1.中国科学院宁波材料技术与工程研究所,宁波 315201
2.中国科学院大学化学科学学院,北京 100049
E-mail: lexiaoxia@nimte.ac.cn
E-mail: tao.chen@nimte.ac.cn
收稿:2025-08-27,
录用:2025-09-26,
网络出版:2025-11-19,
纸质出版:2025-12-20
移动端阅览
孙雨, 吴伽仪, 吴越, 乐晓霞, 陈涛. 智能聚合物凝胶信息存储材料在防伪领域的研究进展. 高分子通报, 2025, 38(12), 1807–1825.
Sun, Y.; Wu, J. Y.; Wu, Y.; Le, X. X.; Chen, T. Research progress on smart polymer gel information storage materials for anti-counterfeiting. Polym. Bull. (in Chinese), 2025, 38(12), 1807–1825.
孙雨, 吴伽仪, 吴越, 乐晓霞, 陈涛. 智能聚合物凝胶信息存储材料在防伪领域的研究进展. 高分子通报, 2025, 38(12), 1807–1825. DOI: 10.14028/j.cnki.1003-3726.2025.25.242.
Sun, Y.; Wu, J. Y.; Wu, Y.; Le, X. X.; Chen, T. Research progress on smart polymer gel information storage materials for anti-counterfeiting. Polym. Bull. (in Chinese), 2025, 38(12), 1807–1825. DOI: 10.14028/j.cnki.1003-3726.2025.25.242.
信息安全是维护社会稳定、保障国家安全和促进人类文明发展的重要基础,其核心需求推动了防伪材料及相关技术的创新突破。传统防伪材料依赖静态信息存储,难以应对复杂伪造技术的挑战。智能聚合物凝胶凭借对外界刺激(光、热、化学信号等)的颜色变化和形状变形响应,为动态信息存储与高等级防伪提供了新范式。本文概述了聚合物凝胶基信息存储材料在防伪领域的最新研究进展:首先简要介绍防伪材料的发展背景和智能凝胶材料的独特优势;随后重点阐述基于化学色和物理色智能凝胶的制备方法,解析其加密/解密机制;进一步探讨从单色到多色、从单维到多维的防伪模式升级发展;最后总结当前面临的稳定性、规模化等挑战,并展望其与4D打印、多功能集成等技术结合的未来发展方向。本文旨在为智能防伪材料的设计与应用提供理论指导,推动信息安全技术的创新发展。
Information security is crucial for safeguarding human life
social stability and national security. This importance has accelerated the development of anti-counterfeiting materials and related technologies in recent years. Conventional anti-counterfeiting materials rely on static information storage
which often fails against increasingly advanced counterfeiting methods. In contrast
smart polymer gels provide a new approach through dynamic responses. These gels can change color or shape when exposed to external stimuli
such as light
heat
or chemical signals
enabling dynamic information storage and enhanced anti-counterfeiting. This review highlights the recent progress in polymer gel-based materials for anti-counterfeiting applications. It begins with a brief overview of the development of anti-counterfeiting materials and the distinctive advantages of smart gels. The article further elaborates on the preparation methods for smart gels based on chemical colorants and structural colors
along with an analysis of their encryption and decryption mechanisms. It also explores the advancement from single-color to multi-color and single-dimensional to multi-dimensional anti-counterfeiting strategies. Current challenges
such as improving stability and scalability
are also discussed. Future prospects
including integration with 4D printing and multifunctional systems
are discussed. This review aims to offer theoretical guidance for designing and applying intelligent anti-counterfeiting materials to promote innovation in the field of information security technology.
Hu, H. B. ; Zhong, H. ; Chen, C. L. ; Chen, Q. W . Magnetically responsive photonic watermarks on banknotes . J. Mater. Chem. C , 2014 , 2 ( 19 ), 3695 – 3702 .
Ruffato, G. ; Rossi, R. ; Massari, M. ; Mafakheri, E. ; Capaldo, P. ; Romanato, F . Design, fabrication and characterization of computer generated holograms for anti-counterfeiting applications using OAM beams as light decoders . Sci. Rep . , 2017 , 7 , 18011 .
