浏览全部资源
扫码关注微信
用于丙烯/丙烷分离的混合基质膜研究进展
Research Progress in Mixed Matrix Membranes for Propylene/Propane Gas Separation
- 高分子通报 2025年38卷第8期 页码：1249-1266
- 作者机构：
1.天津工业大学化学工程与技术学院，天津 300387
2.天津工业大学材料科学与工程学院先进分离膜材料全国重点实验室，天津 300387
- 作者简介：
*辛清萍，E-mail: xinqingping@tiangong.edu.cn
- 基金信息：
DOI：10.14028/j.cnki.1003-3726.2025.25.032
中图分类号：收稿日期：2025-01-25，
录用日期：2025-03-25，
网络出版日期：2025-05-29，
纸质出版日期：2025-08-20
- 稿件说明：
移动端阅览
金慧敏, 麻珂珂, 岳晓彤, 黄威, 辛清萍, 李泓, 张玉忠. 用于丙烯/丙烷分离的混合基质膜研究进展. 高分子通报, 2025, 38(8), 1249–1266.
Jin, H. M.; Ma, K. K.; Yue, X. T.; Huang, W.; Xin, Q. P.; Li, H.; Zhang, Y. Z. Research progress in mixed matrix membranes for propylene/propane gas separation. Polym. Bull. (in Chinese), 2025, 38(8), 1249–1266.
金慧敏, 麻珂珂, 岳晓彤, 黄威, 辛清萍, 李泓, 张玉忠. 用于丙烯/丙烷分离的混合基质膜研究进展. 高分子通报, 2025, 38(8), 1249–1266. DOI： 10.14028/j.cnki.1003-3726.2025.25.032.
Jin, H. M.; Ma, K. K.; Yue, X. T.; Huang, W.; Xin, Q. P.; Li, H.; Zhang, Y. Z. Research progress in mixed matrix membranes for propylene/propane gas separation. Polym. Bull. (in Chinese), 2025, 38(8), 1249–1266. DOI： 10.14028/j.cnki.1003-3726.2025.25.032.
摘要
丙烯(C
3
H
6
)/丙烷(C
3
H
8
)分离是石油化工行业纯化C
3
H
6
的关键步骤。膜分离技术尤其是混合基质膜(MMMs)因其低能耗和高效率而显示出超越传统低温蒸馏的优势。本文综述了MMMs在C
3
H
6
/C
3
H
8
分离中的应用进展，探讨了MMMs的分类、分离原理、制备方法以及气体传递机制，并分析了不同填料对膜性能的影响。最后，分析了MMMs用于更高效的C
3
H
6
/C
3
H
8
分离所面临的挑战和未来发展的方向。
Abstract
The separation of propylene (C
3
H
6
) from propane (C
3
H
8
) is the critical step in the purification of C
3
H
6
within the petrochemical industry. Membrane separation technology
especially mixed matrix membranes (MMMs)
has shown advantages over traditional low-temperature distillation due to its low energy consumption and high efficiency. This paper reviews the application progress of MMMs in the separation of C
3
H
6
/C
3
H
8
and discusses the classification
separation principles
preparation methods
and gas transport mechanisms of MMMs
and analyzes the impact of different fillers on membrane performance. Finally
it analyzes
the challenges faced by applications for the more efficient separation of C
3
H
6
/C
3
H
8
and future development directions.
关键词
Keywords
references
Wang, X. B. ; Zhang, P. X. ; Zhang, Z. Q. ; Yang, L. F. ; Ding, Q. ; Cui, X. L. ; Wang, J. ; Xing, H. B . Efficient separation of propene and propane using anion-pillared metal-organic frameworks . Ind. Eng. Chem. Res. , 2020 , 59 ( 8 ), 3531 – 3537 .
Qi, H. G. ; Lu, M. ; Qi, S. C. ; Li, H. D. ; Li, L. B. ; Cui, X. L. ; Xin, M. D. ; Chang, G. G. ; Tian, G. ; Liu, G. L. ; Liu, X. Q. ; Sun, L. B . Indolo [3, 2-b ] carbazole-based Hyper-Crosslinked organic polymers for adsorptive separation of C 3 H 6 /C 2 H 4 . Sep. Purif. Technol. , 2025 , 353 , 128349 .
Sadegh, F. ; Sadegh, N. ; Wongniramaikul, W. ; Choodum, A . Recent advances in metal-organic frameworks for C 3 H 6 - and C 3 H 8 -selective separation of C 3 H 6 /C 3 H 8 binary natural gas mixtures: A review . Fuel , 2024 , 366 , 131314 .
Zhou, X. Y. ; Miao, G. ; Xu, G. D. ; Luo, J. Z. ; Yang, C. T. ; Xiao, J . Mixed (Ag + , Ca 2+ )-LTA zeolite with suitable pore feature for effective separation of C 3 H 6 /C 3 H 8 . Chem. Eng. J. , 2022 , 450 , 137913 .
张博 , 苗鹏杰 , 郭勤 , 后春静 , 马信 . 丙烯生产工艺的技术现状与进展 . 化工技术与开发 , 2023 , 52 ( 1 ), 45 – 49 .
