MOF-76@黏胶水刺非织造材料的原位合成及其对有机染料的吸附性能

陈高原; 孙辉; 刘芙蓉; 于斌

doi:10.14028/j.cnki.1003-3726.2026.25.378

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MOF-76@黏胶水刺非织造材料的原位合成及其对有机染料的吸附性能

研究论文 | 更新时间：2026-04-30

- MOF-76@黏胶水刺非织造材料的原位合成及其对有机染料的吸附性能
- In Situ Synthesis of MOF-76@Viscose Spunlace Nonwoven and the Adsorption Performance for Organic Dyes
- 高分子通报 2026年39卷第5期页码：783-792
- 作者机构：
  
  浙江理工大学纺织科学与工程学院(国际丝绸学院)　杭州 310018
  浙江省现代纺织技术创新中心　绍兴 312000
- 作者简介：
  
  sunhui@zstu.edu.cn
- 基金信息：
  
  浙江省自然科学基金(LTGS23E030005);第一师阿拉尔市财政科技计划项目(2024GX02)
- DOI：10.14028/j.cnki.1003-3726.2026.25.378
  中图分类号：
- 收稿：2025-12-26，
  
  录用：2026-02-25，
  
  网络首发：2026-04-14，
  
  纸质出版：2026-05-20
- 稿件说明：
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陈高原, 孙辉, 刘芙蓉, 于斌. MOF-76@黏胶水刺非织造材料的原位合成及其对有机染料的吸附性能. 高分子通报, 2026, 39(5), 783–792.

Chen, G. Y.; Sun, H.; Liu, F. R.; Yu, B. In situ synthesis of MOF-76@viscose spunlace nonwoven and the adsorption performance for organic dyes. Polym. Bull. (in Chinese), 2026, 39(5), 783–792.
陈高原, 孙辉, 刘芙蓉, 于斌. MOF-76@黏胶水刺非织造材料的原位合成及其对有机染料的吸附性能. 高分子通报, 2026, 39(5), 783–792. DOI： 10.14028/j.cnki.1003-3726.2026.25.378.

Chen, G. Y.; Sun, H.; Liu, F. R.; Yu, B. In situ synthesis of MOF-76@viscose spunlace nonwoven and the adsorption performance for organic dyes. Polym. Bull. (in Chinese), 2026, 39(5), 783–792. DOI： 10.14028/j.cnki.1003-3726.2026.25.378.

摘要

为了解决金属有机框架材料(MOFs)回收再利用困难的问题，通过原位溶剂热合成将MOF-76锚定在黏胶水刺非织造材料(VSN)表面，并将所得的MOF-76@VSN用于水中有机染料的吸附研究。结果表明：VSN纤维表面的MOF-76具有圆柱棒状结构，长度约为400 nm。MOF-76@VSN对一些阴离子染料，如刚果红(CR)、胭脂红(CAR)表现出较高的吸附效率，在吸附温度为35 ℃，吸附溶液pH=7时，MOF-76@VSN对CR的吸附效率最佳，在30 min内达到99.50%。MOF-76@VSN表现出良好的可重复使用性，经过5次吸附—脱附循环后，其对CR的吸附效率约为67.05%。

Abstract

To solve the difficulty of recovery and reuse of metal-organic frameworks (MOFs) in aqueous systems

MOF-76 was successfully immobilized onto viscose spunlace nonwoven (VSN) fibers

via

in situ

solvothermal synthesis. The resulting MOF-76@VSN was applied for the adsorption of organic dyes from water. The results showed that MOF-76 crystals with a rod-like morphology were anchored on the surface of VSN fibers

the average length was approximately 400 nm. MOF-76@VSN demonstrates high adsorption efficiency toward several anionic dyes

such as congo red (CR) and carmine (CAR). Under the optimal conditions of adsorption temperature of 35 ℃

and the adsorption solution of pH=7; the adsorption efficiency of MOF-76@VSN for CR was the maxmium

and reached 99.50% within 30 min. In addition

MOF-76@VSN exhibits good reusability

maintaining an adsorption efficiency of approximately 67.05% after five adsorption–desorption cycles.

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