She, P. F. ; Ma, Y. ; Qin, Y. Y. ; Xie, M. J. ; Li, F. Y. ; Liu, S. J. ; Huang, W. ; Zhao, Q . Dynamic luminescence manipulation for rewritable and multi-level security printing . Matter , 2019 , 1 ( 6 ), 1644 – 1655 .
Liu, M. J. ; Ishida, Y. ; Ebina, Y. ; Sasaki, T. ; Hikima, T. ; Takata, M. ; Aida, T . An anisotropic hydrogel with electrostatic repulsion between cofacially aligned nanosheets . Nature , 2015 , 517 ( 7532 ), 68 – 72 .
Hao, X. P. ; Xu, Z. ; Li, C. Y. ; Hong, W. ; Zheng, Q. ; Wu, Z. L . Kirigami-design-enabled hydrogel multimorphs with application as a multistate switch . Adv. Mater . , 2020 , 32 ( 22 ), 2000781 .
Jian, Y. K. ; Handschuh-Wang, S. ; Zhang, J. W. ; Lu, W. ; Zhou, X. C. ; Chen, T . Biomimetic anti-freezing polymeric hydrogels: keeping soft-wet materials active in cold environments . Mater. Horiz . , 2021 , 8 ( 2 ), 351 – 369 .
Jiang, Z. ; Diggle, B. ; Shackleford, I. C. G. ; Connal, L. A. . Tough, self-healing hydrogels capable of ultrafast shape changing . Adv. Mater . , 2019 , 31 ( 48 ), 1904956 .
Lu, W. ; Si, M. Q. ; Liu, H. ; Qiu, H. Y. ; Wei, S. X. ; Wu, B. Y. ; Wang, R. J. ; Yin, G. Q. ; Zhang, J. W. ; Theato, P. ; Wei, Y. ; Chen, T . A panther chameleon skin-inspired core@shell supramolecular hydrogel with spatially organized multi-luminogens enables programmable color change . Cell Rep. Phys. Sci . , 2021 , 2 ( 5 ), 100417 .
Lin, G. Q. ; Si, M. Q. ; Wang, L. G. ; Wei, S. X. ; Lu, W. ; Liu, H. ; Zhang, Y. ; Li, D. Y. ; Chen, T . Dual-channel flexible strain sensors based on mechanofluorescent and conductive hydrogel laminates . Adv. Opt. Mater . , 2022 , 10 ( 5 ), 2102306 .
Baker, S. ; Baker, G . Luminescent carbon nanodots: Emergent nanolights . Angew. Chem. Int. Ed . , 2010 , 49 ( 38 ), 6726 – 6744 .
Wu, Y. Q. ; Ren, Y. Y. ; Guo, J. N. ; Liu, Z. Y. ; Liu, L. L. ; Yan, F . Imidazolium-type ionic liquid-based carbon quantum dot doped gels for information encryption . Nanoscale , 2020 , 12 ( 40 ), 20965 – 20972 .
Zhou, D. ; Li, D. ; Jing, P. T. ; Zhai, Y. C. ; Shen, D. Z. ; Qu, S. N. ; Rogach, A. L . Conquering aggregation-induced solid-state luminescence quenching of carbon dots through a carbon dots-triggered silica gelation process . Chem. Mater . , 2017 , 29 ( 4 ), 1779 – 1787 .
Wu, S. S. ; Shi, H. H. ; Lu, W. ; Wei, S. X. ; Shang, H. ; Liu, H. ; Si, M. Q. ; Le, X. X. ; Yin, G. Q. ; Theato, P. ; Chen, T . Aggregation-induced emissive carbon dots gels for octopus-inspired shape/color synergistically adjustable actuators . Angew. Chem. Int. Ed . , 2021 , 60 ( 40 ), 21890 – 21898 .
Lu, H. ; Mack, J. ; Yang, Y. C. ; Shen, Z . Structural modification strategies for the rational design of red/NIR region BODIPYs . Chem. Soc. Rev . , 2014 , 43 ( 13 ), 4778 – 4823 .
