SONG Yi-hu. Differences Between Networks of Gaussian Chains and Rubber Vulcanizates. [J]. Polymer Bulletin 36(10):1366-1380(2023)
DOI:
SONG Yi-hu. Differences Between Networks of Gaussian Chains and Rubber Vulcanizates. [J]. Polymer Bulletin 36(10):1366-1380(2023) DOI: 10.14028/j.cnki.1003-3726.2023.10.014.
Differences Between Networks of Gaussian Chains and Rubber Vulcanizates
"rubber elasticity" is an important chapter linking the statistics of conformation of long-chain macromolecules and mechanical behaviors of polymer materials. In the current textbooks
rubber elasticity is introduced following the Rehner-Flory "four chains" model to present conformational entropy and contraction force of network of Gaussian chains by formulating entropy of single Gaussian chain in the first step and summing entropies of all Gaussian chains under assumption of affine deformation under constant volume in the second step. In general
the approximations and academic disputes involving the modellization are not referred to. Under the prevailing teaching practice
some students may believe that vulcanizates behave like network of Gaussian chains and some technicians may try to develop the so-called reversibly deformable flexible electronics by designing the so-called ideal network structure. Here reviewed are the modellization of network of Gaussian chains and the involved theories
approximations and disputes
aiming to point out that the network of Gaussian chains is only a model concepted under many assumptions and that the model cannot be used to describe the structure of vulcanizates.
关键词
橡胶弹性Gaussian链网络链节位移长度构象熵
Keywords
Rubber elasticityNetwork of Gaussian chainsNetwork chainsDisplacement lengthConformational entropy
Deduction of GPC Calibration Equation from Diffusion Separation Model and Conformational Entropy Model
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高分子合成与功能构造教育部重点实验室,山西浙大新材料与化工研究院, 浙江大学高分子科学与工程学系
Department of Polymer Science and Engineering, College of Chemistry and Molecular Engineering, Key Laboratory of Polymer Chemistry and Physics of Ministry of Education,Peking University