摘要:The state of research of hyperbranched polymers,which is very brisk recently in the domain of polymer chemistry,is introduced.It is pointed out that the hyperbranched polymers can be preparated by the polycondensation of the monomers with ABx funcationality or by selfcondension vinyl polymerization of the monomers with the general structure A = B - C*.At present the degree of branching and the molecular weight of hyperbranched polymers are characterized mainly by nuclar magetic resonance spectroscopy (NMR) and gel permeation chromatography (GPC). But there is a limit in the practical application of these mothods.
关键词:Hyperbranched polymer;Synthesis;Characterization;Branched structure;Degree of branching
摘要:Development in biodegradable polyesters synthesized by chemical methods was reviewed in this paper.These methods include condensation polymerization of aliphatic diacids with aliphatic glycol,ring-opening polymerization of glycolide,lactide,lactones,and substituted lactones with carboxy or amino pendant groups.
摘要:The review with 114 references discussed the resarch advances of the crosslinkable acrylate latex using for catings in preparation,relationships of compositions and structures with properties of latexes and films,and the crosslinking mechanisms.
摘要:We review the application of block copolymers in emulsion polymevization and dispersion polymerization.The effect on polymerization system of copolymer composition、 molecular weight and amphiphilic ratio、Stabilizer concentration、formation of micelle has been discussed.
摘要:In this paper,a general review with 68refs.on the progress of polyNIPAAm series polymers is pressented.The methods of syntheses,characteristics,and applications of polyNIPAAm linear polymers, hydrogels and grafting polymers are described in detail, respectively.
摘要:In this paper,the theoretical studies of the hydrodynamic chromatography(HDC) and the three types of HDC:microcapillary HDC,capillary HDC and packed-column HDC are reviewed.Then,the HDC’s applications to the analysis and separation of colloidal particles and macromolueules are also introduced.
摘要:In this paper,the characterization method of pore structure parameters including specific surface area,pore volume,average pore diameter and the distribution of pore size for macroporous resins have been introduced. The different characterized method for these parameters have been analyzed and compared.The characterized method of macroporous resins and the problems need to be pay attention during the course of characterization have been discussed.The advantages and disadvantages of the different characterized method have been summarized.
摘要:Molecular imprinting is a new research method developed in recent several decades.It counts mostly on the high selectivity that the special constructions in the imprinted polymer showed to the imprint molecule that is used.Recently,impressive progress has been achieved in the areas as chiral sepration,catalysis,sensor.
摘要:A review was given on research developments of modification methods、reaction mechanisms and modification mechanisms of epoxy modified by polysiloxane.
摘要:This paper discusses the usage of chitosan and its derivative in the field of cosmetics with regard to their character and speciality that is fit for cosmetics.
摘要:Polymer materials used in electrochemical biosensors were reviewed with 54 references.These materials include polymeric mediators,inert polymer membrane,materials used as supports for the immobilization of enzymes and materials generated electrochemically.Further more,it is pointed out that the improvement of the biosensor will depend on the development of polymeric materials.
关键词:Sensor;Polymeric materials;Mediators;Immobilization of enzyme
摘要:In this paper,the development and mechanism of phase morphology of multiphase polymer during melting were reviewed.The on-line analysis methods of multi-phase polymer blending were summarized.At the end,introducing a new on-line analysis system-Dynamic Laser Back Scattering System.
摘要:Achievements,including main results and their academic level,of 6Key Projects on Organic Polymeric Materials Granted by Department of Engineering and Material Science of NSFC in1992-1995are introduced.The policy and management procedures of NSFC on the key projects is explained.An outline of Key Projects Granted in the1996-1999is given.