基于二氧化钛无氟超疏水非织造织物制备及其油水分离性能

郝云歌; 周缘; 李解放; 李蓉; 周嫦娥; 栗志广

doi:10.14028/j.cnki.1003-3726.2024.24.212

您当前的位置：

首页 >

文章列表页 >

基于二氧化钛无氟超疏水非织造织物制备及其油水分离性能

研究论文 | 更新时间：2025-01-06

- 基于二氧化钛无氟超疏水非织造织物制备及其油水分离性能
- Preparation of Superhydrophobic Nonwoven Fabric Based on Titanium Dioxide Particles and Its Oil-water Separation Performance
- 高分子通报 2025年38卷第1期页码：100-108
- 作者机构：
  
  1.江南大学纺织科学与工程学院，生态纺织教育部重点实验室，无锡 214122
  2.武汉纺织大学生物质纤维与生态染整湖北省重点实验室，武汉 430200
- 作者简介：
  
  *栗志广，E-mail: lizg@jiangnan.edu.cn
- 基金信息：
  
  中国博士后科学基金(2021M701449);江苏省博士后科研资助计划项目(2021K080A);生物质纤维与生态染整湖北省重点实验室开放基金资助(STRZ202312)
- DOI：10.14028/j.cnki.1003-3726.2024.24.212
  中图分类号：
- 收稿日期：2024-07-23，
  
  录用日期：2024-08-19，
  
  网络出版日期：2024-09-12，
  
  纸质出版日期：2025-01-20
- 稿件说明：
移动端阅览
郝云歌, 周缘, 李解放, 李蓉, 周嫦娥, 栗志广. 基于二氧化钛无氟超疏水非织造织物制备及其油水分离性能. 高分子通报, 2025, 38(1), 100–108.

Hao, Y. G.; Zhou, Y.; Li, J. F.; Li, R.; Zhou, C. E.; Li, Z. G. Preparation of subperhydrophoic nonwoven faric ased on titanium dioxide particles and its oil-water separation performance. Polym. Bull. (in Chinese), 2025, 38(1), 100–108.
郝云歌, 周缘, 李解放, 李蓉, 周嫦娥, 栗志广. 基于二氧化钛无氟超疏水非织造织物制备及其油水分离性能. 高分子通报, 2025, 38(1), 100–108. DOI： 10.14028/j.cnki.1003-3726.2024.24.212.

Hao, Y. G.; Zhou, Y.; Li, J. F.; Li, R.; Zhou, C. E.; Li, Z. G. Preparation of subperhydrophoic nonwoven faric ased on titanium dioxide particles and its oil-water separation performance. Polym. Bull. (in Chinese), 2025, 38(1), 100–108. DOI： 10.14028/j.cnki.1003-3726.2024.24.212.

摘要

采用硅烷偶联剂KH560作为桥梁，十八烷基三氯硅烷(OTS)作为长疏水链结构，对纳米二氧化钛(TiO

)粒子改性制得OTS-KH560/TiO

溶胶，并整理到织物上制备超疏水非织造织物。利用红外光谱、扫描电镜和X射线能谱表征织物表面化学结构、形貌和元素组成，通过测试水接触角表征织物表面疏水性能，分析TiO

/OTS用量比、焙烘温度、焙烘时间等因素对于整理织物水接触角的影响。此外，研究疏水整理织物的耐酸碱性能、防污性能、油水分离性能和力学性能。结果表明：当TiO

/OTS用量比为0.3 g/0.984 g，焙烘温度和焙烘时间分别为170 ℃和80 s时，整理织物表面的接触角可高达166.5°，且整理后的织物具有良好的耐酸碱性能、防污性能、油水分离能力、吸油性能和力学性能。

Abstract

In this paper

OTS-KH560/TiO

sol was obtained by modifying nano-TiO

particles with silane coupling agent KH560 as a bridge and OTS as a long hydrophobic chain structure

and then finished on the fabric to prepare superhydrophobic fabric. The fabric structure

surface morphology and element composition were characterized by Fourier transform infrared spectrometer

scanning electron microscopy and energy dispersive spectrometer

and the hydrophobic properties of the fabric surface were characterized by testing the water contact angle. The effects of TiO

/OTS dosage ratio

baking temperature and baking time on the contact angle of the finished fabric were further analyzed. In addition

the acid-alkali resistance

anti-fouling performance

oil-water separation performance and mechanical property of the hydrophobic finished fabric were studied. The results showed that when the TiO

/OTS dosage ratio was 0.3 g/0.

984 g

the baking temperature was 170 ℃

and the baking time was 80 s

the water contact angle on the surface of the finished fabric could reach 166.5°. The finished fabric had good acid-alkali resistance

anti-fouling performance

oil-water separation ability

oil absorption performance and mechanical property.