Kim, H. N. ; Lee, M. H. ; Kim, H. J. ; Kim, J. S. ; Yoon, J . A new trend in rhodamine-based chemosensors: application of spirolactam ring-opening to sensing ions . Chem. Soc. Rev . , 2008 , 37 ( 8 ), 1465 – 1472 .
Cao, D. X. ; Liu, Z. Q. ; Verwilst, P. ; Koo, S. ; Jangjili, P. ; Kim, J. S. ; Lin, W. Y . Coumarin-based small-molecule fluorescent chemosensors . Chem. Rev . , 2019 , 119 ( 18 ), 10403 – 10519 .
Keerthana, S. ; Sam, B. ; George, L. ; Sudhakar, Y. N. ; Varghese, A . Fluorescein based fluorescence sensors for the selective sensing of various analytes . J. Fluoresc . , 2021 , 31 ( 5 ), 1251 – 1276 .
Wang, N. ; Yu, K. K. ; Li, K. ; Li, M. J. ; Wei, X. ; Yu, X. Q . Plant-inspired multifunctional fluorescent hydrogel: a highly stretchable and recoverable self-healing platform with water-controlled adhesiveness for highly effective antibacterial application and data encryption-decryption . ACS Appl. Mater. Interfaces , 2020 , 12 ( 52 ), 57686 – 57694 .
Ji, X. F. ; Wu, R. T. ; Long, L. L. ; Ke, X. S. ; Guo, C. X. ; Ghang, Y. J. ; Lynch, V. M. ; Huang, F. H. ; Sessler, J. L . Encoding, reading, and transforming information using multifluorescent supramolecular polymeric hydrogels . Adv. Mater . , 2018 , 30 ( 11 ), 1705480 .
Guillou, O. ; Daiguebonne, C. ; Calvez, G. ; Bernot, K . A long journey in lanthanide chemistry: from fundamental crystallogenesis studies to commercial anticounterfeiting taggants . Acc. Chem. Res . , 2016 , 49 ( 5 ), 844 – 856 .
Wei, S. X. ; Lu, W. ; Le, X. X. ; Ma, C. X. ; Lin, H. ; Wu, B. Y. ; Zhang, J. W. ; Theato, P. ; Chen, T . Bioinspired synergistic fluorescence-color-switchable polymeric hydrogel actuators . Angew. Chem. Int. Ed . , 2019 , 58 ( 45 ), 16243 – 16251 .
Xu, X. ; Wang, J. M. ; Yan, B . Facile fabrication of luminescent Eu(III) functionalized HOF hydrogel film with multifunctionailities: quinolones fluorescent sensor and anticounterfeiting platform . Adv. Funct. Mater . , 2021 , 31 ( 37 ), 2103321 .
Zhou, Q. ; Dong, X. L. ; Xiong, Y. X. ; Zhang, B. B. ; Lu, S. ; Wang, Q. ; Liao, Y. G. ; Yang, Y. J. ; Wang, H . Multi-responsive lanthanide-based hydrogel with encryption, naked eye sensing, shape memory, self-healing, and antibacterial activity . ACS Appl. Mater. Interfaces , 2020 , 12 ( 25 ), 28539 – 28549 .
Li, Z. Q. ; Chen, H. Z. ; Li, B. ; Xie, Y. M. ; Gong, X. L. ; Liu, X. ; Li, H. R. ; Zhao, Y. L . Photoresponsive luminescent polymeric hydrogels for reversible information encryption and decryption . Adv. Sci . , 2019 , 6 ( 21 ), 1901529 .
Zhu, Q. D. ; Van Vliet, K. ; Holten-Andersen, N. ; Miserez, A . A double-layer mechanochromic hydrogel with multidirectional force sensing and encryption capability . Adv. Funct. Mater . , 2019 , 29 ( 14 ), 1808191 .