Ren, Y. X. ; Liang, X. ; Dou, H. Z. ; Ye, C. M. ; Guo, Z. Y. ; Wang, J. Y. ; Pan, Y. C. ; Wu, H. ; Guiver, M. D. ; Jiang, Z. Y . Membrane-based olefin/paraffin separations . Adv. Sci. , 2020 , 7 ( 19 ), 2001398 .
Kunjattu, H. S. ; Kharul, U. K . PPO-ZIF MMMs possessing metal-polymer interactions for propane/propylene separation . J. Membr. Sci. , 2023 , 668 , 121208 .
Hu, P. ; Han, J. ; Zhou, J. ; Wang, H. ; Xiong, C. ; Liu, H. ; Zhou, X. T. ; Wang, Y. Q. ; Ji, H. B . Customized H-bonding acceptor and aperture chemistry within a metal-organic framework for efficient C 3 H 6 /C 3 H 8 separation . Chem. Eng. J. , 2021 , 426 , 131302 .
Chen, Y. W. ; Qiao, Z. W. ; Lv, D. F. ; Duan, C. X. ; Sun, X. J. ; Wu, H. X. ; Shi, R. F. ; Xia, Q. B. ; Li, Z . Efficient adsorptive separation of C 3 H 6 over C 3 H 8 on flexible and thermoresponsive CPL-1 . Chem. Eng. J. , 2017 , 328 , 360 – 367 .
Yoon, J. W. ; Kim, A. R. ; Kim, M. J. ; Yoon, T. U. ; Kim, J. H. ; Bae, Y. S . Low-temperature Cu(Ⅰ) loading on a mesoporous metal-organic framework for adsorptive separation of C 3 H 6 /C 3 H 8 mixtures . Microporous Mesoporous Mater. , 2019 , 279 , 271 – 277 .
Du, S. J. ; Huang, B. L. ; Zhu, L. ; Wu, Y. ; Huang, J. W. ; Li, Z. ; Yu, H. ; Xiao, J . Optimizing gas transport for C 3 H 6 /C 3 H 8 size sieving separation via fine pore engineering of carbon microspheres . Carbon , 2023 , 215 , 118451 .
Liu, L. L. ; Ji, T. T. ; Hu, W. J. ; Sun, Y. W. ; He, Y. F. ; Yan, J. H. ; He, G. H. ; Liu, Y . Epitaxial supercritical fluid processing of ZIF-8 membranes towards efficient C 3 H 6 /C 3 H 8 separation . J. Membr. Sci. , 2023 , 669 , 121300 .
Ji, T. T. ; Yan, J. H. ; He, Y. F. ; Hu, W. J. ; Peng, Y. ; Yang, W. S. ; Liu, Y . Towards ZIF-8 membranes with superb C 3 H 6 /C 3 H 8 separation performances under varying conditions: Necessity of precise temperature control . J. Membr. Sci. , 2023 , 683 , 121776 .
Ding, Y. P. ; Dai, Y. ; Wang, H. H. ; Yang, X. C. ; Yu, M. ; Zheng, W. J. ; Ruan, X. H. ; Xi, Y. ; Liang, H. ; Liu, H. J. ; He, G. H . Synergistic improvement in gas separation performance of MMMs by porogenic action and strong molecular forces of ZIF-93 . Sep. Purif. Technol. , 2024 , 345 , 127214 .
Hua, J. X. ; Li, C. ; Tao, H. X. ; Wang, L. ; Song, E. Y. ; Lian, H. Q. ; Wang, C. Q. ; Jiang, J. L. ; Pan, Y. C. ; Xing, W. H . Improved C 3 H 6 /C 3 H 8 separation performance on ZIF-8 membranes through enhancing PDMS contact-dependent confinement effect . J. Membr. Sci. , 2021 , 636 , 119613 .
岳庆友 , 王宝珠 , 李存磊 , 赵然磊 , 乔雨朋 . 二氧化碳膜分离材料及其性能研究进展 . 精细化工 , 2024 , 41 ( 6 ), 1230 – 1245 .
Amedi, H. R. ; Aghajani, M . Economic estimation of various membranes and distillation for propylene and propane separation . Ind. Eng. Chem. Res. , 2018 , 57 ( 12 ), 4366 – 4376 .
Han, Y. ; Winston Ho, W. S . Polymeric membranes for CO 2 separation and capture . J. Membr. Sci. , 2021 , 628 , 119244 .
Fan, W. D. ; Ying, Y. P. ; Peh, S. B. ; Yuan, H. Y. ; Yang, Z. Q. ; Yuan, Y. D. ; Shi, D. C. ; Yu, X. ; Kang, C. J. ; Zhao, D . Multivariate polycrystalline metal-organic framework membranes for CO 2 /CH 4 separation . J. Am. Chem. Soc. , 2021 , 143 ( 42 ), 17716 – 17723 .
Aroon, M. A. ; Ismail, A. F. ; Matsuura, T. ; Montazer-Rahmati, M. M . Performance studies of mixed matrix membranes for gas separation: A review . Sep. Purif. Technol. , 2010 , 75 ( 3 ), 229 – 242 .
