Research Progress on Fabrication Methods for Three-Dimensional Graphene-Polymer Composites

Li-qiang ZHANG; Qing-ran DING; Bao-yi HAO; Li-xin WU

doi:10.14028/j.cnki.1003-3726.2018.08.014

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Research Progress on Fabrication Methods for Three-Dimensional Graphene-Polymer Composites

更新时间：2022-09-05

- Research Progress on Fabrication Methods for Three-Dimensional Graphene-Polymer Composites
- Polymer Bulletin Vol. 31, Issue 8, Pages: 75-80(2018)
- 作者机构：
  
  1.中国科学院大学，北京　100049
  2.中国科学院福建物质结构研究所，福州　350000
  3.中国科学院山西煤炭化学研究所，太原　030001
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2018.08.014
  CLC：
- Published：20 August 2018，
  
  Received：03 November 2017，
  
  Revised：21 June 2018，
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Li-qiang ZHANG, Qing-ran DING, Bao-yi HAO, Li-xin WU. Research Progress on Fabrication Methods for Three-Dimensional Graphene-Polymer Composites. [J]. Polymer Bulletin 31(8):75-80(2018)
DOI：

Li-qiang ZHANG, Qing-ran DING, Bao-yi HAO, Li-xin WU. Research Progress on Fabrication Methods for Three-Dimensional Graphene-Polymer Composites. [J]. Polymer Bulletin 31(8):75-80(2018) DOI： 10.14028/j.cnki.1003-3726.2018.08.014.

摘要

石墨烯是一种具有蜂窝状结构的二维纳米碳材料，具有高的比表面积、优异的导电／热性和理想的机械强度，因而被广泛用作聚合物基复合材料的增强填料。将二维石墨烯片构筑成三维石墨烯，既能充分发挥二维石墨烯片的性质，又能具备三维材料的特性。聚合物填充三维石墨烯制备的实心三维石墨烯-聚合物复合材料（Three-Dimensional Graphene-Polymer Composites，3DGPCs) ，可实现石墨烯在基体中的均匀分散，制备具有优异力学性能的导电、导热复合材料。以石墨烯三维网络为骨架制备的多孔3DGPCs具有高孔隙率、大比表面积和高电子传输能力等特性，可广泛应用于能量存储、环境保护、传感、电磁屏蔽和油污清理等领域。本文综述了 3DGPCs的制备方法，并评述了制备3DGPCs所面临的挑战及发展前景。

Abstract

Graphene

a 2D honeycomb-like nanocarbon material with high specific surface area

excellent electrical/ thermal conductivity and ideal mechanical properties

is emerging as a desirable reinforced filler for the fabrication of polymer-based composites. Three-dimensional graphene-polymer composites (3DGPCs) can not only fully utilize the exceptional properties of two-dimensional graphene nanosheet

but also desirably impart characteristics of 3D porous material. Solid 3DGPCs fabricated by backfilling polymer into three-dimensional graphene network have the ability to achieve uniform dispersion in polymeric matrix

thus significantly improving its mechanical

electrical and thermal properties. Porous 3DGPCs based on three dimensional graphene framework is characteristic of high porosity

large surface area and outstanding electrical conduction ability

holding significant potential applications in energy storage

environmental protection

sensor

electromagnetic interference shielding and oil pollution clean

and so forth. In this paper

fabrication methods for 3DGPCs are reviewed

and a brief perspective on the challenges and future opportunities is concluded.

关键词

三维石墨烯聚合物复合材料制备方法

Keywords

Three-dimensional graphenePolymerCompositesFabrication methods

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