Zhu, Q. D. ; Zhang, L. H. ; van Vliet, K. ; Miserez, A. ; Holten-Andersen, N . White light-emitting multistimuli-responsive hydrogels with lanthanides and carbon dots . ACS Appl. Mater. Interfaces , 2018 , 10 ( 12 ), 10409 – 10418 .
Long, S. J. ; Ye, Z. H. ; Jin, Y. Q. ; Huang, J. C. ; Huang, Y. W. ; Liao, Y. G. ; Li, X. F . High-performance photochromic hydrogels for rewritable information record . Macromol. Rapid Commun . , 2021 , 42 ( 7 ), 2000701 .
Wang, F. S. ; Cui, A. Y. ; Hu, Z. G. ; Zhang, L. D . Photogated coordination switching of silver nanoparticles for reversible coloration/discoloration of hydrogel . Adv. Opt. Mater . , 2021 , 9 ( 24 ), 2101505 .
Chen, G. J. ; Hong, W . Mechanochromism of structural-colored materials . Adv. Opt. Mater . , 2020 , 8 ( 19 ), 2000984 .
Haque, M. A. ; Kamita, G. ; Kurokawa, T. ; Tsujii, K. ; Gong, J. P . Unidirectional alignment of lamellar bilayer in hydrogel: one-dimensional swelling, anisotropic modulus, and stress/strain tunable structural color . Adv. Mater . , 2010 , 22 ( 45 ), 5110 – 5114 .
Chen, J. Y. ; Xu, L. R. ; Yang, M. J. ; Chen, X. C. ; Chen, X. D. ; Hong, W . Highly stretchable photonic crystal hydrogels for a sensitive mechanochromic sensor and direct ink writing . Chem. Mater . , 2019 , 31 ( 21 ), 8918 – 8926 .
Choi, J. ; Hua, M. T. ; Lee, S. Y. ; Jo, W. ; Lo, C. Y. ; Kim, S. H. ; Kim, H. T. ; He, X. M . Hydrocipher: bioinspired dynamic structural color-based cryptographic surface . Adv. Opt. Mater . , 2020 , 8 ( 1 ), 1901259 .
Wu, Y. ; Shen, Y. ; Han, J. Y. ; Théato, P. ; Le, X. X. ; Chen, T . Brush-like polymeric gels enabled photonic crystals toward ultrasensitive cosolvent chromism . Angew. Chem. Int. Ed . , 2024 , 63 ( 49 ), e202414136 .
Wu, Y. ; Sun, Y. M. ; Le, X. X. ; Shen, Y. ; Jiang, S. ; Théato, P. ; Wu, S. L. ; Chen, T . Regulating interpenetrating network gels to create anisotropic photonic crystals toward ultrasensitive mechanochromism . Nano Lett . , 2025 , 25 ( 25 ), 10178 – 10186 .
Jiang, P. ; Yan, C. Y. ; Ji, Z. Y. ; Guo, Y. X. ; Zhang, X. Q. ; Jia, X. ; Wang, X. L. ; Zhou, F . Drawing high-definition and reversible hydrogel paintings with grayscale exposure . ACS Appl. Mater. Interfaces , 2019 , 11 ( 45 ), 42586 – 42593 .
Wu, S. ; Yan, K. ; Zhao, Y. N. ; Tsai, C. C. ; Shen, J. ; Bentley, W. E. ; Chen, Y. ; Deng, H. B. ; Du, Y. M. ; Payne, G. F. ; Shi, X. W . Electrical writing onto a dynamically responsive polysaccharide medium: Patterning structure and function into a reconfigurable medium . Adv. Funct. Mater . , 2018 , 28 ( 40 ), 1803139 .
Yang, C. ; Shi, X. W. ; Qi, L. H. ; Zhu, X. Y. ; Tong, J. ; Deng, H. B. ; Du, Y. M . Electrical writing induced covalent cross-linking on hydrogel for multidimensional structural information storage . ACS Appl. Mater. Interfaces , 2021 , 13 ( 30 ), 36538 – 36547 .