Katare, A. ; Borgohain, R. ; Prasad, B. ; Mandal, B . A strategical improvement in the performance of CO 2 /N 2 gas permeation via conjugation of L-tyrosine onto chitosan membrane . Membranes , 2023 , 13 ( 5 ), 487 .
Guo, L. ; Liu, W. H. ; Yang, Y. ; Ali, A. ; Hon Lau, C. ; Bermeshev, M. V. ; Shao, L . Recent progress in thermally rearranged (TR) polymer based membranes for sustainable gas separations . Sep. Purif. Technol. , 2025 , 355 , 129690 .
Castro-Muñoz, R. ; Ahmad, M. Z. ; Fíla, V . Tuning of nano-based materials for embedding into low-permeability polyimides for a featured gas separation . Front. Chem. , 2020 , 7 , 897 .
时飞 , 李奕帆 . 混合基质膜在碳捕集领域的研究进展 . 化工进展 , 2020 , 39 ( 6 ), 2453 – 2462 .
Velioğlu, S. ; Ahunbay, M. G. ; Tantekin-Ersolmaz, S. B . Propylene/propane plasticization in polyimide membranes . J. Membr. Sci. , 2016 , 501 , 179 – 190 .
Najari, S. ; Saeidi, S. ; Gallucci, F. ; Drioli, E . Mixed matrix membranes for hydrocarbons separation and recovery: a critical review . Rev. Chem. Eng. , 2021 , 37 ( 3 ), 363 – 406 .
Imtiaz, A. ; Othman, M. H. D. ; Jilani, A. ; Khan, I. U. ; Kamaludin, R. ; Samuel, O . ZIF-filler incorporated mixed matrix membranes (MMMs) for efficient gas separation: A review . J. Environ. Chem. Eng. , 2022 , 10 ( 6 ), 108541 .
Wang, Z. H. ; Zhang, Z. E. ; Soltanian, M. R. ; Pang, R. Z . Facilitated transport membranes in post-combustion carbon capture: Recent advancements in polymer materials and challenges towards practical application . Green Energy Environ. , 2025 , 10 ( 3 ), 500 – 517 .
Sun, S. Y. ; Li, S. D. ; Wang, S. K. ; Chen, Y. F . Design and development of highly selective and permeable membranes for H 2 /CO 2 separation: a review . Chem. Eng. J. , 2024 , 494 , 152972 .
Liu, C. M. ; Zhang, X. ; Zhai, J. X. ; Li, X. ; Guo, X. Y. ; He, G. L . Research progress and prospects on hydrogen separation membranes . Clean Energy , 2023 , 7 ( 1 ), 217 – 241 .
Al-Shaeli, M. ; Orhun Teber, O. ; Al-Juboori, R. A. ; Khataee, A. ; Koyuncu, I. ; Vatanpour, V . Inorganic layered polymeric membranes: Highly-ordered porous ceramics for surface engineering of polymeric membranes . Sep. Purif. Technol. , 2024 , 350 , 127925 .
武佳宁 . H 2 /CO 2 气体分离用聚苯并咪唑膜的研究进展 . 高分子通报 , 2025 , ( 1 ), 75 – 89 .
Yu, J. ; Wang, C. Q. ; Xiang, L. ; Xu, Y. Z. ; Pan, Y. C . Enhanced C 3 H 6 /C 3 H 8 separation performance in poly(vinyl acetate) membrane blended with ZIF-8 na nocrystals . Chem. Eng. Sci. , 2018 , 179 , 1 – 12 .
Qin, Z. K. ; Wei, J. ; Wu, Y. M. ; Deng, M. ; Yao, L. ; Yang, L. ; Jiang, W. J. ; Zheng, J. F. ; Liu, Z. ; Dai, Z. D . Mixed matrix membranes (MMMs) fabricated via ultrathin Cu-MOF nanosheets for CO 2 /N 2 separation: Low loading but high performance . Results Eng. , 2024 , 24 , 103184 .
安少杭 , 陈占营 , 李奇 , 常印忠 , 刘蜀疆 , 王世联 . 高分子气体分离膜技术研究进展 . 高分子通报 , 2023 , ( 1 ), 1 – 11 .
Acharya, N. K . Temperature-dependent gas transport and its correlation with kinetic diameter in polymer nanocomposite membrane . Bull. Mater. Sci. , 2017 , 40 ( 3 ), 537 – 543 .
Kamble, A. R. ; Patel, C. M. ; Murthy, Z. V. P . A review on the recent advances in mixed matrix membranes for gas separation processes . Renew. Sustain. Energy Rev. , 2021 , 145 , 111062 .
Qian, S. H. ; Xia, L. ; Yang, L. F. ; Wang, X. B. ; Suo, X. ; Cui, X. L. ; Xing, H. B . Defect-free mixed-matrix membranes consisting of anion-pillared metal-organic frameworks and poly(ionic liquid)s for separation of acetylene from ethylene . J. Membr. Sci. , 2020 , 611 , 118329 .
Sun, Y. X. ; Tian, L. ; Qiao, Z. H. ; Geng, C. X. ; Guo, X. Y. ; Zhong, C. L . Surface modification of bilayer structure on metal-organic frameworks towards mixed matrix membranes for efficient propylene/propane separation . J. Membr. Sci. , 2022 , 648 , 120350 .
