摘要:In this review our progress on high heat-resistant silicone rubbers was expounded. The effect on improving the thermal stability of silicone rubbers by introducing Si-N bond into polysiloxane main-chain、using Si-N compounds as additives and using silazane as crosslinking agent was discussed. The mechanism was proposed that the thermal stability of silicone rubbers was improved by removing silanol and water which could lead to main-chain degradation. High heat-resistant polysiloxane elastomers were synthesized by living polymerization.
摘要:Poled polymeric materials have been extensively studied because of their potential application in integrated opto-electonics. In this article, based on a brief introduction to the electro- optic modulator and its materials, recent progress of poled polymeric electro-optic materials was reviewed, and the emphasis was placed on the design and synthesis of the chromophores and polymers, then the future directions of this type of materials were also discussed.
摘要:The research achievement and development of fullerene in polymer chemistry including the synthesis of fullerene-containing polymer, the formation of charge-transfer complex of fullerene with polymer and catalyst in polymerization were reviewed.
摘要:The research background of the graded-index polymer optical fiber (GI POF) was described. Recent advance on GI POF in the world was reviewed in this paper. The preparation of GI POF, the mechanism of the graded index formation, as well as the research of functional GI POF were introduced.
摘要:For theirs unique properties in some aspects, derivatives of polyethylene glycol (PEG) have proven valuable in a variety of diverse chemical and biological endeavors. This article describes the recent advances on the study of synthesis of polyethylene glycol derivatives.
摘要:One of the most important breakthroughs in cationic polymerization in1980s is perhaps the discovery of living cationic polymerization. By now, the scope of living cationic polymerization in terms of initiating systems, monomers and synthetic applications has rapidlly been expanded. In this review, we focus on the progress in synthesis of new block polymers and multiblock polymers by living cationic polymerization.
摘要:The development of polyurethane interpenetrating polymer networks used as vibration damping materials were reviewed in this paper. The damping properties and its influence factor of PU/EP IPN and PU/vinyl-polymer IPN were discussed. The advantages and disadvantages of different type of PU IPN were compared. Finally, the authors forwarded some new possibly research direct.
摘要:In this paper, the relationship of molecular design and thermal properties of liquid crystalline ionomer was summarized. Usually, the existence of ionic groups in the terminal of main-chain liquid crystalline ionomers almost did not influence the Tg and Tm of the polymers. Tg and Tm decreased with increasing ionic concentration in the main-chain liquid crystalline ionomers. The influence of ions in the side-chain liquid crystalline ionomers depended on the flexibility of main chain and the ionic position in the polymer chain et al. Generally, The Ti decreased with increasing ionic concentration in the chain for both main-chain and side-chain liquid crystalline ionomers.
摘要:Modification of non-polar polyolefins with polar monomers is a good way to expand the application of polyolefins. In this paper, the methods of chemical grafting of polyolefins were reviewed, including solution grafting, melt grafting and solid state grafting. Some properties of grafted polyolefin, such as thermal behavior, crystal structure, and adhesive property were also discussed.
摘要:An overview was given in synthesis, degradation and application of polylactic acid in internal fixation materials. The mechanisms and factors of polymerization and degradation were discussed. The developments and future treads in this area also depicted.
摘要:This paper introduced a new direct liquefaction way of co-liquefaction of coal-plastic mixtures, The research about the co-liquefaction of coal-plastic mixtures was a new development technique in the coal conversion fields. It’s characteristic is that the waste plastic mixtures were used as main supply of hydrogen material. This paper also presented the resent progress on the technique especially the main effecting factors about the result of coal-plastic mixtures co-liquefaction faction further important research subjects was indicated.
关键词:Co-processing;Waste plastics;Direct-liquefaction of coal;Add hydrogen
摘要:It provides basic information on the project application and proposal evaluation from 1997 to 1999 fiscal year of Division of Polymeric Materials of NSFC. The hot topics have been analyzed. The issues should pay much attention during application have been discussed. The encouraging areas for grant and the guidance for application have been briefly introduced. .
关键词:National natural science foundation of China;Organic polymeric materials;Application and evaluation of project