Research Progress of Polyaniline/Carbon Nanotube Composites

Chun-lei ZHAO; Rui WANG; Hong GONG; Heng JIANG

doi:10.14028/j.cnki.1003-3726.2018.07.014

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Research Progress of Polyaniline/Carbon Nanotube Composites

更新时间：2022-09-06

- Research Progress of Polyaniline/Carbon Nanotube Composites
- Polymer Bulletin Vol. 31, Issue 7, Pages: 113-117(2018)
- 作者机构：
  
  辽宁石油化工大学化学与材料科学学院，抚顺　113001
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2018.07.014
  CLC：
- Published：20 July 2018，
  
  Received：19 September 2017，
  
  Revised：09 December 2017，
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Chun-lei ZHAO, Rui WANG, Hong GONG, Heng JIANG. Research Progress of Polyaniline/Carbon Nanotube Composites. [J]. Polymer Bulletin 31(7):113-117(2018)
DOI：

Chun-lei ZHAO, Rui WANG, Hong GONG, Heng JIANG. Research Progress of Polyaniline/Carbon Nanotube Composites. [J]. Polymer Bulletin 31(7):113-117(2018) DOI： 10.14028/j.cnki.1003-3726.2018.07.014.

摘要

聚苯胺(PANI)作为一种研究最广泛的导电高分子材料，具有高导电性及良好的氧化还原性。但PANI具有的共轭离域结构使其难溶于有机溶剂，在中性和碱性环境中电导性差，应用受到制约。将具有优异电学性能、导热性能、光学性能和机械性能的碳纳米管(CNTs)与PANI复合，克服PANI的结构缺陷，充分发挥二者的协同作用，可有效提高电容和循环稳定性。综述了近年来国内外有关PANI/CNTs复合材料的制备方法，如化学氧化聚合法和电化学聚合法等，详细介绍了 PANI/CNTs复合材料在超级电容器、电化学分析与电池及传感器等方面的应用研究进展，并根据PANI和CNTs性能特点，对复合材料的应用和发展进行展望。

Abstract

As one of the most widely studied conductive polymer

Polyaniline (PANI) has high conductivity and good redox property. But its conjugated delocalization structure make it difficult to dissolve in the organic solvent and the conductivity will become poor under neutral and alkaline environment

which restrict its application. Carbon nanotubes (CNTs) have been frequently applied with excellent electrical

thermal properties

optical properties and unique mechanical properties. The combination of CNTs and PANI will overcome the defects of PANI itself by utilizing the synergistic effect of the two

which effectively improves its capacity and cyclical stability. The preparation processes of polyaniline/carbon nanotube composites using chemical oxidation polymerization

electrochemical polymerization and etc were summarized. Applications of the composites in supercapacitor

electrochemical analysis

batteries

sensors and etc were introduced particularly. The future applications and development in PANI composites were outlooked according to the properties of PANI and CNTs.

关键词

聚苯胺碳纳米管研究进展

Keywords

PolyanilineCarbon nanotubeResearch progress

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