Zhang, Y. ; Liang, C. ; Yu, J. N. ; Li, Z. M. ; Li, X. Q . Constructing the electrostatic potential microenvironment in MMMs by poly(ionic liquid)s functionalized metal–organic frameworks for efficient CO 2 /CH 4 separation . Sep. Purif. Technol. , 2025 , 354 , 129361 .
Huang, G. C. ; Liu, T. X. ; Peng, H. X. ; Xie, Y. B. ; Chen, Q. ; Li, J. R . Enhancement of CO 2 /N 2 separation in MMMs by the regulation of nanofiller microenvironment . Sep. Purif. Technol. , 2025 , 354 , 128737 .
Yuan, Y. ; Yang, Y. ; Shi, F. ; Song, C. Y. ; Wang, B. ; Sheng, M. L. ; Wang, Z . Polymer-modified nanofillers for enhancing CO 2 separation performance of MMMs: A comparative study on the role of bridging ligands . J. Membr. Sci. , 2024 , 711 , 123220 .
Zagho, M. M. ; Hassan, M. K. ; Khraisheh, M. ; Al Ali Al-Maadeed, M. ; Nazarenko, S . A review on recent advances in CO 2 separation using zeolite and zeolite-like materials as adsorbents and fillers in mixed matrix membranes (MMMs) . Chem. Eng. J. Adv. , 2021 , 6 , 100091 .
Genduso, G. ; Ogieglo, W. ; Wang, Y. G. ; Pinnau, I . Carbon molecular sieve gas separation materials and membranes: A comprehensive review . J. Membr. Sci. , 2024 , 699 , 122533 .
Patil, M. ; Hunasikai, S. G. ; Mathad, S. N. ; Patil, A. Y. ; Hegde, C. G. ; Sudeept, M. A. ; Amshumali, M. K. ; Elgorban, A. M. ; Wang, S. F. ; Wong, L. S. ; Syed, A . Enhanced O 2 /N 2 separation by QuaternizedMatrimid/Multiwalled carbon nanotube mixed-matrix membrane . Heliyon , 2023 , 9 ( 11 ), e21992 .
Casadei, R. ; Giacinti Baschetti, M. ; Yoo, M. J. ; Park, H. B. ; Giorgini, L . Pebax ® 2533/graphene oxide nanocomposite membranes for carbon capture . Membranes , 2020 , 10 ( 8 ), 188 .
Chuah, C. Y. ; Lee, J. ; Song, J. H. ; Bae, T. H . Carbon molecular sieve membranes comprising graphene oxides and porous carbon for CO 2 /N 2 separation . Membranes , 2021 , 11 ( 4 ), 284 .
Li, S. W. ; Jiang, X. ; Sun, H. G. ; He, S. S. ; Zhang, L. L. ; Shao, L . Mesoporous dendritic fibrous nanosilica (DFNS) stimulating mix matrix membranes towards superior CO 2 capture . J. Membr. Sci. , 2019 , 586 , 185 – 191 .
Yahia, M. ; Refaat, D. ; Coronas, J. ; Tellez, C . Enhancing CO 2 /CH 4 separation performance in PIM-1 based MXene nanosheets mixed matrix membranes . Sep. Purif. Technol. , 2025 , 356 , 129825 .
Rajpure, M. M. ; Mujmule, R. B. ; Kim, U. ; Kim, H . Fabrication of MgO nanorods blended cellulose acetate-based mixed matrix membranes for selecti ve gas separation of H 2 /CH 4 , CO 2 /CH 4 and H 2 /CO 2 : Effect of loading and pressure . Int. J. Hydrog. Energy , 2024 , 50 , 615 – 628 .
Jaid, G. M. ; AbdulRazak, A. A. ; Meskher, H. ; Al-Saadi, S. ; Alsalhy, Q. F . Metal-organic frameworks (MOFs), covalent organic frameworks (COFs), and hydrogen-bonded organic frameworks (HOFs) in mixed matrix membranes . Mater. Today Sustain. , 2024 , 25 , 100672 .
Song, Y. Y. ; He, M. G. ; Zhao, J. ; Jin, W. Q . Structural manipulation of ZIF-8-based membranes for high-efficiency molecular separation . Sep. Purif. Technol. , 2021 , 270 , 118722 .
Xin, Q. P. ; Zhang, X. H. ; Shao, W. ; Li, H. ; Zhang, Y. Z . COF-based MMMs with light-responsive properties generating unexpected surface segregation for efficient SO 2 /N 2 separation . J. Membr. Sci. , 2023 , 665 , 121109 .
Liu, K. G. ; Bigdeli, F. ; Panjehpour, A. ; Hwa Jhung, S. ; Al Lawati, H. A. J. ; Morsali, A . Potential applications of MOF composites as selective membranes for separation of gases . Coord. Chem. Rev. , 2023 , 496 , 215413 .
Reddy, A. S. ; Sharda, P. ; Nehra, S. P. ; Sharma, A . Advanced strategies in MOF-based mixed matrix membranes for propylene/propane separation: A critical review . Coord. Chem. Rev. , 2024 , 498 , 215435 .
