds completely linked by organic covalent bonds

possessing good thermal and chemical stability

high specific surface area

permanent porosity

and potential applications in gas storage

adsorption

separation

homogeneous catalysis

et cl. As extension applications of basic organic synthesis

the synthesis of POPs not only endows the compound with excellent properties by diverse and adjustable synthetic methods but also greatly promotes the development of POPs

making it a highlight after zeolite

MOFs and so on. Getting a high molecular weight and crosslinking degree of POPs is a challenge restricted by the monomers steric resistance and stringent synthesis conditions. Here

recent progress about two main methods-Suzuki and Friedel-Crafts alkylation reaction

is provided a prospect of POPs synthesis development.

关键词

POPsSuzuki反应傅克烷基化反应催化体系气体吸附

Keywords

POPsSuzuki coupling reactionFriedel-Crafts alkylation reactionsCatalyst systemGas adsorption

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Liaoning Province Key Laboratory of Polymer Science and Engineering, Department of Polymer Science and Engineering, School of Chemical Engineering, Dalian University of Technology

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