Research Progress on Application of ARGET-ATRP Technology

Wei LI; Jie WU; Lan-juan WU; Zheng-qiao ZHANG; Yu-hao LU

doi:10.14028/j.cnki.1003-3726.2020.07.002

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Research Progress on Application of ARGET-ATRP Technology

更新时间：2022-08-31

- Research Progress on Application of ARGET-ATRP Technology
- Polymer Bulletin Vol. 33, Issue 7, Pages: 18-25(2020)
- 作者机构：
  
  1.安徽工程大学纺织面料安徽省重点实验室,芜湖 241000
  2.合肥塞夫特淀粉有限公司,合肥 230000
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2020.07.002
  CLC：
- Published：20 July 2020，
  
  Received：04 August 2019，
  
  Revised：05 January 2020，
扫描看全文
Wei LI, Jie WU, Lan-juan WU, Zheng-qiao ZHANG, Yu-hao LU. Research Progress on Application of ARGET-ATRP Technology. [J]. Polymer Bulletin 33(7):18-25(2020)
DOI：

Wei LI, Jie WU, Lan-juan WU, Zheng-qiao ZHANG, Yu-hao LU. Research Progress on Application of ARGET-ATRP Technology. [J]. Polymer Bulletin 33(7):18-25(2020) DOI： 10.14028/j.cnki.1003-3726.2020.07.002.

摘要

电子转移活化再生催化剂原子转移自由基聚合(ARGET-ATRP)作为活性/可控自由基聚合技术的一种

克服了传统ATRP反应的引发剂毒性较大

催化剂用量大

反应需在无氧条件下进行等缺点

利用此技术可合成具有特殊结构和性能的高分子聚合物

已成为高分子领域的研究热点且应用前景广阔。本文阐述了ARGET-ATRP技术的反应机理

综述了ARGET-ATRP技术在制备高聚物(如星型聚合物、嵌段聚合物、超支化聚合物等)和材料改性(如无机材料改性和有机材料表面改性)方面的应用研究进展

并展望了ARGET-ATRP在纺织浆纱领域中具有潜在的应用前景。

Abstract

Activators regenerated by electron transfer for atom transfer radical polymerization (ARGET-ATRP) as a kind of active/controllable radical polymerization technology

can overcome the shortcomings of conventional ATRP reaction such as high toxicity of initiator

high usage of catalyst and demand of anaerobic conditions. The ARGET-ATRP technology can be applied for synthesizing the polymers with special structures and properties

and has become a research hot topic in the polymer field with a wide application prospect. In this paper

the reaction mechanism of ARGET-ATRP technology was described. The research progress on the application of ARGET-ATRP technology in preparation of polymer (such as star polymer

block polymer

hyperbranched polymer

etc.) and material modification (such as inorganic material modification and surface modification of organic material) was reviewed

and the potential application prospected of ARGET-ATRP in the field of textile sizing was prospected.

关键词

ARGET-ATRP技术反应机理高聚物无机材料改性有机材料表面改性

Keywords

ARGET-ATRP technologyReaction mechanismPolymerInorganic material modificationSurface modification of organic material

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