Jheng, L. C. ; Park, J. ; Yoon, H. W. ; Chang, F. C . Mixed matrix membranes comprising 6FDA-based polyimide blends and UiO-66 with co-continuous structures for gas separations . Sep. Purif. Technol. , 2023 , 310 , 123126 .
Hassan, N. S. ; Jalil, A. A. ; Bahari, M. B. ; Khusnun, N. F. ; Sharaf Aldeen, E. M. ; Mim, R. S. ; Firmansyah, M. L. ; Rajendran, S. ; Mukti, R. R. ; Andika, R. ; Devianto, H . A comprehensive review on zeolite-based mixed matrix membranes for CO 2 /CH 4 separation . Chemosphere , 2023 , 314 , 137709 .
Dai, G. L. ; Zhang, Q. Q. ; Xiong, S. H. ; Deng, L. F. ; Gao, Z. ; Chen, A. Q. ; Li, X. F. ; Pan, C. Y. ; Tang, J. T. ; Yu, G. P . Building interfacial compatible PIM-1-based mixed-matrix membranes with β -ketoenamine-linked COF fillers for effective CO 2 /N 2 separation . J. Membr. Sci. , 2023 , 676 , 121561 .
Al-Rowaili, F. N. ; Khaled, M. ; Jamal, A. ; Zahid, U . Mixed matrix membranes for H 2 /CO 2 gas separation- a critical review . Fuel , 2023 , 333 , 126285 .
莫凯 , 问菲 , 金花 , 李砚硕 . ZIF-8膜分离丙烯/丙烷的研究进展 . 膜科学与技术 , 2020 , 40 ( 2 ), 136 – 145 .
常晓青 , 彭东来 , 李东洋 , 张延武 , 王景 , 张亚涛 . MOFs基丙烯/丙烷高效分离混合基质膜研究进展 . 化工进展 , 2023 , 42 ( 4 ), 1961 – 1973 .
何文 , 王波 , 冯晗俊 , 孔祥如 , 李桃 , 肖睿 . CO 2 捕集膜分离的Pebax基材料研究进展 . 化学学报 , 2024 , 82 ( 2 ), 226 – 241 .
Paul, D. R. ; Kemp, D. R . The diffusion time lag in polymer membranes containing adsorptive fillers . J. Polym. Sci. Polym. Symp. , 1973 , 41 ( 1 ), 79 – 93 .
Riasat Harami, H. ; Amirkhani, F. ; Ahmad Khadem, S. ; Rezakazemi, M. ; Asghari, M. ; Shirazian, S . Mass transfer through PDMS/zeolite 4A MMMs for hydrogen separation: Molecular dynamics and grand canonical Monte Carlo simulations . Int. Commun. Heat Mass Transf. , 2019 , 108 , 104259 .
Viriya, V. ; Chew, T. L. ; Ng, Q. H. ; Ho, C. D. ; Jawad, Z. A . Mixed matrix membranes incorporated with small pore zeolite UZM-5 for enhanced CO 2 /CH 4 separation . Results Eng. , 2024 , 24 , 102951 .
Tsegay Tikue, E. ; Kang, S. K. ; Kim, M. H. ; Kwak, W. C. ; An, I. ; Yang, S. ; Kim, J. H. ; Lee, P. S . Mixed matrix membrane based on DOCDA polyimide with twisted kink structure and zeolite 4A for energy-efficient oxygen purification . J. Ind. Eng. Chem. , 2024 , 130 , 612 – 622 .
Zhang, Q. ; Zhou, M. ; Liu, X. F. ; Zhang, B. Q . Pebax/two-dimensional MFI nanosheets mixed-matrix membranes for enhanced CO 2 separation . J. Membr. Sci. , 2021 , 636 , 119612 .
姜海飞 . 有机分子筛膜的通道精密构筑及气体分离性能强化 . 博士学位论文 , 天津 : 天津大学 , 2022 .
Najafi, M. ; Sadeghi, M. ; Shamsabadi, A. A. ; Dinari, M. ; Soroush, M . Polysulfone membranes incorporated with reduced graphene oxide nanoparticles for enhanced olefin/paraffin separation . ChemistrySelect , 2020 , 5 ( 12 ), 3675 – 3681 .
Suhail, F. ; Batool, M. ; Anjum, T. ; Shah, A. T. ; Tabassum, S. ; Khan, A. L. ; AlMohamadi, H. ; Najam, M. ; Gilani, M. A . Enhanced CO 2 separation performance of polysulfone membranes via incorporation of pyrazole modified MCM-41 mesoporous silica as a nano-filler . Fuel , 2023 , 350 , 128840 .
Song, Z. H. ; Wang, Y. ; Zha, Z. Y. ; Wang, Z. ; Zhao, S . Porous organic cage separation membranes: Exploratory journey from preparation to application . Adv. Membr. , 2025 , 5 , 100125 .
王绍宇 , 马翰泽 , 吴洪 , 梁旭 , 王洪建 , 朱姿亭 , 姜忠义 . 有机框架膜在气体分离中的研究进展 . 化工学报 , 2021 , 72 ( 7 ), 3488 – 3510 .
