Research Progress of Hyperbranched Silicon Functional Polymer

Zhi-peng LIU; Jun WU; Zheng-guang SUN; Long-hai WANG; Yu-hong ZHANG

doi:10.14028/j.cnki.1003-3726.2019.05.004

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Research Progress of Hyperbranched Silicon Functional Polymer

更新时间：2022-09-02

- Research Progress of Hyperbranched Silicon Functional Polymer
- Polymer Bulletin Vol. 32, Issue 5, Pages: 23-36(2019)
- 作者机构：
  
  功能材料绿色制备与应用教育部重点实验室，湖北大学材料科学与工程学院，武汉 430062
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2019.05.004
  CLC：
- Published：20 May 2019，
  
  Received：14 September 2018，
  
  Revised：16 February 2019，
扫描看全文
Zhi-peng LIU, Jun WU, Zheng-guang SUN, Long-hai WANG, Yu-hong ZHANG. Research Progress of Hyperbranched Silicon Functional Polymer. [J]. Polymer Bulletin 32(5):23-36(2019)
DOI：

Zhi-peng LIU, Jun WU, Zheng-guang SUN, Long-hai WANG, Yu-hong ZHANG. Research Progress of Hyperbranched Silicon Functional Polymer. [J]. Polymer Bulletin 32(5):23-36(2019) DOI： 10.14028/j.cnki.1003-3726.2019.05.004.

摘要

超支化有机硅一般具有三维结构，分子与分子之间基本不出现链缠结，使其宏观上表现出低粘度、高反应活性、高溶解性等特性。超支化有机硅因制备方法较简单、成本较低、可规模化生产、易于功能化等优点，在功能高分子材料领域有广阔的应用前景。本文综述了超支化有机硅功能高分子的制备，包括超支化聚硅氧烷、聚碳硅烷、聚硅烷以及含杂原子的超支化有机硅的制备，重点总结了超支化有机硅功能高分子在催化剂载体、生物医药材料、耐热材料、陶瓷前驱体以及光电材料方面的应用，并对超支化有机硅功能高分子未来的发展作出了展望。

Abstract

Hyperbranched organic silicon usually have three dimensional structure and no chain entanglement between molecules and molecules

making them exhibit low viscosity

high reactivity

high solubility and so on. Hyperbranched organic silicon has wide-range prospect in the field of functional polymers due to its simple procedures

lower cost as well as scale production and functionalization. The paper reviews the preparation of the functional polymer of hyperbranched organic silicon including the hyperbranched polysiloxane

polycarbosilane

polysilane as well as the organic silicon of hyperbranched with heteroatom. It concludes the implementation of the functional polymer of hyperbranched organic silicon in areas

such as the catalyst carrier

biomedical materials

heat-resistant material

ceramic precursor and photoelectric material

and provides an outlook of the future of the functional polymer of hyperbranched organic silicon.

关键词

超支化有机硅功能高分子聚硅氧烷聚碳硅烷聚硅烷

Keywords

HyperbranchedOrganic siliconFunctional polymerPolysiloxanePolycarbosilanePolysilane

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