LIU Hua-qiao, MA De-long, LI Yun-feng, WANG Chuan-sheng. Study on Vulcanization Kinetics of Silica Filled Compound. [J]. Polymer Bulletin 36(5):643-649(2023)
DOI:
LIU Hua-qiao, MA De-long, LI Yun-feng, WANG Chuan-sheng. Study on Vulcanization Kinetics of Silica Filled Compound. [J]. Polymer Bulletin 36(5):643-649(2023) DOI: 10.14028/j.cnki.1003-3726.2023.05.010.
Study on Vulcanization Kinetics of Silica Filled Compound
The setting of tire curing process depends on the curing parameters of each component
and ultimately determines the curing efficiency
energy consumption and product quality of tires. The accuracy of curing parameters is crucial.The vulcanization crosslinking reaction of rubber products conforms to the first-order kinetic equation. The vulcanization reaction of silica filled rubber is not only the sulfur accelerator crosslinking reaction
but also the physical effect of polar agglomeration of silica. The vulcanization behavior cannot be accurately characterized by directly using the data measured by the rheometer.Based on this
the vulcanization behavior of silica filled master batch (without sulfur) was studied in this paper
indicating that the agglomeration of silica interfered with the torque increase during vulcanization test. Finally
the vulcanization curves of silica filled final rubber and master rubber were "subtracted" according to the "time torque" data
and the curves that can more accurately characterize the vulcanization dynamic behavior were redrawn to better guide the setting of tire vulcanization process.