关键词

Keywords

references

焦宏璞 , 钱晓明 , 钱幺 , 邹驰 . 医疗用非织造材料的加工技术及发展 . 化工新型材料 , 2019 , 47 ( 12 ), 27 – 31 .

陈苗苗 , 曾泳春 , 卢晨 , 刘力 , 王洪 . 水驻极熔喷非织造材料的制备与性能研究 . 高分子通报 , 2022 , ( 2 ), 48 – 55 .

张红阳 , 任煜 , 徐林 , 吴双全 , 李雅 , 臧传锋 , 徐思峻 , 丁志荣 . 常压等离子体辅助涤纶非织造材料表面拒水拒油整理研究 . 纺织导报 , 2019 , ( 4 ), 26 – 29 .

Pakdel, E. ; Wang, J. F. ; Kashi, S. M. ; Sun, L. ; Wang, X. G . Advances in photocatalytic self-cleaning, superhy-drophobic and electromagnetic interference shielding textile treatments . Adv. Colloid Interface Sci. , 2020 , 277 , 102116 .

Xu, L. H. ; Liu, Y. D. ; Yuan, X. L. ; Wan, J. ; Wang, L. M. ; Pan, H. ; Shen, Y . One-pot preparation of robust, ultraviolet-proof superhydrophobic cotton fabrics for self-cleaning and oil/water separation . Cellulose , 2020 , 27 ( 15 ), 9005 – 9026 .

贺立 , 陈晓丹 , 李铮 , 靳焘 , 陈玉放 , 赖华杰 , 刘瑞 . 基于点击化学反应的织物超疏水改性研究 . 高分子通报 , 2019 , ( 11 ), 26 – 32 .

张炜栋 , 黄旭 . 烷基类SiO 2 改性聚乳酸高效除油非织造布的制备及性能 . 印染 , 2022 , 48 ( 10 ), 55 – 58 .

Xing, L. L. ; Zhou, Q. Q. ; Chen, G. Q. ; Sun, G. ; Xing, T. L . Recent developments in preparation, properties, and applications of superhydrophobic textiles . Text. Res. J. , 2022 , 92 ( 19-20 ), 3857 – 3874 .

何丽红 , 周超 , 李力 , 卢章天 . 硅烷偶联剂表面改性二氧化钛粒子超疏水性能 . 精细化工 , 2014 , 31 ( 9 ), 1061 – 1064 .

徐林 , 任煜 , 张红阳 , 吴双全 , 李雅 , 丁志荣 , 蒋文雯 , 徐思峻 , 臧传锋 . 涤纶织物表面TiO 2 /氟硅烷超疏水层构筑及其性能 . 纺织学报 , 2019 , 40 ( 12 ), 86 – 92 .

Xue, C. H. ; Guo, X. J. ; Ma, J. Z. ; Jia, S. T . Fabric-ation of robust and antifouling superhydrophobic surfaces via surface-initiated atom transfer radical polymerization . ACS Appl. Mater. Interfaces , 2015 , 7 ( 15 ), 8251 – 8259 .

Zhang, L. S. ; Zhou, A. G. ; Sun, B. R. ; Chen, K. S. ; Yu, H. Z . Functional and versatile superhydrophobic coatings via stoichiometric silanization . Nat. Commun. , 2021 , 12 ( 1 ), 982 .

Gui, C. M. ; Ma, H. D. ; Zhang, R. X. ; Liu, Y. L. ; Li, H. L. ; Huang, J. J. ; Li, P . Stability analysis: rational design of a Ag nanoparticle/polymer brush for fabricating Cu coating on a PET surface . Langmuir , 2021 , 37 ( 18 ), 5673 – 5681 .

Zheng, X. C. ; Zhou, X. F. ; Chen, S. Q. ; Wei, F. ; Huang, M. D. ; Hu, T . Terminal amine-based hyperbr-anched polymer-modified metal oxide particles for improving the stability of water-based drilling fluids in interaction with shales . J. Appl. Polym. Sci. , 2024 , 141 ( 11 ), e55102 .

Zhuo, T. ; Chen, Z. ; Xin, B. . Surface modification of PE/PET by two-step method with graphene and silver nanoparticles for enhanced electrical conductivity . J. Ind. Text , 2022 , 51 ( 5S ), 8246S – 8266S .

浏览量

472

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

纳米纤维基膜材料在油水分离中的研究进展

超疏水聚酯纤维织物的制备及其油水分离性能研究

基于点击化学反应的织物超疏水改性研究

疏水防污环氧基织物涂层的性能研究