Progress in Synthesis of Polyester Polymers Based on Lactide Derivatives

Yuan-yuan PEI; Tao WEN

doi:10.14028/j.cnki.1003-3726.2022.01.005

您当前的位置：

首页 >

文章列表页 >

Progress in Synthesis of Polyester Polymers Based on Lactide Derivatives

更新时间：2022-09-09

- Progress in Synthesis of Polyester Polymers Based on Lactide Derivatives
- Polymer Bulletin Vol. 35, Issue 1, Pages: 32-45(2022)
- 作者机构：
  
  华南理工大学分子科学与工程学院,华南软物质科学与技术高等研究院,广东省功能与智能杂化材料与器件重点实验室,广州 510640
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2022.01.005
  CLC：
- Published：20 January 2022，
  
  Received：19 November 2020，
  
  Revised：02 August 2021，
扫描看全文
Yuan-yuan PEI, Tao WEN. Progress in Synthesis of Polyester Polymers Based on Lactide Derivatives. [J]. Polymer Bulletin 35(1):32-45(2022)
DOI：

Yuan-yuan PEI, Tao WEN. Progress in Synthesis of Polyester Polymers Based on Lactide Derivatives. [J]. Polymer Bulletin 35(1):32-45(2022) DOI： 10.14028/j.cnki.1003-3726.2022.01.005.

摘要

聚乳酸具有良好的生物相容性和生物可降解性

在众多领域有着广泛的应用。但是

聚乳酸自身的耐热性较差

且化学改性较为困难

难以进行功能化。近年来

研究者围绕着聚乳酸的化学改性及功能化开展了大量研究。特别地

通过对聚乳酸的合成单体———丙交酯的设计和修饰

可以得到具有不同结构的内酯类单体

进而通过开环聚合得到具有特定侧链结构的“类聚乳酸”。这类高分子在保留了聚乳酸可生物降解性和生物相容性的同时

往往具有更加优异的耐热性能以及可拓展的功能性。本综述介绍了两类制备“类聚乳酸”的方法:直接化学改性及丙交酯衍生物开环聚合

并对已有的“类聚乳酸”材料的合成及应用进行了梳理。

Abstract

Due to its good biocompatibility and biodegradability

polylactide (PLA) has a wide range of applications in many fields. However

the application of PLA is limited by its poor heat resistance

and it is challenging to be chemically modified nor functionalized. In recent years

lots of studies on the chemical modification and functionalization of PLA were carried out. In particular

synthesis and polymerization of lactones with different structures were developed

which providing an efficient approach to develop PLA-derived polymers with given side-chain structures by ring-opening polymerization. While retaining the biodegradability and biocompatibility of PLA

these PLA-derived polymers could possess better heat resistance and rich functionality. This review will introduce two methods for preparing PLA-derived polymers: direct chemical modification and ring-opening polymerization of lactones. Also

the application of PLA-derived polymers are summarized.

关键词

聚乳酸丙交酯聚酯化学改性官能团化

Keywords

PolylactideLactidePolyesterChemical modificationFunctionalization

references

更多指标>

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Recent Research Progress in Stereoselective Polymerization of Rac-lactide

Fabrication and Control of PLLA/CA Honeycomb Composite Porous Membrane

Research Progress in Modification of Waste Plastics

Recent Progress on Polylactide with High Melt Strength

The Synthesis of Functional Cyclic Ester Monomers Based on "Click Reaction"and the Properties of Their Polyesters

Related Author

No data

Related Institution

School of Life Science & Technology, Xi’an Jiaotong University

School of Materials and Chemical Engineering, Xi’an Technological University

Fujian Provincial Key laboratory of Eco-Industrial Green Technology, College of Ecological and Resources Engineering, Wuyi University

State Key Laboratory of Polymer Materials Engineering, Polymer Research Institute of Sichuan University, Sichuan Provincial Engineering Laboratory of Plastic/Rubber Complex Processing Technology

College of Polymer Science and Engineering, State Key Laboratory of Polymer Materials Engineering Sichuan University

⁰