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山东京博聚烯烃新材料有限公司,滨州 256500
*马丙建,E-mail: Mbj2306079@163.com
收稿日期:2024-09-16,
录用日期:2024-11-14,
网络出版日期:2024-12-03,
纸质出版日期:2025-01-20
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马丙建. 聚丁烯合金材料的创新之路. 高分子通报, 2025, 38(1), 130–136.
Ma, B. J. Innovation of polyutylene alloy materials. Polym. Bull. (in Chinese), 2025, 38(1), 130–136.
马丙建. 聚丁烯合金材料的创新之路. 高分子通报, 2025, 38(1), 130–136. DOI: 10.14028/j.cnki.1003-3726.2024.24.272.
Ma, B. J. Innovation of polyutylene alloy materials. Polym. Bull. (in Chinese), 2025, 38(1), 130–136. DOI: 10.14028/j.cnki.1003-3726.2024.24.272.
我国碳四装置产能约280万吨/年,但国内鲜有国产商业化产品聚丁烯树脂,作为管件材料使用的聚丁烯树脂基本依赖进口。国外也仅有荷兰Basell、日本三井石化等公司能够进行聚丁烯工业化生产。基于技术保护的原因,凡是希望生产聚丁烯管道的中国企业要向国外公司提出申请,经其考察认为生产条件合格后才能够被列入供货名单且进行限量供应,因此聚丁烯价格一直处于高位,同时由于丁烯聚合具有反应慢、放热少、黏度大、易结块等一系列生产难题,其国内产业化举步维艰。2017年在京博石油化工有限公司(以下简称“京博石化”)技术团队的共同努力下,采取对设备进行实用性改造、对工艺指标进行精准化控制、对工序进行精益管理等措施,成功产出了聚丁烯合金这种管材专用料,经检测分析与下游试用,各项指标全部达标。
The production capacity of C4 plant in China is about 2.8 million tons/year
but there is almost no domestic commercial product polybutylene resin in China. Polybutylene resin
used as pipe fitting material
is completely dependent on imports. Only Basell of the Netherlands
Mitsui Petrochemical of Japan and other companies abroad can carry out industrial production of polybutylene. For the reason of technical protection
Chinese enterprises wishing to produce polybutylene pipelines should apply to foreign companies. After investigation
they believe that only when the production conditions are qualified
can they be included in the supply list and limited supply be carried out. Therefore
the price of polybutylene has always been at a high level. At the same time
due to a series of production problems such as slow reaction
less heat release
high viscosity
and easy caking in butylene polymerization
domestic industrialization is difficult. In 2017
with the joint efforts of the technical team of Chambroad Petrochemical Co.
Ltd. (hereinafter referred to as “Chambroad Petrochemical”)
polybutylene alloy
a special material for pipes
was successfully produced. Practical transformation of equipment
accurate control of process indicators
lean management of processes and other measures were taken to make the prouduct meet the all standards of testing
analysis and downstream trial.
洪定一 . 聚丙烯——原理、工艺与技术 . 2版 . 北京 : 中国石化出版社 , 2011 , 451 – 452 .
杜大琳 , 高艺勇 , 郑伟平 , 邵华锋 , 贺爱华 . 聚丙烯/聚(1-丁烯)釜内合金的合成与结构性能 . 高分子材料科学与工程 , 2021 , 37 ( 6 ), 27 – 33 .
杨晓莹 , 白玉洁 , 王秀绘 . 聚丁烯-1技术研究进展 . 化工中间体 , 2012 , ( 6 ), 5 – 8 .
姜柏羽 , 刘振学 , 贺爱华 . 聚烯烃合金的研究进展(Ⅱ): 分级方法、结构调控与性能 . 高分子通报 , 2016 , ( 1 ), 9 – 16 .
吴念 , 代占文 . 聚丁烯(PB)管道的生产和应用 . 塑料制造 , 2008 , ( 12 ), 90 – 95 .
江镇海 . 聚丁烯-1在建材工业上的应用 . 精细与专用化学品 , 1997 , 5 ( 18 ), 9 .
宋琦珍 . 聚丁烯-1的特性及应用 . 塑料技术 , 2002 , ( 2 ), 33 – 36 .
马亚萍 , 李兰阁 , 邵华锋 , 贺爱华 . 聚1-丁烯釜内合金的微观结构及其对性能的影响 . 化学世界 , 2016 , 57 ( 5 ), 261 – 264 .
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