Preparation and Characterization of Poly(L-lactide-co-<italic style="font-style: italic">ε</italic>- caprolactone)

Wei ZHANG; Hong-yuan LI; Li-qun YANG; Ying JIN; Dong-xu YI

doi:10.14028/j.cnki.1003-3726.2018.10.004

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Preparation and Characterization of Poly(L-lactide-co-ε- caprolactone)

更新时间：2022-09-05

- Preparation and Characterization of Poly(L-lactide-co-ε- caprolactone)
- Polymer Bulletin Vol. 31, Issue 10, Pages: 37-41(2018)
- 作者机构：
  
  1.辽宁省计划生育科学研究院，国家卫生和计划生育委员会生殖健康与遗传医学重点实验室，沈阳　110031
  2.中国医科大学附属第四医院，沈阳　110031
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2018.10.004
  CLC：
- Published：20 October 2018，
  
  Received：20 March 2018，
  
  Revised：10 July 2018，
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Wei ZHANG, Hong-yuan LI, Li-qun YANG, Ying JIN, Dong-xu YI. Preparation and Characterization of Poly(L-lactide-co-ε- caprolactone). [J]. Polymer Bulletin 31(10):37-41(2018)
DOI：

Wei ZHANG, Hong-yuan LI, Li-qun YANG, Ying JIN, Dong-xu YI. Preparation and Characterization of Poly(L-lactide-co-ε- caprolactone). [J]. Polymer Bulletin 31(10):37-41(2018) DOI： 10.14028/j.cnki.1003-3726.2018.10.004.

摘要

以低毒辛酸亚锡为催化剂，

-丙交酯和

-己内酯为原料，聚四氟乙烯管为模具，采用一步法开环聚合成型三种无规共聚物P（LLA-CL）棒。利用核磁共振氢谱、红外光谱、差示扫描量热仪和热重分析仪对共聚物棒进行性能分析，利用扫描电镜观察共聚物棒脆断断面的微观形态。结果表明：合成的聚合物为无规共聚物，共聚比例接近投料比；改变

-己内酯的含量可改变共聚物的结晶形态，也可调节共聚物力学性能。此结果为共聚物P（LLA-CL）在医疗器械方面的应用具有一定价值。

Abstract

Three kinds of random copolymer P(LLA-CL) rods were prepared by one-step ring-opening polymerizing molding from the L-lactide and

-caprolactone with low toxicity stannous octoate as catalyst

and PTFE tubes were used as mould. The properties of copolymer rods were analyzed by

H nuclear magnetic resonance

infrared spectrum

differential scanning calorimeter and thermogravimetric analyzer. Scanning electron microscopy was used to observe the micromorphology of the brittle fracture section of the copolymer rods. The results showed that the synthesized polymers were random copolymers

the copolymerization ratio was close to the feed ratio. Changing the content of

-caprolactone could change the crystalline morphology and adjust the mechanical properties of copolymer. The results are valuable for the application of copolymer P(LLA-CL) in medical devices.

关键词

L-丙交酯ε-己内酯P（LLA-CL）输卵管栓塞性能微观形态

Keywords

L-lactideε-caprolactoneP(LLA-CL)Fallopian tube embolizationPropertiesMicromorphology

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Key Laboratory of Tropical Island Resources Advanced Materials,Ministry of Education, Hainan University

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Department of Polymer Materials, Shanghai University

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Preparation and Characterization of Poly(L-lactide-co-ε- caprolactone)

DOI：10.14028/j.cnki.1003-3726.2018.10.004

摘要

Abstract

关键词

Keywords

references