Research Progress in Selective Catalytic Dimerization of Ethylene with Nickel Catalysts

Yu-qiang MU; Hong-liang HUO; Yan JIANG; Bu-wei YU; Hong-yu MA

doi:10.14028/j.cnki.1003-3726.2022.05.006

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Research Progress in Selective Catalytic Dimerization of Ethylene with Nickel Catalysts

更新时间：2022-09-09

- Research Progress in Selective Catalytic Dimerization of Ethylene with Nickel Catalysts
- Polymer Bulletin Vol. 35, Issue 5, Pages: 55-59(2022)
- 作者机构：
  
  中国石油天然气股份有限公司大庆化工研究中心,大庆 163714
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2022.05.006
  CLC：
- Published：20 May 2022，
  
  Received：28 July 2021，
  
  Revised：25 October 2021，
扫描看全文
Yu-qiang MU, Hong-liang HUO, Yan JIANG, Bu-wei YU, Hong-yu MA. Research Progress in Selective Catalytic Dimerization of Ethylene with Nickel Catalysts. [J]. Polymer Bulletin 35(5):55-59(2022)
DOI：

Yu-qiang MU, Hong-liang HUO, Yan JIANG, Bu-wei YU, Hong-yu MA. Research Progress in Selective Catalytic Dimerization of Ethylene with Nickel Catalysts. [J]. Polymer Bulletin 35(5):55-59(2022) DOI： 10.14028/j.cnki.1003-3726.2022.05.006.

摘要

1-丁烯和2-丁烯是重要的有机合成原料

可以通过金属催化剂选择性催化乙烯二聚合成丁烯。乙烯选择性二聚合成丁烯的催化剂通常有镍催化体系、钒催化体系、钨催化体系、铁或钴催化体系、钽催化体系以及钛催化体系等。近年来镍系催化剂催化乙烯选择性二聚取得了很大的进展

本论文对近年来镍系催化剂催化乙烯选择性二聚进行了综述。主要概述了[NN]、[NO]、[NP]等均相的镍催化剂

同时也概述了非均相或负载的镍催化剂催化乙烯选择性二聚的研究进展。

Abstract

1-Butene and 2-butene are important raw materials for organic synthesis

which can be selectively catalyzed by metal catalysts to catalyze the dimerization of ethylene into butene. Catalysts for selective dimerization of ethylene to butene usually include nickel catalyst system

vanadium catalyst system

tungsten catalyst system

iron or cobalt catalyst system

tantalum catalyst system and titanium catalyst system. In recent years

nickel-based catalysts have made great progress in the selective dimerization of ethylene. This paper reviews the selective dimerization of ethylene catalyzed by nickel-based catalysts in recent years. It mainly summarizes [NN]

[NO]

[NP] and other homogeneous nickel catalysts

and also summarizes the research progress of heterogeneous or supported nickel catalysts catalyzing the selective dimerization of ethylene.

关键词

1-丁烯2-丁烯乙烯选择性二聚镍系催化剂

Keywords

1-Butene2-ButeneEthyleneSelective dimerizationNickel catalyst

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