四川大学高分子研究所先进高分子材料全国重点实验室 成都 610065
湖北科迪雅科技有限公司 随州 441300
ph@scu.edu.cn
收稿:2025-07-13,
录用:2025-10-19,
网络出版:2025-12-05,
纸质出版:2026-02-20
移动端阅览
苏凯宇, 叶宇琛, 李艳丽, 叶先科, 皮红. 多孔聚合物涂层制备技术的研究进展. 高分子通报, 2026, 39(2), 199–212.
Su, K. Y.; Ye, Y. C.; Li, Y. L.; Ye, X. K.; Pi, H. Research progress in fabrication techniques for porous polymer coatings. Polym. Bull. (in Chinese), 2026, 39(2), 199–212.
苏凯宇, 叶宇琛, 李艳丽, 叶先科, 皮红. 多孔聚合物涂层制备技术的研究进展. 高分子通报, 2026, 39(2), 199–212. DOI: 10.14028/j.cnki.1003-3726.2025.25.196.
Su, K. Y.; Ye, Y. C.; Li, Y. L.; Ye, X. K.; Pi, H. Research progress in fabrication techniques for porous polymer coatings. Polym. Bull. (in Chinese), 2026, 39(2), 199–212. DOI: 10.14028/j.cnki.1003-3726.2025.25.196.
多孔聚合物涂层因其独特的轻量化特性与高功能性优势,在众多领域呈现出广阔的应用前景。本文综述了近5年多孔聚合物涂层制备技术的研究进展,重点评述了相分离法、化学气相沉积法、致孔剂法、自组装法等主要的原位制备技术,详细阐述了各类方法的成孔机理和典型工艺,并归纳了现有技术普遍面临的挑战,如对有机溶剂依赖性大、设备要求高、成本高等。综合对比显示,复合法因其分步优化的模块化特性,有望突破现有技术的瓶颈,推动多孔聚合物涂层制备方法向绿色化、便捷化、低成本化方向发展。
Owing to their unique lightweight characteristics and superior functional properties
porous polymer coatings hold immense application potential in numerous fields. This article provides a comprehensive review of the research progress in the fabrication technologies of porous polymer coatings over the past five years. It critically assesses mainstream
in situ
preparation techniques
including phase separation
chemical vapor deposition
porogen leaching
and self-assembly
providing detailed elaborations of their pore-forming mechanisms and representative processes. The review further summarizes the common challenges faced by existing technologies
such as high dependence on organic solvents
stringent equipment requirements
and significant costs. A comprehensive comparison indicates that the composite method
leveraging its modular nature for step-by-step optimization
is expected to overcome the current bottlenecks and advance the preparation methods of porous polymer coatings towards enhanced environmental sustainability
operational simplicity
and cost-effectiveness.
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