Bügel, S. ; Spieß, A. ; Janiak, C . Covalent triazine framework CTF-fluorene as porous filler material in mixed matrix membranes for CO 2 /CH 4 separation . Microporous Mesoporous Mater. , 2021 , 316 , 110941 .
Yan, W. J. ; Huang, H. H. ; Zhang, A. Y. ; Dong, H. ; Liao, W. Z. ; He, Z. N. ; Yang, X. F. ; He, Q . Frontiers in applications of porous materials in CO 2 gas separation membranes: Mechanisms, membrane properties, and future perspectives of porous aromatic frameworks (PAFs) . J. Environ. Chem. Eng. , 2024 , 12 ( 5 ), 113509 .
Song, W. L. ; Tang, Y. X. ; Moon, B. Y. ; Liao, Q. ; Xu, H. L. ; Hou, Q. ; Zhang, H. ; Yu, D. G. ; Liao, Y. Z. ; Kim, I . Green synthesis of hypercrosslinked polymers for CO 2 capture and conversion: recent advances, opportunities, and challenges . Green Chem. , 2024 , 26 ( 5 ), 2476 – 2504 .
Pan, Y. K. ; Zhang, X. M. ; He, W. W. ; Zheng, L. ; Han, X. L . Dha Tab-COF filled PEBAX mixed matrix membranes for effective CO 2 /CH 4 separation . Chin. J. Chem. Eng. , 2025 , 77 , 123 – 134 .
Cheng, Z. L. ; Zhang, P. Y. ; Wang, Z. Y. ; Jiang, H. C. ; Wang, W. J. ; Liu, D. D. ; Wang, L. N. ; Zhu, G. S. ; Zou, X. Q . A bipyridyl covalent organic framework with coordinated Cu(I) for membrane C 3 H 6 /C 3 H 8 separation . Small , 2023 , 19 ( 30 ), 2300438 .
Zhang, Q. ; Li, H. B. ; Chen, S. ; Duan, J. G. ; Jin, W. Q . Mixed-matrix membranes with soluble porous organic molecular cage for highly efficient C 3 H 6 /C 3 H 8 separation . J. Membr. Sci. , 2020 , 611 , 118288 .
Zhang, Y. M. ; Yin, B. H. ; Huang, L. Z. ; Ding, L. ; Lei, S. ; Telfer, S. G. ; Caro, J. ; Wang, H. H . MOF membranes for gas separations . Prog. Mater. Sci. , 2025 , 151 , 101432 .
Hu, S. Y. ; Guo, G. J. ; Zhang, J. X. ; Khan, M. N. ; Xu, S. H. ; Yang, F. ; Schwandt, B. W. ; Hu, Z. G. ; Zou, J. X . Advanced porous MOF materials and technologies for high-efficiency ppm-level toxic gas separation . Mater. Sci. Eng. R Rep. , 2024 , 161 , 100874 .
Shahid, S. ; Nijmeijer, K. ; Nehache, S. ; Vankelecom, I. ; Deratani, A. ; Quemener, D . MOF-mixed matrix membranes: Precise dispersion of MOF particles with better compatibility via a particle fusion approach for enhanced gas separation properties . J. Membr. Sci. , 2015 , 492 , 21 – 31 .
苏尚德 , 祝轩 , 辛清萍 , 叶卉 , 赵莉芝 , 李泓 , 丁晓莉 , 张玉忠 . 用于碳捕集的气体分离复合膜研究进展 . 高分子通报 , 2024 , ( 4 ), 458 – 470 .
Lee, T. H. ; Lee, B. K. ; Youn, C. ; Kang, J. H. ; Kim, Y. J. ; Kim, K. I. ; Ha, Y. R. ; Han, Y. J. ; Park, H. B . Interface engineering in MOF/crosslinked polyimide mixed matrix membranes for enhanced propylene/propane separation performance and plasticization resistance . J. Membr. Sci. , 2023 , 667 , 121182 .
Geng, C. X. ; Chen, A. B. ; Sun, Y. X. ; Zhang, C. X. ; Qin, Z. X. ; Zhang, Z. Q. ; Gu, Z. J. ; Qiao, Z. H . Spacial regulation of precise aperture in metal-organic frameworks towards ultrahigh-selective mixed matrix membranes for low-energy-consumption C 3 H 6 /C 3 H 8 separation . Chem. Eng. J. , 2024 , 489 , 151451 .
Hua, Y. Y. ; Park, S. ; Choi, G. M. ; Jung, H. J. ; Cho, K. Y. ; Jeong, H. K . Highly propylene-selective asymmetric mixed-matrix membranes by polymer phase-inversion in sync with in situ ZIF-8 formation. Chem. Eng. J. , 2023 , 466 , 143048 .
Park, S. ; Abdul Hamid, M. R. ; Jeong, H. K . Highly propylene-selective mixed-matrix membranes by in situ metal-organic framework formation using a polymer-modification strategy . ACS Appl. Mater. Interfaces , 2019 , 11 ( 29 ), 25949 – 25957 .
