Synthesis of Poly(<italic style="font-style: italic">p</italic>-benzoquinone diimide-naphthalene) and Poly(<italic style="font-style: italic">p</italic>-benzoquinone diimide-anthracene) and Performance Research

Ka-der AYGUL; Nurul-la ISMAYIL

doi:10.14028/j.cnki.1003-3726.2021.03.007

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Synthesis of Poly(p-benzoquinone diimide-naphthalene) and Poly(p-benzoquinone diimide-anthracene) and Performance Research

更新时间：2022-08-30

- Synthesis of Poly(p-benzoquinone diimide-naphthalene) and Poly(p-benzoquinone diimide-anthracene) and Performance Research
- Polymer Bulletin Vol. 34, Issue 3, Pages: 45-50(2021)
- 作者机构：
  
  新疆大学化工学院,乌鲁木齐 830046
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2021.03.007
  CLC：
- Published：20 March 2021，
  
  Received：16 December 2019，
  
  Revised：18 December 2020，
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Ka-der AYGUL, Nurul-la ISMAYIL. Synthesis of Poly(p-benzoquinone diimide-naphthalene) and Poly(p-benzoquinone diimide-anthracene) and Performance Research. [J]. Polymer Bulletin 34(3):45-50(2021)
DOI：

Ka-der AYGUL, Nurul-la ISMAYIL. Synthesis of Poly(p-benzoquinone diimide-naphthalene) and Poly(p-benzoquinone diimide-anthracene) and Performance Research. [J]. Polymer Bulletin 34(3):45-50(2021) DOI： 10.14028/j.cnki.1003-3726.2021.03.007.

摘要

采用镍(Ⅱ)催化剂1

3-双(二苯基膦)丙烷二氯化镍(Ⅱ)的催化下

制备出了聚(对苯醌二亚胺-萘)和聚(对苯醌二亚胺-蒽)两种新型共聚物并及其进行了性能对比研究。采用FT-IR

UV-Vis

XRD和TG等方法对其进行表征。结果表明:合成的两种共聚物在三氟乙酸(TFA)溶液中

紫外可见吸收光谱的吸收波长分别为524nm

293nm 和502nm

295nm 有吸收峰

聚合物P1相比P2红移了22nm

P1具有较高的共轭程度;循环伏安表明P1的峰面积比P2大

峰面积越大共聚物的比电容越大;碘掺杂会提高共聚物的电话活性。本文对共聚物电化学研究方面有很高应用潜力和参考价值。

Abstract

Using nickel (Ⅱ) catalyst 1

3-bis(diphenyl phosphine)propane nickel dichloride (Ⅱ)

poly(p-benzoquinone diamine-naphthalene) and poly(p-benzoquinone diamine) were prepared. Imine-anthracene) two new copolymers and their performance comparison studies. It was characterized by FT-IR

UV-Vis

XRD and TG methods. The results show that: the two copolymers synthesized in the trifluoroacetic acid (TFA) solution

the absorption wavelengths of the ultraviolet-visible absorption spectrum are 524nm

293nm and 502nm

respectively. There are absorption peaks at 295nm. The red shift of polymer P1 is 22nm compared with P2. P1 has a higher degree of conjugation; cyclic voltammetry shows that the peak area of P1 is larger than that of P2

and the larger the peak area

the greater the specific capacitance of the copolymer; iodine doping will increase the telephone activity of the copolymer. This article has high application potential and reference value for the electrochemical research of copolymers.

关键词

对苯醌二亚胺Ni(Ⅱ)催化剂萘蒽

Keywords

p-Benzoquinone diamineNi(Ⅱ) catalystNaphthaleneAnthracene

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Synthesis of Poly(p-benzoquinone diimide-naphthalene) and Poly(p-benzoquinone diimide-anthracene) and Performance Research

DOI：10.14028/j.cnki.1003-3726.2021.03.007

摘要

Abstract

关键词

Keywords

references