Yu, C. T. ; Guo, H. L. ; Cui, K. P. ; Li, X. Y. ; Ye, Y. N. ; Kurokawa, T. ; Gong, J. P . Hydrogels as dynamic memory with forgetting ability . Proc. Natl. Acad. Sci. U. S. A . , 2020 , 117 ( 32 ), 18962 – 18968 .
Liu, J. ; Chen, Z. ; Chen, Y. J. ; Rehman, H. U. ; Guo, Y. T. ; Li, H. ; Liu, H. Z . Ionic conductive organohydrogels with dynamic pattern behavior and multi-environmental stability . Adv. Funct. Mater . , 2021 , 31 ( 24 ), 2101464 .
Li, P. ; Zhang, D. ; Zhang, Y. C. ; Lu, W. ; Zhang, J. W. ; Wang, W. Q. ; He, Q. S. ; Théato, P. ; Chen, T . Aggregation-caused quenching-type naphthalimide fluorophores grafted and ionized in a 3D polymeric hydrogel network for highly fluorescent and locally tunable emission . ACS Macro Lett . , 2019 , 8 ( 8 ), 937 – 942 .
Hai, J. ; Li, T. R. ; Su, J. X. ; Liu, W. S. ; Ju, Y. M. ; Wang, B. D. ; Hou, Y. L . Reversible response of luminescent terbium(Ⅲ)-nanocellulose hydrogels to anions for latent fingerprint detection and encryption . Angew. Chem. Int. Ed . , 2018 , 57 ( 23 ), 6786 – 6790 .
Ji, X. F. ; Chen, W. ; Long, L. L. ; Huang, F. H. ; Sessler, J. L. . Double layer 3D codes: fluorescent supramolecular polymeric gels allowing direct recognition of the chloride anion using a smart phone . Chem. Sci . , 2018 , 9 ( 40 ), 7746 – 7752 .
Deng, J. W. ; Wu, H. R. ; Xie, W. D. ; Jia, H. Y. ; Xia, Z. G. ; Wang, H. L . Metal cation-responsive and excitation-dependent nontraditional multicolor fluorescent hydrogels for multidimensional information encryption . ACS Appl. Mater. Interfaces , 2021 , 13 ( 33 ), 39967 – 39975 .
Shang, H. ; Le, X. X. ; Sun, Y. ; Wu, S. S. ; Wang, Y. ; Théato, P. ; Chen, T . Water-sensitive fluorescent microgel inks to produce verifiable information for highly secured anti-counterfeiting . Mater. Horiz . , 2024 , 11 ( 12 ), 2856 – 2864 .
Du, X. M. ; Li, T. Y. ; Li, L. J. ; Zhang, Z. C. ; Wu, T. Z . Water as a colorful ink: transparent, rewritable photonic coatings based on colloidal crystals embedded in chitosan hydrogel . J. Mater. Chem. C , 2015 , 3 ( 15 ), 3542 – 3546 .
Zhang, Z. H. ; Chen, Z. Y. ; Sun, L. Y. ; Zhang, X. X. ; Zhao, Y. J . Bio-inspired angle-independent structural color films with anisotropic colloidal crystal array domains . Nano Res . , 2019 , 12 ( 7 ), 1579 – 1584 .
Yue, Y. F. ; Haque, M. A. ; Kurokawa, T. ; Nakajima, T. ; Gong, J. P . Lamellar hydrogels with high toughness and ternary tunable photonic stop-band . Adv. Mater . , 2013 , 25 ( 22 ), 3106 – 3110 .
Li, L. Q. ; Zhou, J. Y. ; Han, J. Y. ; Liu, D. P. ; Qi, M. ; Xu, J. F. ; Yin, G. Q. ; Chen, T . Finely manipulating room temperature phosphorescence by dynamic lanthanide coordination toward multi-level information security . Nat. Commun . , 2024 , 15 ( 1 ), 3846 .
Sun, Y. ; Le, X. X. ; Shang, H. ; Shen, Y. ; Wu, Y. ; Liu, Q. Q. ; Théato, P. ; Chen, T . Dual-mode hydrogels with structural and fluorescent colors toward multistage secure information encryption . Adv. Mater . , 2024 , 36 ( 28 ), 2401589 .
