LIU Ze-xin, LIU Hu, YUAN Ming, ZHAO Bai-jin, LIU Yan-guo, YANG Shu-guang. Transamidation of Polyamide Melt Blending Process. [J]. Polymer Bulletin 36(6):669-687(2023)
DOI:
LIU Ze-xin, LIU Hu, YUAN Ming, ZHAO Bai-jin, LIU Yan-guo, YANG Shu-guang. Transamidation of Polyamide Melt Blending Process. [J]. Polymer Bulletin 36(6):669-687(2023) DOI: 10.14028/j.cnki.1003-3726.2023.06.002.
Polyamide (PA) is one of the most widely used engineering-plastics. Different typs of PAs have distinct variations in properties
such as processability
heat-resistance and water adsorption. In order to further improve the comprehensive performance of polyamide materials and reduce costs
melt blending is the most basic method. Under the influence of high temperature and mechanical force field during melt blending
the amide bond is opened and rearranged to undergo an exchange reaction
and the homopolymer is first converted into a copolymer
resulting in changes in the polymer chain structure
crystalline structure and higher-level aggregation structure. The strength
modulus
toughness
thermal deformation
moisture absorption and other properties of the material change to meet the needs of specific application scenarios. This paper summarizes the transamidation of PA blending
including characterization techniques
the available research systems
accelerating
and restriction process. The transamidation of polyamide with other polymers
such as polyester and polyurethane is also briefly discussed. Finally
the design and preparation of polymer materials based on transamidation and dynamic chemistry principle are prospected.
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江苏博云塑业股份有限公司,张家港
纤维材料改性国家重点实验室,东华大学先进低维材料中心,东华大学材料科学与工程学院,松江
Shandong Provincial Key Laboratory of Olefin Catalysis and Polymerization, Key Laboratory of Rubber-Plastics (Ministry of Education), School of Polymer Science and Engineering, Qingdao University of Science and Technology
Beijing University of Chemical Technology
Key Laboratory of Rubber-Plastics,Ministry of Education/Shandong Provincial Key Laboratory of Rubber-plastics,School of Polymer Science and Engineering,Qingdao University of Science and Technology