Park, S. ; Jeong, H. K . Transforming polymer hollow fiber membrane modules to mixed-matrix hollow fiber membrane modules for propylene/propane separation . J. Membr. Sci. , 2020 , 612 , 118429 .
Luo, J. Y. ; Lyu, L. X. ; Yin, Z. J. ; Wei, Y. Y . Enhanced C 3 H 6 /C 3 H 8 separation performance in polysulfone membrane blended with rigid ZIF-8 crystals . Front. Chem. Sci. Eng. , 2024 , 19 ( 1 ), 4 .
Kayadoe, V. ; Widiastuti, N. ; Gunawan, T. ; Salleh, W. N. W. ; Fansuri, H. ; Romadiansyah, T. Q. ; Pratama, A. W . Fabrication of PSf/P84-blended membranes with low P84 content: Characteristics and gas separation performance . Case Stud. Chem. Environ. Eng. , 2024 , 10 , 100835 .
Wang, L. T. ; Yang, J . Zirconia-doped methylated silica membranes via sol-gel process: microstructure and hydrogen permselectivity . Nanomaterials , 2022 , 12 ( 13 ), 2159 .
dos Santos Pirola, A. ; Pacheco, P. S. ; Zawadski, S. F. ; Eiras, D . In-situ polymerized Pebax ® /polydopamine blend membranes with high CO 2 /N 2 selectivity . Polímeros , 2023 , 33 ( 4 ), e20230043 .
Chen, G. N. ; Chen, C. L. ; Guo, Y. N. ; Chu, Z. Y. ; Pan, Y. ; Liu, G. Z. ; Liu, G. P. ; Han, Y. ; Jin, W. Q. ; Xu, N. P . Solid-solvent processing of ultrathin, highly loaded mixed-matrix membrane for gas separation . Science , 2023 , 381 ( 6664 ), 1350 – 1356 .
Jeong, I. ; Hossain, I. ; Husna, A. ; Kim, T. H . Development of CO 2 -philic blended membranes using PIM-PI and PIM-PEG/PPG . Macromol. Mater. Eng. , 2023 , 308 ( 5 ), 2200596 .
Gawali, A. V. ; Gawali, S. ; Jampa, S. S. ; Sinha, M. K . Investigating the effect of ZIF-8@PEI filler and its comparison with ZIF-8 in mixed matrix membranes for CO 2 /CH 4 separation with the help of DFT study . Sustain. Chem. Clim. Action , 2024 , 5 , 100044 .
Kononova, I. ; Moshnikov, V. ; Kononov, P . SnO 2 -based porous nanomaterials: Sol-gel formation and gas-sensing application . Gels , 2023 , 9 ( 4 ), 283 .
Jonnalagedda, A. ; Kuncharam, B. V. R . Study of mixed matrix membranes with in situ synthesized zeolite imidazolate frameworks (ZIF-8, ZIF-67) in polyethersulfone polymer for CO 2 /CH 4 separation . RSC Adv. , 2024 , 14 ( 37 ), 27074 – 27085 .
张凯 . 客体组装金属-有机框架混合基质膜的制备及其烷烯烃分离性能研究 . 硕士学位论文 , 青岛 : 中国石油大学(华东) , 2021 .
赵静 , 金万勤 . 基于三维多孔填料的聚二甲基硅氧烷混合基质渗透汽化膜研究进展 . 华东理工大学学报(自然科学版) , 2024 , 50 ( 5 ), 633 – 644 .
Yu, Q. X. ; Bei, R. X. ; Liu, J. H. ; He, Y. W. ; Liu, S. W. ; Chi, Z. G. ; Xu, J. R. ; Zhang, Y . Bioinspired polyimide film with fire retardant and gas barrier properties by gravity-induced deposition of montmorillonite . Aggregate , 2023 , 4 ( 6 ), e392 .
Ying, Y. P. ; Tong, M. M. ; Ning, S. C. ; Ravi, S. K. ; Peh, S. B. ; Tan, S. C. ; Pennycook, S. J. ; Zhao, D . Ultrathin two-dimensional membranes assembled by ionic covalent organic nanosheets with reduced apertures for gas separation . J. Am. Chem. Soc. , 2020 , 142 ( 9 ), 4472 – 4480 .
Longo, M. ; Mobili, R. ; Monteleone, M. ; La Cognata, S. ; Fuoco, A. ; Esposito, E. ; Boiocchi, M. ; Milanese, C. ; Armentano, D. ; Hajivand, P. ; Amendola, V. ; Jansen, J. C . Metal-organic cages in polyimide and polyetheretherketone thin film composite mixed matrix membranes for gas separation . J. Membr. Sci. , 2025 , 714 , 123391 .
An, H. ; Shin, M. G. ; Yoo, C. H. ; Lee, J. H. ; Lee, J. S . Expanding interfacial polymerization for gas separation beyond water purification . J. Membr. Sci. , 2025 , 713 , 123331 .
Ding, X. L. ; Wang, W. J. ; Cheng, X. Y. ; Fan, X. Q. ; Zhao, H. Y. ; Xin, Q. P. ; Zhang, Y. Z . Composite membranes based on ether oxygen-rich polyimide with superior CO 2 /N 2 separation properties prepared by interfacial polymerization . J. Membr. Sci. , 2024 , 693 , 122355 .
