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H2/CO2气体分离用聚苯并咪唑膜的研究进展
Recent Advances in Polybenzimidazole Membranes for H2/CO2 Gas Separation
- 高分子通报 2025年38卷第1期 页码：75-89
- 作者机构：
中石化(北京)化工研究院有限公司，北京 100013
- 作者简介：
*武佳宁，E-mail: wujn.bjhy@sinopec.com
- 基金信息：
DOI：10.14028/j.cnki.1003-3726.2024.24.209
中图分类号：收稿日期：2024-07-19，
录用日期：2024-08-27，
网络出版日期：2024-10-10，
纸质出版日期：2025-01-20
- 稿件说明：
移动端阅览
武佳宁. H2/CO2气体分离用聚苯并咪唑膜的研究进展. 高分子通报, 2025, 38(1), 75–89.
Wu, J. N. Recent advances in polyenzimidazole memranes for H2/CO2 gas separation. Polym. Bull. (in Chinese), 2025, 38(1), 75–89.
武佳宁. H2/CO2气体分离用聚苯并咪唑膜的研究进展. 高分子通报, 2025, 38(1), 75–89. DOI： 10.14028/j.cnki.1003-3726.2024.24.209.
Wu, J. N. Recent advances in polyenzimidazole memranes for H2/CO2 gas separation. Polym. Bull. (in Chinese), 2025, 38(1), 75–89. DOI： 10.14028/j.cnki.1003-3726.2024.24.209.
摘要
H
2
/CO
2
气体分离膜技术具有高能效、维护简单等优点，在高纯氢气生产领域有着巨大的潜力。在众多气体分离膜中，仅有小部分能够耐受氢气生产中的严苛环境，并兼具高氢气渗透性能和高H
2
/CO
2
选择性。聚苯并咪唑(PBI)因有着优异的化学稳定性和热稳定性，以及固有的分子筛分能力，已成为高温H
2
/CO
2
分离膜的备选材料。本文综述了近年来H
2
/CO
2
分离用PBI膜的研究进展，包括PBI交联膜、PBI共混膜、PBI混合基质膜、PBI/超分子复合膜、PBI中空纤维膜和基于PBI的碳分子筛膜，介绍了杂质气体对PBI膜分离性能的影响，分析了各类PBI膜面临的挑战，并对H
2
/CO
2
分离用PBI膜的未来发展进行了展望。
Abstract
H
2
/CO
2
separation membrane technology enjoys the advantages of high energy efficiency and simple maintenance
and has great potential in the field of high purity hydrogen production. Among various gas separation membranes
only a few can withstand the harsh environment in hydrogen production and have high hydrogen permeability as well as high H
2
/CO
2
selectivity. Polybenzimidazole (PBI)
due to its excellent chemical and thermal stability
as well as intrinsic molecular sieving ability
has emerged as a candidate material for fabricating high temperature H
2
/CO
2
separation membranes. In this review
the recent research progress of PBI-based membranes for H
2
/CO
2
separation is reviewed
including PBI-based cross-linked membranes
PBI-based blend membranes
PBI-based mixed matrix membranes
PBI/supramolecular composite membranes
PBI-based hollow fiber membranes and PBI-based carbon molecular sieve membranes. The effect of gas impurity on the separation performance of PBI memb
ranes is introduced. The challenges for various PBI-based H
2
/CO
2
separation membranes are analyzed. Further development prospects are also provided.
关键词
Keywords
references
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