Shang, H. ; Sun, Y. ; Le, X. X. ; Shen, Y. ; Chen, T . Dynamic metal-ligand coordination enables a hydrogel with rewritable dual-mode pattern display . Mater. Horiz . , 2024 , 11 ( 21 ), 5244 – 5250 .
Shen, Y. ; Shang, H. ; Le, X. X. ; Wu, Y. ; Sun, Y. ; Théato, P. ; Chen, T . Spatiotemporal regulation enabling photo-dimerizable gel networks toward multi-channel information encryption . Adv. Funct. Mater . , 2025 , e13532 .
Bairi, P. ; Roy, B. ; Chakraborty, P. ; Nandi, A. K. . Co-assembled white-light-emitting hydrogel of melamine . ACS Appl. Mater. Interfaces , 2013 , 5 ( 12 ), 5478 – 5485 .
Zhu, C. N. ; Bai, T. W. ; Wang, H. ; Bai, W. ; Ling, J. ; Sun, J. Z. ; Huang, F. H. ; Wu, Z. L. ; Zheng, Q . Single chromophore-based white-light-emitting hydrogel with tunable fluorescence and patternability . ACS Appl. Mater. Interfaces , 2018 , 10 ( 45 ), 39343 – 39352 .
Liu, S. Q. ; Wang, J. ; Tang, F. ; Wang, N. ; Li, L. ; Yao, C. ; Li, L. D . Aqueous systems with tunable fluorescence including white-light emission for anti-counterfeiting fluorescent inks and hydrogels . ACS Appl. Mater. Interfaces , 2020 , 12 ( 49 ), 55269 – 55277 .
Le, X. X. ; Lu, W. ; He, J. ; Serpe, M. J. ; Zhang, J. W. ; Chen, T . Ionoprinting controlled information storage of fluorescent hydrogel for hierarchical and multi-dimensional decryption . Sci. China Mater . , 2019 , 62 ( 6 ), 831 – 839 .
Le, X. X. ; Shang, H. ; Yan, H. Z. ; Zhang, J. W. ; Lu, W. ; Liu, M. J. ; Wang, L. P. ; Lu, G. M. ; Xue, Q. J. ; Chen, T . A urease-containing fluorescent hydrogel for transient information storage . Angew. Chem. Int. Ed . , 2021 , 60 ( 7 ), 3640 – 3646 .
Le, X. X. ; Shang, H. ; Wu, S. S. ; Zhang, J. W. ; Liu, M. J. ; Zheng, Y. F. ; Chen, T . Heterogeneous fluorescent organohydrogel enables dynamic anti-counterfeiting . Adv. Funct. Mater . , 2021 , 31 ( 52 ), 2108365 .
Shi, H. H. ; Wu, S. S. ; Si, M. Q. ; Wei, S. X. ; Lin, G. Q. ; Liu, H. ; Xie, W. P. ; Lu, W. ; Chen, T . Cephalopod-inspired design of photomechanically modulated display systems for on-demand fluorescent patterning . Adv. Mater . , 2022 , 34 ( 4 ), 2107452 .
Zhang, Y. C. ; Le, X. X. ; Jian, Y. K. ; Lu, W. ; Zhang, J. W. ; Chen, T . 3D fluorescent hydrogel origami for multistage data security protection . Adv. Funct. Mater . , 2019 , 29 ( 46 ), 1905514 .
Sun, Y. ; Shang, H. ; Le, X. X. ; Chen, T . An organohydrogel with tunable fluorescence and shape-memory property for advanced anti-counterfeiting . RSC Appl. Polym . , 2024 , 2 ( 3 ), 426 – 433 .
Wen, X. ; Zhang, K. H. ; Wu, B. Y. ; Chen, G. C. ; Zheng, N. ; Wu, J. J. ; Yang, X. X. ; Xie, T. ; Zhao, Q . Multi-mode geometrically gated encryption with 4D morphing hydrogel . Nat. Commun . , 2025 , 16 ( 1 ), 2830 .
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