Yu, J. J. ; Wang, Z. ; Wang, F. ; Han, S. ; Li, X. W . Gravity-induced approach to mixed matrix membrane with asymmetric structure for ultrahigh CO 2 separation: Influence of particle deposition . ACS Appl. Polym. Mater. , 2025 , 7 ( 1 ), 343 – 353 .
Zheng, W. J. ; Guo, Y. H. ; Li, Z. H. ; Ruan, X. H. ; Jiang, X. B. ; Li, T. T. ; Li, X. C. ; Dai, Y. ; He, G. H . Gravity induced deposition of MOFs to construct mixed-matrix substrate for defect-free and flexible MOFs membrane . J. Membr. Sci. , 2024 , 710 , 123170 .
马玉磊 , 魏静 , 银登国 , 冯超 , 杜文韬 , 黄娅 , 代忠德 . 用于CO 2 分离的含氨基酸盐促进传递膜研究进展 . 膜科学与技术 , 2024 , 44 ( 2 ), 165 – 176 .
Xin, Q. P. ; Kong, S. N. ; Cao, X. T. ; Pan, Y. C. ; Wan, K. ; Chen, H. ; Jin, H. M. ; Gao, N. N. ; Ding, X. L. ; Zhang, Y. Z . Heterostructure ZIF-8@MXene with sieving effect in mixed matrix membranes for CO 2 separation . Sep. Purif. Technol. , 2025 , 355 , 129779 .
Fan, H. W. ; Peng, M. H. ; Strauss, I. ; Mundstock, A. ; Meng, H. ; Caro, J . MOF-in-COF molecular sieving membrane for selective hydrogen separation . Nat. Commun. , 2021 , 12 ( 1 ), 38 .
马悦 . 多孔芳香骨架材料的孔道设计及其气体分离性能研究 . 博士学位论文 , 长春 : 东北师范大学 , 2022 .
Li, H. J. ; Sun, Y. C. ; Zhao, Q. Z. ; He, G. H. ; Ma, C. H . Model prediction of gas permeability of mixed matrix membranes and their fillers . Sep. Purif. Technol. , 2025 , 354 , 129338 .
Zhang, C. ; Dai, Y. ; Johnson, J. R. ; Karvan, O. ; Koros, W. J . High performance ZIF-8/6FDA-DAM mixed matrix membrane for propylene/propane separations . J. Membr. Sci. , 2012 , 389 , 34 – 42 .
Feng, Y. ; Yu, L. T. ; Zhang, K. ; Fan, W. D. ; Fan, L. L. ; Kang, Z. X. ; Sun, D. F . Fabrication of mixed matrix membranes with regulated MOF fillers via incorporating guest molecules for optimizing light hydrocarbon separation performance . CrystEngComm , 2022 , 24 ( 43 ), 7658 – 7668 .
Cheng, Z. L. ; Wu, H. ; Zhang, H. ; Wang, Z. Y. ; Wang, L. N. ; Zou, X. Q. ; Zhu, G. S . Synthesis of cuprous organic frameworks with adjustable pores as membrane materials for C 3 H 6 /C 3 H 8 separation . Small Struct. , 2024 , 5 ( 12 ), 2400295 .
冯孝权 . 基于Ag功能化材料混合基质膜的制备及其丙烯/丙烷分离性能研究 . 博士学位论文 , 郑州 : 郑州大学 , 2022 .
Li, H. J. ; Sun, Y. C. ; Guan, J. Y. ; Bai, L. ; Li, T. Y. ; Sun, F. K. ; Liu, Y. J. ; He, G. H. ; Ma, C. H . Amidoxime-functionalized PIM-1 incorporating defect-engineered ZIF-8 for enhanced propylene/propane separation and plasticization resistance . J. Membr. Sci. , 2025 , 722 , 123907 .
Yu, Z. J. ; Sun, Y. X. ; Zhang, Z. Q. ; Geng, C. X. ; Qiao, Z. H . Rational matching of metal-organic frameworks and polymers in mixed matrix membranes for efficient propylene/propane separation . Polymers , 2024 , 16 ( 17 ), 2545 .
An, H. ; Park, S. ; Kwon, H. T. ; Jeong, H. K. ; Lee, J. S . A new superior competitor for exceptional propylene/propane separations: ZIF-67 containing mixed matrix membranes . J. Membr. Sci. , 2017 , 526 , 367 – 376 .
0
浏览量
12
下载量
0
CSCD
- 网络PDF下载
- Meta-XML下载
- BibTeX下载
- Endnote下载
- RefMan 下载
- NoteExpress下载
- NoteFirst下载
关联资源
相关文章
相关作者
相关机构
- 技术支持由北京北大方正电子有限公司提供 京ICP备09064830号-19
京公网安备11010802024621 - 本系统建议在Chrome、 IE9+ 以上版本浏览器阅读本站内容，360浏览器请切换至极速模式
- Cookies帮助我们提供服务并提供个性化体验。使用本网站，即表示您同意我们使用Cookies