摘要:The macromolecular chain in single-chain condensed state is of looped chain conformation because of van der Waals attractive interaction between the intra-chain monomer units along the chain. As the attractive interaction between intra-chain monomer units in multi-chain condensed state is shielded by the attractive interaction between inter-chain monomer units of the neighboring chains in inter-penetration, the molecular chain in multi-chain condensed state is of Gauss conformation. The methods of preparing samples of single-chain condensed state, the experimental observations of single-chain single crystals, single-chain glasses and the stretching of solvent swollen single-chain rubbery state are briefly discussed. The process of transition from a single-chain condensed state to a multi-chain condensed state, that is the process of polymer coil inter-penetration, is a problem lacking basic understanding at the present time.
摘要:The physical origin of concentration-dependence of viscosity of dilute polymer solution was reviewed. The shortcoming of conventional theories was analyzed, then the advantage of cluster theory proposed recently was introduced.
摘要:Owing to the high performance properties and special functional properties, polymer/ clay nanocomposites become of greater general interest. From experiments it has evidenced that organoclays are easily intercalated by epoxy resins, and exfoliated during the curing process to form nanocomposites. In this paper, the research achievement of formation mechanism, mechanical properties and morphology as well as the applications of epoxy/nanocomeposites were reviewed.
摘要:Based on mathematics methods used by theories, this paper introduce the progress on the theory of free radical crosslinking copolymerization and evaluate these theories, which include statistical theories, kinetics theory and computer simulation.
摘要:The miscibility and liquid-liquid phase separation of polyethylene blends have been reviewed. The different results and opinions between two main research groups studying on liquid-liquid phase separation of polyethylene blends are discussed.
摘要:Organic and polymer thin film electroluminescent devices have become a fascinating field in recent years. The multifunctional electroluminescent materials with bipolar carrier transport abilities and high luminescent quantum yields are desired. This article provides a review of the main types, functions and synthetic strategies of these materials.
摘要:New development of single-composition rare earth catalysts for α-olefin polymerization, olefin/olefin copolymerization, olefin/styrene copolymerization, and block polymerization of α-olefin and polar monomers was reviewed.
摘要:The synthesis methods and application in biomedical fields of Poly (ε-caprolactone) homopolymer, copolymer, moreover, the preparation, miscibility of its blends with other polymers have been reviewed in this paper.
摘要:The characteristics of photophysical techniques are described and the progress in the photophysical studies of solid/water interface behaviors of water soluble polymers is reviewed. 32references are presented.
摘要:Fluoropolymer latex may acquire extensively use in coating because of its excellent surface property and weatherability. The paper with 33 references reviewed the preparation, property, applications, and the relationship between the composition and the properties of the fluoro polymer latex.
摘要:A review with the resins matrix of electron beam cured composites, the advantage of electron beam curing process, the issue in this process and the situations of this material at home and abroad.
摘要:The research of multi-monomers melt-grafting onto PP and blending of grafted PP were reviewed. The researching on mechanism of the grafting reaction were summarized, then questions needing further imploring were proposed.
摘要:In this review, the space-grade RTV silicone materials and their outgassing property of heat vacuum are presented. Spare-grade silicone materials were exposed to a vacuum of 1.33 ×10-4 Pa and a temperature of about 125℃ for 24 hours. Total weight loss of the material is less than 1% . The product is treated by liquid-liquid extraction or thermal vacuum to reduce weight loss and vapor condensation under vacuum.
关键词:Silicone Rubber;Space material;Weight loss under thermal vacuum
摘要:Study and development on super absorbent resin was commented, and some problems were pointed out in this article. Which is imporant to study and develope super absorbent resin in our country.
摘要:The student experiments in polymer physics should consider following aspects: speciality of polymer in both structure and properties, home-making the experimental apparatus, reflecting the results of researches on polymer physics, introducing computer technique into experiments.
摘要:There are two kinds of judgement to goodness of the solvent in polymer solutions. One is χ=1/2, from the free energy of Flory-Huggins mean-field calculation and the second Virial coefficient in the expansion of the osmotic pressure for dilution solution; another is χ=0, from the mixing heat. The former occurs in the current textbooks about polymer physics in China, but the author prefers the latter and gives his reasons.