基于静电纺丝构建的聚丙烯腈/六方氮化硼衍生物复合膜及其对自主合成香精的释放性能研究

吴泽凡; 郝红玲; 肖焱; 崔青云; 胡雪敏; 杨文秀

doi:10.14028/j.cnki.1003-3726.2025.25.123

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基于静电纺丝构建的聚丙烯腈/六方氮化硼衍生物复合膜及其对自主合成香精的释放性能研究

研究论文 | 更新时间：2025-09-23

- 基于静电纺丝构建的聚丙烯腈/六方氮化硼衍生物复合膜及其对自主合成香精的释放性能研究
- Study on the Release Performance of Polyacrylonitrile/Hexagonal Boron Nitride Derivative Composite Film Constructed Based on Electrospinning and Its Effect on the Self-synthesized Essence
- 高分子通报 2025年38卷第10期页码：1536-1545
- 作者机构：
  
  1.河北科技大学纺织服装学院，石家庄 050018
  2.河北中烟工业有限责任公司技术中心，石家庄 050018
  3.河北省纺织服装技术创新中心，石家庄 050018
- 作者简介：
  
  haohongling_hbzy@163.com
  huxuemin@hebust.edu.cn
- 基金信息：
  
  河北中烟工业有限责任公司科技项目(HBZY2024A063);河北省创新能力提升计划(23554002K)
- DOI：10.14028/j.cnki.1003-3726.2025.25.123
  中图分类号：
- 收稿日期：2025-04-23，
  
  录用日期：2025-07-15，
  
  网络出版日期：2025-09-02，
  
  纸质出版日期：2025-10-20
- 稿件说明：
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吴泽凡, 郝红玲, 肖焱, 崔青云, 胡雪敏, 杨文秀. 基于静电纺丝构建的聚丙烯腈/六方氮化硼衍生物复合膜及其对自主合成香精的释放性能研究. 高分子通报, 2025, 38(10), 1536–1545.

Wu, Z. F.; Hao, H. L.; Xiao, Y.; Cui, Q. Y.; Hu, X. M.; Yang, W. X. Study on the release performance of polyacrylonitrile/hexagonal boron nitride derivative composite film constructed based on electrospinning and its effect on the self-synthesized essence. Polym. Bull. (in Chinese), 2025, 38(10), 1536–1545.
吴泽凡, 郝红玲, 肖焱, 崔青云, 胡雪敏, 杨文秀. 基于静电纺丝构建的聚丙烯腈/六方氮化硼衍生物复合膜及其对自主合成香精的释放性能研究. 高分子通报, 2025, 38(10), 1536–1545. DOI： 10.14028/j.cnki.1003-3726.2025.25.123.

Wu, Z. F.; Hao, H. L.; Xiao, Y.; Cui, Q. Y.; Hu, X. M.; Yang, W. X. Study on the release performance of polyacrylonitrile/hexagonal boron nitride derivative composite film constructed based on electrospinning and its effect on the self-synthesized essence. Polym. Bull. (in Chinese), 2025, 38(10), 1536–1545. DOI： 10.14028/j.cnki.1003-3726.2025.25.123.

摘要

吡嗪类香味化合物因其独特的香气在香烟加香中被广泛应用，但吡嗪类化合物沸点较高，影响消费者抽吸体验感。因此，本研究以聚丙烯腈(PAN)为皮层，2-苯乙烯基吡嗪为芯层，六方氮化硼(h-BN)及其衍生物(HBN、GHBN)为功能填料，采用同轴静电纺丝技术制备了皮芯结构复合纳米纤维膜。研究表明，在复合纳米纤维膜中添加GHBN可明显提升2-苯乙烯基吡嗪的挥发速率，将热响应速度缩短至127 s，提升58%，香气强度值可达484，较单一PAN皮芯结构膜提升85%。同时，复合纤维膜水接触角为115.2°，疏水性明显增强，可降低香烟抽吸过程中湿度对挥发性物质的影响。

Abstract

Pyrazine aroma compounds are widely used in cigarette flavoring due to their unique aroma. But the boiling point of pyrazine compounds is high

which affects consumers’ sense of suction experience. Therefore

in this study

polyacrylonitrile (PAN) was used as the cortex

2-styrylpyrazine as the core layer

and hexagonal boron nitride (h-BN) and its derivatives (HBN

GHBN) as the functional filler. The composite nanofiber membrane with skin core structure was prepared by coaxial electrospinning technology. The results showed that the volatilization rate of 2-styrylpyrazine was significantly improved by adding GHBN to the composite nanofiber membrane

the thermal response rate was shortened to 127 s

and the aroma intensity value was up to 484

which was 85% higher than that of the single pan skin core structure membrane. At the same time

the water contact angle of the composite fiber membrane was 115.2°

and the hydrophobicity was significantly enhanced

which could reduce the effect of humidity on volatile substances during cigarette smoking.

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references

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