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1.天津大学,材料科学与工程学院,材料科学与工程国家级实验教学示范中心,天津 300350
2.天津大学,智能传感功能材料全国重点实验室,有机集成电路教育部重点实验室,天津市分子光电科学重点实验室,天津 300350
3.山东大学物理学院,物理国家级实验教学示范中心,济南 250100
yelong@tju.edu.cn
收稿日期:2025-03-24,
录用日期:2025-05-23,
网络出版日期:2025-07-16,
纸质出版日期:2025-09-20
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叶龙, 于梦琪, 韩德霞, 韩洋, 殷航, 贾慧珍, 马哲. 前沿研究驱动的高分子综合性实验设计与实践——以可拉伸聚合物光伏电池的制备与表征为例[J]. 高分子通报, 2025,38(9):1439-1450.
YE Long, YU Meng-qi, HAN De-xia, HAN Yang, YIN Hang, JIA Hui-zhen, MA Zhe. Frontier-driven Comprehensive Experimental Design and Practice in Polymer Science:——Taking Fabrication and Characterization of Stretchable Polymer Solar Cells as an Example[J]. Polymer bulletin, 2025, 38(9): 1439-1450.
叶龙, 于梦琪, 韩德霞, 韩洋, 殷航, 贾慧珍, 马哲. 前沿研究驱动的高分子综合性实验设计与实践——以可拉伸聚合物光伏电池的制备与表征为例[J]. 高分子通报, 2025,38(9):1439-1450. DOI: 10.14028/j.cnki.1003-3726.2025.25.088.
YE Long, YU Meng-qi, HAN De-xia, HAN Yang, YIN Hang, JIA Hui-zhen, MA Zhe. Frontier-driven Comprehensive Experimental Design and Practice in Polymer Science:——Taking Fabrication and Characterization of Stretchable Polymer Solar Cells as an Example[J]. Polymer bulletin, 2025, 38(9): 1439-1450. DOI: 10.14028/j.cnki.1003-3726.2025.25.088.
实验教学是高分子学科本科教学的核心环节,将学科前沿知识与本科实验教学深度融合已成为高等教育改革的关键方向。柔性可拉伸电子技术作为颠覆性创新的前沿领域,在服务国家战略需求、促进新质生产力发展及引领未来产业变革方面具有重大意义。本研究围绕可拉伸光伏电池开发了综合性的高分子科学实验教学方案。以廉价易得的共轭高分子材料——聚噻吩为研究对象,通过热塑性弹性体物理共混的策略调控活性层形貌,显著提升了光伏电池的拉伸性能,成功制备出本征可拉伸聚合物光伏电池。综合实验设计基于多学科知识的交叉融合,帮助学生系统掌握相关的理论知识与实验技能,提高其综合运用专业知识的能力,具有较高的推广应用价值,为高分子专业的实验教学改革与实践提供了有益的探索和借鉴。
The experimental course is a core component of undergraduate education in polymer science. The integration of cutting-edge knowledge and undergraduate experimental teaching has become a key direction in higher education reform. Flexible and stretchable electronics
as major disruptive innovations
are of significant importance in serving national strategic needs
promoting the development of new quality productivity
and leading the transformation of future industries. This study focuses on stretchable solar cells and designs a comprehensive experiment in polymer science. Using the low-cost conjugated polymer material polythiophene as the research object
a thermoplastic elastomer physical blending strategy was adopted to modulate the morphology of the active layer
which significantly improved the stretch ability of solar cells. Accordingly
an intrinsically stretchable polymer solar cell was prepared. Based on the integration of multidisciplinary knowledge
the experiment helped students systematically master relevant theories and experimental skills
improving their ability to comprehensively apply professional knowledge. It holds great potential for broader applications and is well suited for experimental teaching reform and practice in polymer science programs.
战艳虎 , 李光 , 王双双 , 李艳凯 , 李玉超 , 邓爱霞 , 谢倩 . 基于工程教育认证和科教融合的《高分子物理实验》教学改革 . 高分子通报 , 2023 , 36 ( 6 ), 764 – 768 .
Bae, Y. ; Kim, D. ; Li, S. M. ; Choi, Y. ; Son, S. Y. ; Park, T. ; Ye, L . Stability of intrinsically stretchable polymer photovoltaics: fundamentals, achievements, and perspectives . Prog. Polym. Sci. , 2024 , 159 , 101899 .
吴小玲 , 杜淼 , 李水兴 , 陈红征 . 柔性电子器件: 想见未来生活方式 . 高分子通报 , 2024 , 37 ( 1 ), 1 – 11 .
Khasbaatar, A. ; Xu, Z. ; Lee, J. H. ; Campillo-Alvarado, G. ; Hwang, C. ; Onusaitis, B. N. ; Diao, Y . From solution to thin film: molecular assembly of π -conjugated systems and impact on (opto)electronic properties . Chem. Rev. , 2023 , 123 ( 13 ), 8395 – 8487 .
Li, S. M. ; Liu, J. W. ; Kuvondikov, V. ; Yan, J. Y. ; Ye, L . Organic photovoltaics generate more power under stretching . Matter , 2025 , 8 ( 4 ), 102062 .
李永舫 . 从导电聚吡咯到共轭聚合物光伏材料: 我在中科院化学所30年共轭高分子研究历程 . 高分子通报 , 2016 , ( 9 ), 10 – 26 .
王思怡 , 钟文楷 , 黄飞 . 可拉伸高分子光电器件的研究进展 . 高分子学报 , 2024 , 55 ( 9 ), 1091 – 1110 .
李韦伟 . 高分子物理教学与共轭高分子前沿研究的融合探索 . 高分子通报 , 2024 , 37 ( 7 ), 979 – 987 .
Li, S. M. ; Gao, M. Y. ; Zhou, K. K. ; Li, X. ; Xian, K. H. ; Zhao, W. C. ; Chen, Y. ; He, C. Y. ; Ye, L . Achieving record-high stretchability and mechanical stability in organic photovoltaic blends with a dilute-absorber strategy . Adv. Mater. , 2024 , 36 ( 8 ), 2307278 .
Wu, J. J. ; Gao, Y. P. ; Zhou, Z. H. ; Du, Y. H. ; Liu, J. W. ; Wang, J. J. ; Wang, Q. ; Zhou, K. K. ; Xian, K. H. ; Lin, Z. J. ; Chen, Y. ; Zhao, W. C. ; Li, S. S. ; Kuvondikov, V. ; Yin, H. ; Yan, J. Y. ; Liu, Y. S. ; Ye, L . Constructing high-performance solar cells and photodetectors with a doping-free polythiophene hole transport material . Adv. Funct. Mater. , 2024 , 34 ( 1 ), 2308584 .
孙冰 , 李赛萌 , 周康康 , 彭忠祥 , 叶龙 . 有机光伏薄膜的力学性能调控与预测 . 高等学校化学学报 , 2023 , 44 ( 9 ), 48 – 56 .
Feng, J. T. ; Sun, C. L. ; Li, S. M. ; Ye, L . Advancing the dynamic mechanical analysis of organic semiconductor materials . Chem. Commun. , 2024 , 60 ( 78 ), 10795 – 10804 .
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